Heterometallic Coii-Lii carboxylate complexes with N-heterocyclic carbene, triphenylphosphine and pyridine: a comparative study of magnetic properties
Publication type: Journal Article
Publication date: 2021-09-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
Heterometallic Coii-Lii compounds with N-heterocyclic carbene 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes), tri phenylphosphine (Ph3P) and pyridine (py), [Co2Li2(Piv)6(IMes)2] (Piv is the anion of pivalic acid), [Co2Li2(Piv)6(Ph3P)2] and [Co2Li2(Fur)6(py)2] (Fur is the anion of 2-furoic acid), respectively, have been prepared and structurally characterized by X-ray crystallography. Easy-plane magnetic anisotropy in Coii complexes with pseudo-tetrahedral cores CoO3X (X = C, P and N) was revealed by measuring the magnetic properties together with quantum-chemical calculations using the SA-CASSCF/NEVPT2 approach. The field-induced slow magnetic relaxation of the complexes was mainly attributed to the Raman and direct processes.
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27
Total citations:
27
Citations from 2025:
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(3.7%)
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Citations in journal:
6
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GOST
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Yambulatov D. S. et al. Heterometallic Coii-Lii carboxylate complexes with N-heterocyclic carbene, triphenylphosphine and pyridine: a comparative study of magnetic properties // Mendeleev Communications. 2021. Vol. 31. No. 5. pp. 624-627.
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Yambulatov D. S., Nikolaevskii S. A., Shmelev M. A., Babeshkin K. A., Korchagin D., Efimov N. N., Goloveshkin A. S., Petrov P. A., Kiskin M. A., Sokolov M., Eremenko I. L. Heterometallic Coii-Lii carboxylate complexes with N-heterocyclic carbene, triphenylphosphine and pyridine: a comparative study of magnetic properties // Mendeleev Communications. 2021. Vol. 31. No. 5. pp. 624-627.
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RIS
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TY - JOUR
DO - 10.1016/j.mencom.2021.09.011
UR - https://doi.org/10.1016/j.mencom.2021.09.011
TI - Heterometallic Coii-Lii carboxylate complexes with N-heterocyclic carbene, triphenylphosphine and pyridine: a comparative study of magnetic properties
T2 - Mendeleev Communications
AU - Yambulatov, Dmitriy S
AU - Nikolaevskii, Stanislav Alexandrovich
AU - Shmelev, M. A.
AU - Babeshkin, Konstantin A
AU - Korchagin, Denis
AU - Efimov, Nikolay N.
AU - Goloveshkin, Alexander S.
AU - Petrov, Pavel A.
AU - Kiskin, Mikhail A.
AU - Sokolov, Maxim
AU - Eremenko, Igor L.
PY - 2021
DA - 2021/09/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 624-627
IS - 5
VL - 31
SN - 0959-9436
SN - 1364-551X
ER -
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BibTex (up to 50 authors)
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@article{2021_Yambulatov,
author = {Dmitriy S Yambulatov and Stanislav Alexandrovich Nikolaevskii and M. A. Shmelev and Konstantin A Babeshkin and Denis Korchagin and Nikolay N. Efimov and Alexander S. Goloveshkin and Pavel A. Petrov and Mikhail A. Kiskin and Maxim Sokolov and Igor L. Eremenko},
title = {Heterometallic Coii-Lii carboxylate complexes with N-heterocyclic carbene, triphenylphosphine and pyridine: a comparative study of magnetic properties},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {sep},
url = {https://doi.org/10.1016/j.mencom.2021.09.011},
number = {5},
pages = {624--627},
doi = {10.1016/j.mencom.2021.09.011}
}
Cite this
MLA
Copy
Yambulatov, Dmitriy S., et al. “Heterometallic Coii-Lii carboxylate complexes with N-heterocyclic carbene, triphenylphosphine and pyridine: a comparative study of magnetic properties.” Mendeleev Communications, vol. 31, no. 5, Sep. 2021, pp. 624-627. https://doi.org/10.1016/j.mencom.2021.09.011.