XPS detection of unusual Cu(II) to Cu(I) transition on the surface of complexes with redox-active ligands
Тип публикации: Journal Article
Дата публикации: 2020-01-01
scimago Q2
wos Q3
БС2
SJR: 0.601
CiteScore: 3.6
Impact factor: 1.5
ISSN: 03682048, 18732526
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
Spectroscopy
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Radiation
Краткое описание
Abstract Electronic structure of copper complexes with redox-active ligands was studied by XPS. The temperature dependence of the redistribution of electron and spin densities was shown. A low temperature anomaly of magnetic properties of the copper complex with redox-active ligands was detected. The observed two states of copper (Cu+1 and Cu+2) allowed proposing valence tautomerism («redox-isomer» copper complex). The donating role of nitrogen atoms was established in the copper complex with redox-active ligand. The role of ligands in the formation of the electronic structure of square-planar complexes was revealed.
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ГОСТ
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Ivanova T. et al. XPS detection of unusual Cu(II) to Cu(I) transition on the surface of complexes with redox-active ligands // Journal of Electron Spectroscopy and Related Phenomena. 2020. Vol. 238. p. 146878.
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Ivanova T., Maslakov K., Sidorov A., Kiskin M. A., Linko R., Savilov S. V., Lunin V. V., Eremenko I. L. XPS detection of unusual Cu(II) to Cu(I) transition on the surface of complexes with redox-active ligands // Journal of Electron Spectroscopy and Related Phenomena. 2020. Vol. 238. p. 146878.
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TY - JOUR
DO - 10.1016/j.elspec.2019.06.010
UR - https://doi.org/10.1016/j.elspec.2019.06.010
TI - XPS detection of unusual Cu(II) to Cu(I) transition on the surface of complexes with redox-active ligands
T2 - Journal of Electron Spectroscopy and Related Phenomena
AU - Ivanova, T.M.
AU - Maslakov, Konstantin
AU - Sidorov, A.V
AU - Kiskin, Mikhail A.
AU - Linko, Roman
AU - Savilov, Serguei V.
AU - Lunin, V. V.
AU - Eremenko, Igor L.
PY - 2020
DA - 2020/01/01
PB - Elsevier
SP - 146878
VL - 238
SN - 0368-2048
SN - 1873-2526
ER -
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BibTex (до 50 авторов)
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@article{2020_Ivanova,
author = {T.M. Ivanova and Konstantin Maslakov and A.V Sidorov and Mikhail A. Kiskin and Roman Linko and Serguei V. Savilov and V. V. Lunin and Igor L. Eremenko},
title = {XPS detection of unusual Cu(II) to Cu(I) transition on the surface of complexes with redox-active ligands},
journal = {Journal of Electron Spectroscopy and Related Phenomena},
year = {2020},
volume = {238},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/j.elspec.2019.06.010},
pages = {146878},
doi = {10.1016/j.elspec.2019.06.010}
}