Mendeleev Communications

, volume 31 , issue 6 , pages 781-783

Hayashi ligand-based rhodium complex in carbon monoxide and molecular hydrogen-assisted reductive amination

Sofiya Runikhina ¹

Denis Chusov ^{1, 2}

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A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991 Moscow, Russian Federation |

G. V. Plekhanov Russian University of Economics, 117997 Moscow, Russian Federation |

Publication type: Journal Article

Publication date: 2021-11-01

OOO Zhurnal "Mendeleevskie Soobshcheniya"

Mendeleev Communications

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wos Q3

SJR: 0.305

CiteScore: 3.0

Impact factor: 1.7

ISSN: 09599436, 1364551X

DOI: 10.1016/j.mencom.2021.11.004

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General Chemistry

Abstract

The CO- and H 2 -assisted reductive amination of carbonyl compounds catalyzed by stable chiral Hayashi ligand-based rhodium complex afforded the racemic amines in moderate yields. The racemic outcome of the process results from the elimination of the chiral ligand from the catalyst under the action of hydrogen or carbon monoxide as reductants.

Found

1 citation

Dorovatovskii Pavel

343 publications, 4 064 citations

h-index: 28

National Research Centre "Kurchatov Institute"

1 citation

Bobrova Angelina

🤝

6 publications, 28 citations

h-index: 4

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Research interests

Asymmetric metal complex catalysis

1 citation

Chusov Denis

DSc in Chemistry, professor

100 publications, 2 411 citations, 36 reviews

h-index: 25

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Research interests

Asymmetric metal complex catalysis

1 citation

Novikov Maxim

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PhD in Chemistry

26 publications, 723 citations

h-index: 9

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

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Runikhina S. et al. Hayashi ligand-based rhodium complex in carbon monoxide and molecular hydrogen-assisted reductive amination // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 781-783.

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Runikhina S., Chusov D. Hayashi ligand-based rhodium complex in carbon monoxide and molecular hydrogen-assisted reductive amination // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 781-783.

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RIS Copy

TY - JOUR

DO - 10.1016/j.mencom.2021.11.004

UR - https://doi.org/10.1016/j.mencom.2021.11.004

TI - Hayashi ligand-based rhodium complex in carbon monoxide and molecular hydrogen-assisted reductive amination

T2 - Mendeleev Communications

AU - Runikhina, Sofiya

AU - Chusov, Denis

PY - 2021

DA - 2021/11/01

PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"

SP - 781-783

IS - 6

VL - 31

SN - 0959-9436

SN - 1364-551X

ER -

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BibTex (up to 50 authors) Copy

@article{2021_Runikhina,

author = {Sofiya Runikhina and Denis Chusov},

title = {Hayashi ligand-based rhodium complex in carbon monoxide and molecular hydrogen-assisted reductive amination},

journal = {Mendeleev Communications},

year = {2021},

volume = {31},

publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},

month = {nov},

url = {https://doi.org/10.1016/j.mencom.2021.11.004},

number = {6},

pages = {781--783},

doi = {10.1016/j.mencom.2021.11.004}

}

MLA

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Runikhina, Sofiya, et al. “Hayashi ligand-based rhodium complex in carbon monoxide and molecular hydrogen-assisted reductive amination.” Mendeleev Communications, vol. 31, no. 6, Nov. 2021, pp. 781-783. https://doi.org/10.1016/j.mencom.2021.11.004.