ACS Catalysis, volume 6, issue 3, pages 2043-2046
Cyclobutadiene Metal Complexes: A New Class of Highly Selective Catalysts. An Application to Direct Reductive Amination
Afanasyev Oleg I
1
,
Tsygankov Alexey A.
1
,
Usanov Dmitry A.
1
,
Maleev Viktor
1
,
Kudinov Alexander R
1
,
Publication type: Journal Article
Publication date: 2016-02-22
General Chemistry
Catalysis
Abstract
A catalyst of a new type, cyclobutadiene complex [(C4Et4)Rh(p-xylene)]PF6, was found to promote selective reductive amination in the presence of carbon monoxide under mild conditions (1–3 bar, 90 °C). The reaction demonstrated perfect compatibility with a wide range of functional groups prone to reduction by conventional reducing agents. The developed system represents the first systematic investigation of cyclobutadiene metal complexes as catalysts.
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Citations by publishers
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18
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11 publications, 21.57%
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Wiley
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9 publications, 17.65%
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Thieme
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2 publications, 3.92%
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International Union of Crystallography (IUCr)
1 publication, 1.96%
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Afanasyev O. I. et al. Cyclobutadiene Metal Complexes: A New Class of Highly Selective Catalysts. An Application to Direct Reductive Amination // ACS Catalysis. 2016. Vol. 6. No. 3. pp. 2043-2046.
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Afanasyev O. I., Tsygankov A. A., Usanov D. A., Perekalin D. S., Shvydkiy N. V., Maleev V., Kudinov A. R., Chusov D. Cyclobutadiene Metal Complexes: A New Class of Highly Selective Catalysts. An Application to Direct Reductive Amination // ACS Catalysis. 2016. Vol. 6. No. 3. pp. 2043-2046.
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TY - JOUR
DO - 10.1021/acscatal.5b02916
UR - https://doi.org/10.1021%2Facscatal.5b02916
TI - Cyclobutadiene Metal Complexes: A New Class of Highly Selective Catalysts. An Application to Direct Reductive Amination
T2 - ACS Catalysis
AU - Tsygankov, Alexey A.
AU - Kudinov, Alexander R
AU - Afanasyev, Oleg I
AU - Usanov, Dmitry A.
AU - Perekalin, Dmitry S
AU - Shvydkiy, Nikita V
AU - Maleev, Viktor
AU - Chusov, Denis
PY - 2016
DA - 2016/02/22 00:00:00
PB - American Chemical Society (ACS)
SP - 2043-2046
IS - 3
VL - 6
SN - 2155-5435
ER -
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@article{2016_Afanasyev,
author = {Alexey A. Tsygankov and Alexander R Kudinov and Oleg I Afanasyev and Dmitry A. Usanov and Dmitry S Perekalin and Nikita V Shvydkiy and Viktor Maleev and Denis Chusov},
title = {Cyclobutadiene Metal Complexes: A New Class of Highly Selective Catalysts. An Application to Direct Reductive Amination},
journal = {ACS Catalysis},
year = {2016},
volume = {6},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021%2Facscatal.5b02916},
number = {3},
pages = {2043--2046},
doi = {10.1021/acscatal.5b02916}
}
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MLA
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Afanasyev, Oleg I., et al. “Cyclobutadiene Metal Complexes: A New Class of Highly Selective Catalysts. An Application to Direct Reductive Amination.” ACS Catalysis, vol. 6, no. 3, Feb. 2016, pp. 2043-2046. https://doi.org/10.1021%2Facscatal.5b02916.