Synthesis, structure, solid-state thermolysis, and thermodynamic properties of new heterometallic complex Li2Co2(Piv)6(NEt3)2
Zn V Dobrohotova
1
,
M. A. Bykov
2
,
A S Alihanian
1
,
V. M. Novotortsev
1
,
G.G. Aleksandrov
1
,
A. V. Tyurin
1
,
A L Emelina
2
,
I. P. MALKEROVA
1
,
A.V Sidorov
1
,
K. S. Gavrichev
1
,
Publication type: Journal Article
Publication date: 2010-10-01
scimago Q2
wos Q1
SJR: 0.629
CiteScore: 6.8
Impact factor: 3.5
ISSN: 00224596, 1095726X
Materials Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Inorganic Chemistry
Physical and Theoretical Chemistry
Condensed Matter Physics
Abstract
Abstract The reaction of lithium pivalate, polymeric cobalt pivalate [Co(Piv)2]n, and triethylamine in THF at 60 °С afforded the new heterometallic antiferromagnetic complex Li2Co2(Piv)6(NEt3)2 (2). The molecular and crystal structure of complex 2 was established and its magnetic behavior was studied. The vaporization and solid-state thermolysis of 2 were investigated. The thermodynamic characteristics of complex 2 were determined. The results of the present study show that complex 2 can be used as a potential molecular precursor for the synthesis of thin films of lithium cobaltate LiCoO2.
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Total citations:
29
Citations from 2024:
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GOST
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Dobrohotova Z. V. et al. Synthesis, structure, solid-state thermolysis, and thermodynamic properties of new heterometallic complex Li2Co2(Piv)6(NEt3)2 // Journal of Solid State Chemistry. 2010. Vol. 183. No. 10. pp. 2475-2482.
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Dobrohotova Z. V., Bykov M. A., Alihanian A. S., Novotortsev V. M., Aleksandrov G., Tyurin A. V., Emelina A. L., MALKEROVA I. P., Sidorov A., Kiskin M. A., Gavrichev K. S., Bogomyakov A. S., Eremenko I. L. Synthesis, structure, solid-state thermolysis, and thermodynamic properties of new heterometallic complex Li2Co2(Piv)6(NEt3)2 // Journal of Solid State Chemistry. 2010. Vol. 183. No. 10. pp. 2475-2482.
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RIS
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TY - JOUR
DO - 10.1016/j.jssc.2010.08.007
UR - https://doi.org/10.1016/j.jssc.2010.08.007
TI - Synthesis, structure, solid-state thermolysis, and thermodynamic properties of new heterometallic complex Li2Co2(Piv)6(NEt3)2
T2 - Journal of Solid State Chemistry
AU - Dobrohotova, Zn V
AU - Bykov, M. A.
AU - Alihanian, A S
AU - Novotortsev, V. M.
AU - Aleksandrov, G.G.
AU - Tyurin, A. V.
AU - Emelina, A L
AU - MALKEROVA, I. P.
AU - Sidorov, A.V
AU - Kiskin, Mikhail A.
AU - Gavrichev, K. S.
AU - Bogomyakov, Artem S
AU - Eremenko, Igor L.
PY - 2010
DA - 2010/10/01
PB - Elsevier
SP - 2475-2482
IS - 10
VL - 183
SN - 0022-4596
SN - 1095-726X
ER -
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BibTex (up to 50 authors)
Copy
@article{2010_Dobrohotova,
author = {Zn V Dobrohotova and M. A. Bykov and A S Alihanian and V. M. Novotortsev and G.G. Aleksandrov and A. V. Tyurin and A L Emelina and I. P. MALKEROVA and A.V Sidorov and Mikhail A. Kiskin and K. S. Gavrichev and Artem S Bogomyakov and Igor L. Eremenko},
title = {Synthesis, structure, solid-state thermolysis, and thermodynamic properties of new heterometallic complex Li2Co2(Piv)6(NEt3)2},
journal = {Journal of Solid State Chemistry},
year = {2010},
volume = {183},
publisher = {Elsevier},
month = {oct},
url = {https://doi.org/10.1016/j.jssc.2010.08.007},
number = {10},
pages = {2475--2482},
doi = {10.1016/j.jssc.2010.08.007}
}
Cite this
MLA
Copy
Dobrohotova, Zn V., et al. “Synthesis, structure, solid-state thermolysis, and thermodynamic properties of new heterometallic complex Li2Co2(Piv)6(NEt3)2.” Journal of Solid State Chemistry, vol. 183, no. 10, Oct. 2010, pp. 2475-2482. https://doi.org/10.1016/j.jssc.2010.08.007.