Coordination capabilities of metal ions and steric features of organic ligands affecting formation of mono- or binuclear zinc(II) and cadmium(II) pivalates
Publication type: Journal Article
Publication date: 2018-09-01
scimago Q3
wos Q2
SJR: 0.396
CiteScore: 4.9
Impact factor: 2.6
ISSN: 02775387, 18733719
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract Reactions between zinc(II) or cadmium(II) pivalates and 2,2′-bipyridine, various substituted 1,10-phenanthroline derivatives or 2,2′:6′,2″-terpyridine have resulted in ten mono- and binuclear complexes with general formula [M(piv)2L] or [Cd2(piv)4L2], where piv is the pivalate anion, L is N,N′- or N,N′,N″-donor ligand, and M = Zn(II), Cd(II). Molecular and crystal structures as well as optical properties of the obtained homometallic complexes are reported and discussed. Preferable formation of binuclear cadmium compounds depending on type of the ligand are studied and clearly explained by means of DFT calculations.
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Total citations:
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Citations from 2024:
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Nikolaevskii S. A. et al. Coordination capabilities of metal ions and steric features of organic ligands affecting formation of mono- or binuclear zinc(II) and cadmium(II) pivalates // Polyhedron. 2018. Vol. 152. pp. 61-72.
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Nikolaevskii S. A., Evstifeev I. S., Kiskin M. A., Starikova A. A., Goloveshkin A. S., Novikov V. V., Gogoleva N. V., Sidorov A., Eremenko I. L. Coordination capabilities of metal ions and steric features of organic ligands affecting formation of mono- or binuclear zinc(II) and cadmium(II) pivalates // Polyhedron. 2018. Vol. 152. pp. 61-72.
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TY - JOUR
DO - 10.1016/j.poly.2018.06.021
UR - https://doi.org/10.1016/j.poly.2018.06.021
TI - Coordination capabilities of metal ions and steric features of organic ligands affecting formation of mono- or binuclear zinc(II) and cadmium(II) pivalates
T2 - Polyhedron
AU - Nikolaevskii, Stanislav Alexandrovich
AU - Evstifeev, Igor S
AU - Kiskin, Mikhail A.
AU - Starikova, Alyona A
AU - Goloveshkin, Alexander S.
AU - Novikov, Valentin V
AU - Gogoleva, Natalya V
AU - Sidorov, A.V
AU - Eremenko, Igor L.
PY - 2018
DA - 2018/09/01
PB - Elsevier
SP - 61-72
VL - 152
SN - 0277-5387
SN - 1873-3719
ER -
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BibTex (up to 50 authors)
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@article{2018_Nikolaevskii,
author = {Stanislav Alexandrovich Nikolaevskii and Igor S Evstifeev and Mikhail A. Kiskin and Alyona A Starikova and Alexander S. Goloveshkin and Valentin V Novikov and Natalya V Gogoleva and A.V Sidorov and Igor L. Eremenko},
title = {Coordination capabilities of metal ions and steric features of organic ligands affecting formation of mono- or binuclear zinc(II) and cadmium(II) pivalates},
journal = {Polyhedron},
year = {2018},
volume = {152},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/j.poly.2018.06.021},
pages = {61--72},
doi = {10.1016/j.poly.2018.06.021}
}