том 392 страницы 73-76

Synthesis of iron complexes [(η5-indenyl)FeL3]+ from the readily available[(η5-indenyl)Fe(η6-indene)]+

Тип публикацииJournal Article
Дата публикации2012-09-01
scimago Q3
wos Q2
БС2
SJR0.393
CiteScore5.5
Impact factor3.2
ISSN00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
The iron complex [(η5-indenyl)Fe(η6-indene)]+ (1) was prepared via one-pot procedure in 25% yield by reaction of FeCl3 with indenyl lithium giving Fe(η5-indenyl)2 and its subsequent protonation with CF3COOH. Cation 1 reacts with 2e ligands L (L = tBuNC, P(OMe)3, P(OEt)3, PMe(OEt)2) under visible light irradiation giving the half-sandwich complexes [(η5-indenyl)FeL3]+ in 50–80% yields. Protonation of the related ruthenium complex Ru(η5-indenyl)2 gives cation [(η5-indenyl)Ru(η6-indene)]+ (23% yield). The structures of [1]BF4 and [(η5-indenyl)Fe(tBuNC)3]PF6 were determined by X-ray diffraction.
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Perekalin D. S. et al. Synthesis of iron complexes [(η5-indenyl)FeL3]+ from the readily available[(η5-indenyl)Fe(η6-indene)]+ // Inorganica Chimica Acta. 2012. Vol. 392. pp. 73-76.
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Perekalin D. S., Babak M. V., Karslyan E. E., Nelyubina Y. V., Kudinov A. R. Synthesis of iron complexes [(η5-indenyl)FeL3]+ from the readily available[(η5-indenyl)Fe(η6-indene)]+ // Inorganica Chimica Acta. 2012. Vol. 392. pp. 73-76.
RIS |
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TY - JOUR
DO - 10.1016/j.ica.2012.06.018
UR - https://linkinghub.elsevier.com/retrieve/pii/S0020169312003830
TI - Synthesis of iron complexes [(η5-indenyl)FeL3]+ from the readily available[(η5-indenyl)Fe(η6-indene)]+
T2 - Inorganica Chimica Acta
AU - Perekalin, Dmitry S
AU - Babak, Maria V
AU - Karslyan, Eduard E
AU - Nelyubina, Yulia V.
AU - Kudinov, Alexander R
PY - 2012
DA - 2012/09/01
PB - Elsevier
SP - 73-76
VL - 392
SN - 0020-1693
SN - 1873-3255
ER -
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@article{2012_Perekalin,
author = {Dmitry S Perekalin and Maria V Babak and Eduard E Karslyan and Yulia V. Nelyubina and Alexander R Kudinov},
title = {Synthesis of iron complexes [(η5-indenyl)FeL3]+ from the readily available[(η5-indenyl)Fe(η6-indene)]+},
journal = {Inorganica Chimica Acta},
year = {2012},
volume = {392},
publisher = {Elsevier},
month = {sep},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0020169312003830},
pages = {73--76},
doi = {10.1016/j.ica.2012.06.018}
}