New mix-ligand copper(i) and copper(ii) pyrazolate complexes with 2,2′-bipyridine
Publication type: Journal Article
Publication date: 2021-03-31
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
The reaction of the trinuclear copper( i ) 3,5-bis(trifluoromethyl) pyrazolate with 2,2′-bipyridine on contact with air leads to the oxidation of Cu centers and affords trinuclear Cu ii complex containing bridged pyrazolate OH anions and chelating bipy ligands. Carrying out the reaction in the presence of dppm prevents oxidation and gives dinuclear copper( i ) complex with bridging dppm and pyrazolate ligands, and chelating bipy ligand. This complex exhibits red-orange phosphorescence originating from the 3MLbipyCT state.
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Total citations:
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Citations from 2024:
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(72%)
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GOST
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Titov A. A. et al. New mix-ligand copper(i) and copper(ii) pyrazolate complexes with 2,2′-bipyridine // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 170-172.
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Titov A. A., Filippov O. A., Smol’yakov A. F., Averin A. A., Shubina E. S. New mix-ligand copper(i) and copper(ii) pyrazolate complexes with 2,2′-bipyridine // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 170-172.
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RIS
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TY - JOUR
DO - 10.1016/j.mencom.2021.03.008
UR - https://doi.org/10.1016/j.mencom.2021.03.008
TI - New mix-ligand copper(i) and copper(ii) pyrazolate complexes with 2,2′-bipyridine
T2 - Mendeleev Communications
AU - Titov, Aleksei A
AU - Filippov, Oleg A.
AU - Smol’yakov, Alexander F.
AU - Averin, Alexey A
AU - Shubina, Elena S.
PY - 2021
DA - 2021/03/31
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 170-172
IS - 2
VL - 31
SN - 0959-9436
SN - 1364-551X
ER -
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@article{2021_Titov,
author = {Aleksei A Titov and Oleg A. Filippov and Alexander F. Smol’yakov and Alexey A Averin and Elena S. Shubina},
title = {New mix-ligand copper(i) and copper(ii) pyrazolate complexes with 2,2′-bipyridine},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {mar},
url = {https://doi.org/10.1016/j.mencom.2021.03.008},
number = {2},
pages = {170--172},
doi = {10.1016/j.mencom.2021.03.008}
}
Cite this
MLA
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Titov, Aleksei A., et al. “New mix-ligand copper(i) and copper(ii) pyrazolate complexes with 2,2′-bipyridine.” Mendeleev Communications, vol. 31, no. 2, Mar. 2021, pp. 170-172. https://doi.org/10.1016/j.mencom.2021.03.008.