Synthesis of cyclohexadienyl ruthenium complexes by replacement of the naphthalene ligand in [(η5-C6H3Me4)Ru(η6-C10H8)]+
Publication type: Journal Article
Publication date: 2015-06-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Reactions of the cyclohexadienyl ruthenium complex [(η5-C6H3Me4)Ru(C10H8)]+ (1) with 2-electron ligands L lead to replacement of the naphthalene ligand with formation of the half–sandwich complexes [(η5-C6H3Me4)RuL3]+ (L = MeCN, tBuNC, P(OEt)3, 1,3,5-triaza-7-phosphaadamantane). Similar reactions with P(OMe)3 or dppe in the presence of Cl− give the neutral complexes (η5-C6H3Me4)Ru(P(OMe)3)2Cl or (η5-C6H3Me4)Ru(dppe)Cl, respectively. Cation 1 also exchanges the naphthalene ligand for other arenes producing the corresponding sandwich compounds [(η5-C6H3Me4)Ru(arene)]+ (arene = C6H6, 1,4-C6H4(OMe)2). Complex 1 catalyzes cyclotrimerization of N,N-di(propargyl)tosylamide with 1-octyne or 4-pentynol, but less effectively than [CpRu(C10H8)]+. The mechanism of the naphthalene replacement in 1 was studied by DFT calculations.
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Total citations:
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Citations from 2024:
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(9%)
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Trifonova E. A. et al. Synthesis of cyclohexadienyl ruthenium complexes by replacement of the naphthalene ligand in [(η5-C6H3Me4)Ru(η6-C10H8)]+ // Journal of Organometallic Chemistry. 2015. Vol. 785. pp. 106-111.
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Trifonova E. A., Perekalin D. S., Loskutova N. L., Nelyubina Y. V., Kudinov A. R. Synthesis of cyclohexadienyl ruthenium complexes by replacement of the naphthalene ligand in [(η5-C6H3Me4)Ru(η6-C10H8)]+ // Journal of Organometallic Chemistry. 2015. Vol. 785. pp. 106-111.
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TY - JOUR
DO - 10.1016/j.jorganchem.2015.03.008
UR - https://linkinghub.elsevier.com/retrieve/pii/S0022328X15001473
TI - Synthesis of cyclohexadienyl ruthenium complexes by replacement of the naphthalene ligand in [(η5-C6H3Me4)Ru(η6-C10H8)]+
T2 - Journal of Organometallic Chemistry
AU - Trifonova, Evgeniya A
AU - Perekalin, Dmitry S
AU - Loskutova, Natalia L
AU - Nelyubina, Yulia V.
AU - Kudinov, Alexander R
PY - 2015
DA - 2015/06/01
PB - Elsevier
SP - 106-111
VL - 785
SN - 0022-328X
SN - 1872-8561
ER -
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@article{2015_Trifonova,
author = {Evgeniya A Trifonova and Dmitry S Perekalin and Natalia L Loskutova and Yulia V. Nelyubina and Alexander R Kudinov},
title = {Synthesis of cyclohexadienyl ruthenium complexes by replacement of the naphthalene ligand in [(η5-C6H3Me4)Ru(η6-C10H8)]+},
journal = {Journal of Organometallic Chemistry},
year = {2015},
volume = {785},
publisher = {Elsevier},
month = {jun},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0022328X15001473},
pages = {106--111},
doi = {10.1016/j.jorganchem.2015.03.008}
}