Synthesis of cyclohexadienyl ruthenium arene complexes by replacement of acetonitrile ligands in [(η5-C6H7)Ru(MeCN)3]+
Publication type: Journal Article
Publication date: 2014-03-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Heating of the cyclohexadienyl ruthenium complex [(η5-C6H7)Ru(MeCN)3]+ (1) with arenes results in replacement of acetonitrile ligands giving complexes [(η5-C6H7)Ru(arene)]+ (arene = toluene, o-xylene, hexamethylbenzene, p-toluidine, benzo-15-crown-5, ethyl ester of N-acetylphenylalanine) in 53–93% yields. Similar reaction of 1 with naphthalene produces labile complex [(η5-C6H7)Ru(naphthalene)]+ which readily undergoes solvolysis in acetone. The reaction of 1 with 1,5-cyclooctadiene unexpectedly gives the benzene complex [(η3,η2-C8H11)Ru(C6H6)]+ in 44% yield, as a result of formal abstraction of two hydrogen atoms. Energy decomposition analysis revealed that the cyclohexadienyl ruthenium cation [(η5-C6H7)Ru]+ is less arenophilic then [CpRu]+ due to weaker orbital interaction with arenes. The structure of [(η5-C6H7)Ru(benzo-15-crown-5)]PF6 was established by X-ray diffraction.
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Perekalin D. S. et al. Synthesis of cyclohexadienyl ruthenium arene complexes by replacement of acetonitrile ligands in [(η5-C6H7)Ru(MeCN)3]+ // Journal of Organometallic Chemistry. 2014. Vol. 754. pp. 1-4.
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Perekalin D. S., Trifonova E. A., Nelyubina Y. V., Kudinov A. R. Synthesis of cyclohexadienyl ruthenium arene complexes by replacement of acetonitrile ligands in [(η5-C6H7)Ru(MeCN)3]+ // Journal of Organometallic Chemistry. 2014. Vol. 754. pp. 1-4.
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TY - JOUR
DO - 10.1016/j.jorganchem.2013.12.031
UR - https://linkinghub.elsevier.com/retrieve/pii/S0022328X13008954
TI - Synthesis of cyclohexadienyl ruthenium arene complexes by replacement of acetonitrile ligands in [(η5-C6H7)Ru(MeCN)3]+
T2 - Journal of Organometallic Chemistry
AU - Perekalin, Dmitry S
AU - Trifonova, Evgeniya A
AU - Nelyubina, Yulia V.
AU - Kudinov, Alexander R
PY - 2014
DA - 2014/03/01
PB - Elsevier
SP - 1-4
VL - 754
SN - 0022-328X
SN - 1872-8561
ER -
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@article{2014_Perekalin,
author = {Dmitry S Perekalin and Evgeniya A Trifonova and Yulia V. Nelyubina and Alexander R Kudinov},
title = {Synthesis of cyclohexadienyl ruthenium arene complexes by replacement of acetonitrile ligands in [(η5-C6H7)Ru(MeCN)3]+},
journal = {Journal of Organometallic Chemistry},
year = {2014},
volume = {754},
publisher = {Elsevier},
month = {mar},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0022328X13008954},
pages = {1--4},
doi = {10.1016/j.jorganchem.2013.12.031}
}