Hybrid iodobismuthates code: adapting the geometry of Bi polyhedra to weak interactions
Vitalii Yu. Kotov
1, 2
,
Petr A. Buikin
3
,
Ivan V Ananyev
3, 6
,
A Gavrikov
4
,
Michael G. Medvedev
3, 7
Publication type: Journal Article
Publication date: 2021-03-31
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
The crystal structure of the new iodobismuthate (PyPy)2(PyPyH)2Bi6I26 was found to consist of unusual hexanuclear [Bi6I26]6− anions containing the linear I42− unit, and the experimental Bi–I bond lengths in this anion were used to obtain the relationship between bond length and bond energy. A statistical analysis of 229 crystal structures of iodobismuthates, based on the quantum chemically estimated strength of Bi–I bonds, revealed that the total energy of the Bi3+ polyhedron remains virtually constant at 64 ± 2 kcal mol−1, regardless of its geometry within this family of materials. Thus, the polyhedron geometry flexibly adapts to the relatively weak interactions between iodobismuthate anions and embedded cations.
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Kotov V. Y. et al. Hybrid iodobismuthates code: adapting the geometry of Bi polyhedra to weak interactions // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 166-169.
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Kotov V. Y., Buikin P. A., Ilyukhin A. B., Korlyukov A., Ananyev I. V., Gavrikov A., Medvedev M. G. Hybrid iodobismuthates code: adapting the geometry of Bi polyhedra to weak interactions // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 166-169.
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TY - JOUR
DO - 10.1016/j.mencom.2021.03.007
UR - https://linkinghub.elsevier.com/retrieve/pii/S0959943621000614
TI - Hybrid iodobismuthates code: adapting the geometry of Bi polyhedra to weak interactions
T2 - Mendeleev Communications
AU - Kotov, Vitalii Yu.
AU - Buikin, Petr A.
AU - Ilyukhin, Andrey B.
AU - Korlyukov, Alexander
AU - Ananyev, Ivan V
AU - Gavrikov, A
AU - Medvedev, Michael G.
PY - 2021
DA - 2021/03/31
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 166-169
IS - 2
VL - 31
SN - 0959-9436
SN - 1364-551X
ER -
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@article{2021_Kotov,
author = {Vitalii Yu. Kotov and Petr A. Buikin and Andrey B. Ilyukhin and Alexander Korlyukov and Ivan V Ananyev and A Gavrikov and Michael G. Medvedev},
title = {Hybrid iodobismuthates code: adapting the geometry of Bi polyhedra to weak interactions},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {mar},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0959943621000614},
number = {2},
pages = {166--169},
doi = {10.1016/j.mencom.2021.03.007}
}
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MLA
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Kotov, Vitalii Yu., et al. “Hybrid iodobismuthates code: adapting the geometry of Bi polyhedra to weak interactions.” Mendeleev Communications, vol. 31, no. 2, Mar. 2021, pp. 166-169. https://linkinghub.elsevier.com/retrieve/pii/S0959943621000614.