Journal of Luminescence, volume 203, pages 546-553

Luminescence and electronic structure of Nd3+ complex with pyrazole-substituted 1,3-diketone and 1,10-phenanthroline

D A Metlina 1
M T Metlin 1
S A Ambrozevich 2, 3, 4
Ilya V. Taydakov 1, 3
V. S. Krivobok 1, 3
D F Aminev 1
A S Tobokhova 1, 3
Publication typeJournal Article
Publication date2018-11-01
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor3.6
ISSN00222313
General Chemistry
Biochemistry
Biophysics
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Abstract
Abstract We studied luminescent properties of two Nd 3 + complexes with two different ligands. The first one was 1,3-diketone bearing a pyrazole fragment and the second ligand was either 1,10-phenanthroline or EtOH. For the ligand environment composed of 1,3-diketone and 1,10-phenanthroline the position of the hybrid triplet level was as low as 18200 cm − 1 . The spectral features specific to Nd 3 + emission observed in the photoluminescence spectra of the complexes under optical excitation provided the evidence for ion-centered luminescence. Radiative transitions were identified using the obtained spectroscopic data. Corresponding diagram of the energy levels of the complex with 1,10-phenanthroline ligand was developed. Possible energy transfer pathways were discussed.

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GOST Copy
Metlina D. A. et al. Luminescence and electronic structure of Nd3+ complex with pyrazole-substituted 1,3-diketone and 1,10-phenanthroline // Journal of Luminescence. 2018. Vol. 203. pp. 546-553.
GOST all authors (up to 50) Copy
Metlina D. A., Metlin M. T., Ambrozevich S. A., Taydakov I. V., Lyssenko K. A., VITUKHNOVSKY A. G., Selyukov A. S., Krivobok V. S., Aminev D. F., Tobokhova A. S. Luminescence and electronic structure of Nd3+ complex with pyrazole-substituted 1,3-diketone and 1,10-phenanthroline // Journal of Luminescence. 2018. Vol. 203. pp. 546-553.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.jlumin.2018.07.005
UR - https://doi.org/10.1016/j.jlumin.2018.07.005
TI - Luminescence and electronic structure of Nd3+ complex with pyrazole-substituted 1,3-diketone and 1,10-phenanthroline
T2 - Journal of Luminescence
AU - Metlina, D A
AU - Metlin, M T
AU - Ambrozevich, S A
AU - Taydakov, Ilya V.
AU - Lyssenko, Konstantin A.
AU - VITUKHNOVSKY, A. G.
AU - Selyukov, Alexandr S
AU - Krivobok, V. S.
AU - Aminev, D F
AU - Tobokhova, A S
PY - 2018
DA - 2018/11/01 00:00:00
PB - Elsevier
SP - 546-553
VL - 203
SN - 0022-2313
ER -
BibTex
Cite this
BibTex Copy
@article{2018_Metlina,
author = {D A Metlina and M T Metlin and S A Ambrozevich and Ilya V. Taydakov and Konstantin A. Lyssenko and A. G. VITUKHNOVSKY and Alexandr S Selyukov and V. S. Krivobok and D F Aminev and A S Tobokhova},
title = {Luminescence and electronic structure of Nd3+ complex with pyrazole-substituted 1,3-diketone and 1,10-phenanthroline},
journal = {Journal of Luminescence},
year = {2018},
volume = {203},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016/j.jlumin.2018.07.005},
pages = {546--553},
doi = {10.1016/j.jlumin.2018.07.005}
}
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