Open Access
Energetic Materials Frontiers, volume 3, issue 3, pages 146-153
Simple and energetic: Novel combination of furoxan and 1,2,4-triazole rings in the synthesis of energetic materials
Ivan V Ananyev
2, 3
,
Ekaterina V Dubasova
2, 4
,
Fedor E. Teslenko
1
,
Dmitry Khakimov
1
,
Chunlin He
6
,
Siping Pang
6
,
4
Publication type: Journal Article
Publication date: 2022-09-01
Journal:
Energetic Materials Frontiers
Quartile SCImago
Q1
Quartile WOS
—
Impact factor: —
ISSN: 26666472
Materials Chemistry
Materials Science (miscellaneous)
Industrial and Manufacturing Engineering
Chemical Engineering (miscellaneous)
Abstract
Two novel representatives of energetic (1,2,4-triazolyl)furoxans were prepared from the readily available (furoxanyl)amidrazones. Synthesized compounds were thoroughly characterized with IR and multinuclear NMR spectroscopy, elemental analysis and X-ray diffraction data. Analysis of structural features supported by quantum-chemical calculations revealed the main reasons for experimentally observed difference in thermal stability and mechanical sensitivity of both compounds. It was found that 3-cyano-4-(1 H -1,2,4-triazol-3-yl)furoxan is more thermally stable ( T d : 229 °C) than 4-azido-3-(1 H -1,2,4-triazol-3-yl)furoxan ( T d : 154 °C) and the latter compound is also more sensitive to impact and friction. In addition, both heterocyclic assemblies have high detonation parameters ( v D : 7.0–8.0 km·s −1 ; p : 22–29 GPa) exceeding those of benchmark explosives trinitrotoluene and hexanitrostilbene which enable their usability for various energetic applications.
Top-30
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Citations by publishers
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1
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3
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Elsevier
4 publications, 26.67%
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Wiley
3 publications, 20%
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2 publications, 13.33%
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2 publications, 13.33%
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Frontiers Media S.A.
1 publication, 6.67%
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1 publication, 6.67%
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American Institute of Physics (AIP)
1 publication, 6.67%
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American Chemical Society (ACS)
1 publication, 6.67%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Larin A. A. et al. Simple and energetic: Novel combination of furoxan and 1,2,4-triazole rings in the synthesis of energetic materials // Energetic Materials Frontiers. 2022. Vol. 3. No. 3. pp. 146-153.
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Larin A. A., Ananyev I. V., Dubasova E. V., Teslenko F. E., Monogarov K., Khakimov D., He C., Pang S., Gazieva G. A., Fershtat L. L. Simple and energetic: Novel combination of furoxan and 1,2,4-triazole rings in the synthesis of energetic materials // Energetic Materials Frontiers. 2022. Vol. 3. No. 3. pp. 146-153.
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TY - JOUR
DO - 10.1016/j.enmf.2022.08.002
UR - https://linkinghub.elsevier.com/retrieve/pii/S2666647222000616
TI - Simple and energetic: Novel combination of furoxan and 1,2,4-triazole rings in the synthesis of energetic materials
T2 - Energetic Materials Frontiers
AU - Larin, Alexander A
AU - Ananyev, Ivan V
AU - Dubasova, Ekaterina V
AU - Teslenko, Fedor E.
AU - Monogarov, Konstantin
AU - Khakimov, Dmitry
AU - He, Chunlin
AU - Pang, Siping
AU - Gazieva, Galina A.
AU - Fershtat, Leonid L.
PY - 2022
DA - 2022/09/01 00:00:00
PB - Elsevier
SP - 146-153
IS - 3
VL - 3
SN - 2666-6472
ER -
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@article{2022_Larin,
author = {Alexander A Larin and Ivan V Ananyev and Ekaterina V Dubasova and Fedor E. Teslenko and Konstantin Monogarov and Dmitry Khakimov and Chunlin He and Siping Pang and Galina A. Gazieva and Leonid L. Fershtat},
title = {Simple and energetic: Novel combination of furoxan and 1,2,4-triazole rings in the synthesis of energetic materials},
journal = {Energetic Materials Frontiers},
year = {2022},
volume = {3},
publisher = {Elsevier},
month = {sep},
url = {https://linkinghub.elsevier.com/retrieve/pii/S2666647222000616},
number = {3},
pages = {146--153},
doi = {10.1016/j.enmf.2022.08.002}
}
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MLA
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Larin, Alexander A., et al. “Simple and energetic: Novel combination of furoxan and 1,2,4-triazole rings in the synthesis of energetic materials.” Energetic Materials Frontiers, vol. 3, no. 3, Sep. 2022, pp. 146-153. https://linkinghub.elsevier.com/retrieve/pii/S2666647222000616.