Imido/nitrene ligands in the complexes of platinum metals
Igor L. Eremenko
1
,
S.E. Nefedov
1
,
A.V Sidorov
1
,
M O Ponina
1
,
P V Danilov
1
,
T. A. Stromnova
1
,
Igor Stolarov
1
,
S B Katser
1
,
S T Orlova
1
,
M.N. Vargaftik
1
,
I. I. Moiseev
1
,
Publication type: Journal Article
Publication date: 1998-01-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A synthetic search for palladium and platinum complexes with nitrene ligands via reaction of tetranuclear cluster Pd 4 ( μ 2 -CO) 4 ( μ 2 -OAc) 4 with nitrosobenzene and reactions of mononuclear complexes [MX 4 ] 2− (M=Pt, Pd; X=Cl, NO 2 ) with o -phenylenediamine and its N -phenyl derivative have been carried out. The complexes obtained, [Pd(OAc) o -(PhN)(NO)C 6 H 4 ] 2 , Pd[ o -(NPh)(N)C 6 H 4 ] 2 , Pt[ o -(NPh)(N)C 6 H 4 ] 2 , Pt 2 [ o -(NPh)(N)C 6 H 4 ] 4 [O 3 SCF 3 ] 2 , and Pt 2 [ o -(NPh)(N)C 6 H 4 ] 4 Br 2 , have been structurally characterized by single crystal X-ray diffraction studies. The oxidation of complex Pt[ o -(NPh)(N)C 6 H 4 ] 2 by excess AgO 3 SCF 3 afforded a heterotricyclic quinoxaline derivative, whose structure has been determined by X-ray analysis. The data obtained suggest that labile nitrene species coordinated to Pd and Pt complexes are possible intermediates in the reactions under study.
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31
Total citations:
31
Citations from 2024:
2
(6%)
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Citations in journal:
2
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GOST
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Eremenko I. L. et al. Imido/nitrene ligands in the complexes of platinum metals // Journal of Organometallic Chemistry. 1998. Vol. 551. No. 1-2. pp. 171-194.
GOST all authors (up to 50)
Copy
Eremenko I. L., Nefedov S., Sidorov A., Ponina M. O., Danilov P. V., Stromnova T. A., Stolarov I., Katser S. B., Orlova S. T., Vargaftik M., Moiseev I. I., Ustynyuk Y. Imido/nitrene ligands in the complexes of platinum metals // Journal of Organometallic Chemistry. 1998. Vol. 551. No. 1-2. pp. 171-194.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/S0022-328X(97)00441-5
UR - https://linkinghub.elsevier.com/retrieve/pii/S0022328X97004415
TI - Imido/nitrene ligands in the complexes of platinum metals
T2 - Journal of Organometallic Chemistry
AU - Eremenko, Igor L.
AU - Nefedov, S.E.
AU - Sidorov, A.V
AU - Ponina, M O
AU - Danilov, P V
AU - Stromnova, T. A.
AU - Stolarov, Igor
AU - Katser, S B
AU - Orlova, S T
AU - Vargaftik, M.N.
AU - Moiseev, I. I.
AU - Ustynyuk, Yu.A.
PY - 1998
DA - 1998/01/01
PB - Elsevier
SP - 171-194
IS - 1-2
VL - 551
SN - 0022-328X
SN - 1872-8561
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1998_Eremenko,
author = {Igor L. Eremenko and S.E. Nefedov and A.V Sidorov and M O Ponina and P V Danilov and T. A. Stromnova and Igor Stolarov and S B Katser and S T Orlova and M.N. Vargaftik and I. I. Moiseev and Yu.A. Ustynyuk},
title = {Imido/nitrene ligands in the complexes of platinum metals},
journal = {Journal of Organometallic Chemistry},
year = {1998},
volume = {551},
publisher = {Elsevier},
month = {jan},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0022328X97004415},
number = {1-2},
pages = {171--194},
doi = {10.1016/S0022-328X(97)00441-5}
}
Cite this
MLA
Copy
Eremenko, Igor L., et al. “Imido/nitrene ligands in the complexes of platinum metals.” Journal of Organometallic Chemistry, vol. 551, no. 1-2, Jan. 1998, pp. 171-194. https://linkinghub.elsevier.com/retrieve/pii/S0022328X97004415.