Asymmetric Friedel–Crafts alkylation of indoles with 2-nitro-3-arylacrylates catalyzed by a metal-templated hydrogen bonding catalyst
Publication type: Journal Article
Publication date: 2015-08-01
scimago Q3
wos Q3
SJR: 0.334
CiteScore: 3.2
Impact factor: 1.5
ISSN: 00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
An asymmetric Friedel–Crafts alkylation of indoles with 2-nitro-3-arylacrylates catalyzed by a metal-templated hydrogen bonding catalyst has been established. The asymmetric induction relies on chirality transfer solely from the octahedral metal stereocenter via three weak hydrogen bonds. All the products are provided with good to excellent enantioselectivities while modest diastereoselectivities, which can be converted into a variety of valuable indole-containing chiral building blocks including tryptophan derivatives.
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Total citations:
49
Citations from 2025:
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(4.08%)
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GOST
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Liu J. et al. Asymmetric Friedel–Crafts alkylation of indoles with 2-nitro-3-arylacrylates catalyzed by a metal-templated hydrogen bonding catalyst // Tetrahedron Letters. 2015. Vol. 56. No. 32. pp. 4653-4656.
GOST all authors (up to 50)
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Liu J., Gong L., Meggers E. Asymmetric Friedel–Crafts alkylation of indoles with 2-nitro-3-arylacrylates catalyzed by a metal-templated hydrogen bonding catalyst // Tetrahedron Letters. 2015. Vol. 56. No. 32. pp. 4653-4656.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.tetlet.2015.06.046
UR - https://doi.org/10.1016/j.tetlet.2015.06.046
TI - Asymmetric Friedel–Crafts alkylation of indoles with 2-nitro-3-arylacrylates catalyzed by a metal-templated hydrogen bonding catalyst
T2 - Tetrahedron Letters
AU - Liu, Jingfen
AU - Gong, Lei
AU - Meggers, E.
PY - 2015
DA - 2015/08/01
PB - Elsevier
SP - 4653-4656
IS - 32
VL - 56
SN - 0040-4039
SN - 1873-3581
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Liu,
author = {Jingfen Liu and Lei Gong and E. Meggers},
title = {Asymmetric Friedel–Crafts alkylation of indoles with 2-nitro-3-arylacrylates catalyzed by a metal-templated hydrogen bonding catalyst},
journal = {Tetrahedron Letters},
year = {2015},
volume = {56},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016/j.tetlet.2015.06.046},
number = {32},
pages = {4653--4656},
doi = {10.1016/j.tetlet.2015.06.046}
}
Cite this
MLA
Copy
Liu, Jingfen, et al. “Asymmetric Friedel–Crafts alkylation of indoles with 2-nitro-3-arylacrylates catalyzed by a metal-templated hydrogen bonding catalyst.” Tetrahedron Letters, vol. 56, no. 32, Aug. 2015, pp. 4653-4656. https://doi.org/10.1016/j.tetlet.2015.06.046.