Elsevier
Inorganica Chimica Acta
,  volume 495 ,  pages 118976

Ortho-lithiation of N-aryl ferrocenylmethanimines

Publication type: Journal Article
Publication date: 2019-09-01
Elsevier
scimago Q3
wos Q2
SJR: 0.393
CiteScore: 5.5
Impact factor: 3.2
ISSN: 00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A series of N-aryl ferrocenylmethanimines was successfully lithiated at ortho-position with the following treatment with various electrophiles such as ketone, alkyl and silyl halides yielding 1,2-disubstituted ferrocenes with good yields. The product of benzophenone addition was characterized with X-ray diffraction study. We showed that cyclization of 2-hydroxymethylferrocenylcarbimines with Tf2O led to formation of 5H-pyrrolo[3,4-a]ferrocen-6-ium salt - a potential precursor of ferrocene-based heterocyclic carbenes.
Found 
Found 
2 citations
Nikovskiy Igor
39 publications,  253 citations
h-index: 9
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
1 citation
Nelyubina Yulia
🤝
DSc in Chemistry
506 publications,  7 574 citations,  1 review
h-index: 38
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Moscow Institute of Physics and Technology
Moscow Institute of Physics and Technology
Research interests
Big Data
Catalysis
Machine learning
Metal-organic frameworks
Quantum technologies
Sensors
1 citation
Pavlov Alexander
🥼 🤝
DSc in Chemistry
120 publications,  1 961 citations
h-index: 23
Bauman Moscow State Technical University
Bauman Moscow State Technical University
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Mendeleev University of Chemical Technology of Russia
Mendeleev University of Chemical Technology of Russia
Research interests
Digital Chemistry
Digital Materials Science
Molecular magnetism

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GOST Copy
Nikovskiy I. A. et al. Ortho-lithiation of N-aryl ferrocenylmethanimines // Inorganica Chimica Acta. 2019. Vol. 495. p. 118976.
GOST all authors (up to 50) Copy
Nikovskiy I. A., Spiridonov K. A., Zakharova D. V., Platonova E. O., Pavlov A., Nelyubina Y. V., Polezhaev A. Ortho-lithiation of N-aryl ferrocenylmethanimines // Inorganica Chimica Acta. 2019. Vol. 495. p. 118976.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.ica.2019.118976
UR - https://doi.org/10.1016/j.ica.2019.118976
TI - Ortho-lithiation of N-aryl ferrocenylmethanimines
T2 - Inorganica Chimica Acta
AU - Nikovskiy, Igor A
AU - Spiridonov, Kirill A
AU - Zakharova, Daria V
AU - Platonova, Elena O
AU - Pavlov, Alexander
AU - Nelyubina, Yulia V.
AU - Polezhaev, Alexander
PY - 2019
DA - 2019/09/01
PB - Elsevier
SP - 118976
VL - 495
SN - 0020-1693
SN - 1873-3255
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2019_Nikovskiy,
author = {Igor A Nikovskiy and Kirill A Spiridonov and Daria V Zakharova and Elena O Platonova and Alexander Pavlov and Yulia V. Nelyubina and Alexander Polezhaev},
title = {Ortho-lithiation of N-aryl ferrocenylmethanimines},
journal = {Inorganica Chimica Acta},
year = {2019},
volume = {495},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/j.ica.2019.118976},
pages = {118976},
doi = {10.1016/j.ica.2019.118976}
}