Sandwich complexes of iron and ruthenium with the semiconducting aromatic hydrocarbon picene
Publication type: Journal Article
Publication date: 2018-11-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Pentacyclic aromatic hydrocarbon picene C22H14 was synthesized by the improved two-step procedure from 1-naphthaldehyde in ca. 50% total yield. Reaction of picene with ferrocene in the presence of AlCl3 produced the binuclear iron complex [(CpFe)2(C22H14)](PF6)2. Reactions of picene with [Cp*Ru(MeCN)3]PF6 produced mono- or binuclear complexes depending on the concentration and ratio of reactants. The structures of the binuclear iron complex and the mononuclear ruthenium complex were established by X-ray diffraction analysis. Irradiation of the iron complex regenerated free picene; this method is proposed for purification and deposition of insoluble aromatic hydrocarbons.
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Shved A. M. et al. Sandwich complexes of iron and ruthenium with the semiconducting aromatic hydrocarbon picene // Journal of Organometallic Chemistry. 2018. Vol. 875. pp. 24-28.
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Shved A. M., Perekalin D. S., Nelyubina Y. V. Sandwich complexes of iron and ruthenium with the semiconducting aromatic hydrocarbon picene // Journal of Organometallic Chemistry. 2018. Vol. 875. pp. 24-28.
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TY - JOUR
DO - 10.1016/j.jorganchem.2018.08.026
UR - https://linkinghub.elsevier.com/retrieve/pii/S0022328X18306211
TI - Sandwich complexes of iron and ruthenium with the semiconducting aromatic hydrocarbon picene
T2 - Journal of Organometallic Chemistry
AU - Shved, Andrei M
AU - Perekalin, Dmitry S
AU - Nelyubina, Yulia V.
PY - 2018
DA - 2018/11/01
PB - Elsevier
SP - 24-28
VL - 875
SN - 0022-328X
SN - 1872-8561
ER -
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@article{2018_Shved,
author = {Andrei M Shved and Dmitry S Perekalin and Yulia V. Nelyubina},
title = {Sandwich complexes of iron and ruthenium with the semiconducting aromatic hydrocarbon picene},
journal = {Journal of Organometallic Chemistry},
year = {2018},
volume = {875},
publisher = {Elsevier},
month = {nov},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0022328X18306211},
pages = {24--28},
doi = {10.1016/j.jorganchem.2018.08.026}
}