Polyhedron

, volume 155 , pages 202-208

Synthesis and photophysical properties of Zn(II) Schiff base complexes possessing strong solvent-dependent solid-state fluorescence

A N Gusev ¹

I Němec ²

V F Shulgin ¹

E V Braga ¹

B. F. Minaev ³

Glib Baryshnikov ³

Zdeněk Trávníček ²

Hans Ågren ^{3, 4}

Igor L. Eremenko ²

Konstantin A. Lyssenko ⁵

Wolfgang Linert ⁶

Hide authors affiliations Show authors affiliations: 6 affiliations

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow 119991, Russia |

Division of Biologically Active Complexes and Molecular Magnets, Regional Centre of Advanced Technologies and Materials, Faculty of Science, Palacký University, Šlechtitelů 27, CZ-783 71 Olomouc, Czech Republic |

Theoretical Chemistry and Biology Laboratory, Royal Institute of Technology, Stockholm SE-10691, Sweden |

⁴

Department of Physics and Astronomy, Uppsala University, Box 516, Se-751 20 Uppsala, Sweden |

⁵

A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991 Moscow, Russia |

⁶

Institute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9/163-AC, A-1060 Vienna, Austria. |

Publication type: Journal Article

Publication date: 2018-11-01

Elsevier

Polyhedron

scimago Q3

wos Q2

SJR: 0.396

CiteScore: 4.9

Impact factor: 2.6

ISSN: 02775387, 18733719

DOI: 10.1016/j.poly.2018.08.019

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Materials Chemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Abstract

Abstract The present article reports on the syntheses, crystal structures and luminescence properties of three solvate forms of a zinc(II) complex containing 4-{(E)-[(2-fluorophenyl)imino]methyl}-5-methyl-2-phenyl-2,4-dihydro-3H-pyrazol-3-one (HL). The reaction of zinc(II)acetate with the HL ligand in ethanol and acetonitrile led to the formation of two solvate analogues [Zn(L)2]·Solv (Solv – ethanol (1) and acetonitrile (2)). The properties of the [Zn(L)2]·Solv complexes were investigated by UV–Vis absorption and fluorescence emission spectroscopy, and the density functional theory calculations. Bader’s topological analysis was performed to investigate the electronic peculiarities of Zn(II) polyhedra and non-covalent interactions within crystal packing of studied solvates.

Found

3 citations

Kiskin Mikhail

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DSc in Chemistry, professor

407 publications, 5 037 citations

h-index: 31

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Research interests

Magnets

Nanoparticles

1 citation

V RAMKUMAR

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199 publications, 3 301 citations

h-index: 33

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GOST Copy

Gusev A. N. et al. Synthesis and photophysical properties of Zn(II) Schiff base complexes possessing strong solvent-dependent solid-state fluorescence // Polyhedron. 2018. Vol. 155. pp. 202-208.

GOST all authors (up to 50) Copy

Gusev A. N., Němec I., Shulgin V. F., Braga E. V., Minaev B. F., Baryshnikov G., Trávníček Z., Ågren H., Eremenko I. L., Lyssenko K. A., Linert W. Synthesis and photophysical properties of Zn(II) Schiff base complexes possessing strong solvent-dependent solid-state fluorescence // Polyhedron. 2018. Vol. 155. pp. 202-208.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.poly.2018.08.019

UR - https://doi.org/10.1016/j.poly.2018.08.019

TI - Synthesis and photophysical properties of Zn(II) Schiff base complexes possessing strong solvent-dependent solid-state fluorescence

T2 - Polyhedron

AU - Gusev, A N

AU - Němec, I

AU - Shulgin, V F

AU - Braga, E V

AU - Minaev, B. F.

AU - Baryshnikov, Glib

AU - Trávníček, Zdeněk

AU - Ågren, Hans

AU - Eremenko, Igor L.

AU - Lyssenko, Konstantin A.

AU - Linert, Wolfgang

PY - 2018

DA - 2018/11/01

PB - Elsevier

SP - 202-208

VL - 155

SN - 0277-5387

SN - 1873-3719

ER -

BibTex

Cite this

BibTex (up to 50 authors) Copy

@article{2018_Gusev,

author = {A N Gusev and I Němec and V F Shulgin and E V Braga and B. F. Minaev and Glib Baryshnikov and Zdeněk Trávníček and Hans Ågren and Igor L. Eremenko and Konstantin A. Lyssenko and Wolfgang Linert},

title = {Synthesis and photophysical properties of Zn(II) Schiff base complexes possessing strong solvent-dependent solid-state fluorescence},

journal = {Polyhedron},

year = {2018},

volume = {155},

publisher = {Elsevier},

month = {nov},

url = {https://doi.org/10.1016/j.poly.2018.08.019},

pages = {202--208},

doi = {10.1016/j.poly.2018.08.019}

}

Publisher

Elsevier

Journal

Polyhedron

scimago Q3

wos Q2

SJR

0.396

CiteScore

4.9

Impact factor

2.6

ISSN

02775387 (Print)

18733719

Labs

Laboratory of Chemistry of Coordinating Polynuclear Compounds

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