Cyclobutadiene Metal Complexes: A New Class of Highly Selective Catalysts. An Application to Direct Reductive Amination
Oleg I Afanasyev
1
,
Alexey A. Tsygankov
1
,
Dmitry A. Usanov
1
,
Viktor Maleev
1
,
Alexander R Kudinov
1
,
Publication type: Journal Article
Publication date: 2016-02-22
scimago Q1
wos Q1
SJR: 3.782
CiteScore: 19.5
Impact factor: 13.1
ISSN: 21555435
General Chemistry
Catalysis
Abstract
A catalyst of a new type, cyclobutadiene complex [(C4Et4)Rh(p-xylene)]PF6, was found to promote selective reductive amination in the presence of carbon monoxide under mild conditions (1–3 bar, 90 °C). The reaction demonstrated perfect compatibility with a wide range of functional groups prone to reduction by conventional reducing agents. The developed system represents the first systematic investigation of cyclobutadiene metal complexes as catalysts.
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56
Total citations:
56
Citations from 2024:
5
(8.93%)
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GOST
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Afanasyev O. I. et al. Cyclobutadiene Metal Complexes: A New Class of Highly Selective Catalysts. An Application to Direct Reductive Amination // ACS Catalysis. 2016. Vol. 6. No. 3. pp. 2043-2046.
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Afanasyev O. I., Tsygankov A. A., Usanov D. A., Perekalin D. S., Shvydkiy N. V., Maleev V., Kudinov A. R., Chusov D. Cyclobutadiene Metal Complexes: A New Class of Highly Selective Catalysts. An Application to Direct Reductive Amination // ACS Catalysis. 2016. Vol. 6. No. 3. pp. 2043-2046.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acscatal.5b02916
UR - https://doi.org/10.1021/acscatal.5b02916
TI - Cyclobutadiene Metal Complexes: A New Class of Highly Selective Catalysts. An Application to Direct Reductive Amination
T2 - ACS Catalysis
AU - Afanasyev, Oleg I
AU - Tsygankov, Alexey A.
AU - Usanov, Dmitry A.
AU - Perekalin, Dmitry S
AU - Shvydkiy, Nikita V
AU - Maleev, Viktor
AU - Kudinov, Alexander R
AU - Chusov, Denis
PY - 2016
DA - 2016/02/22
PB - American Chemical Society (ACS)
SP - 2043-2046
IS - 3
VL - 6
SN - 2155-5435
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Afanasyev,
author = {Oleg I Afanasyev and Alexey A. Tsygankov and Dmitry A. Usanov and Dmitry S Perekalin and Nikita V Shvydkiy and Viktor Maleev and Alexander R Kudinov and Denis Chusov},
title = {Cyclobutadiene Metal Complexes: A New Class of Highly Selective Catalysts. An Application to Direct Reductive Amination},
journal = {ACS Catalysis},
year = {2016},
volume = {6},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acscatal.5b02916},
number = {3},
pages = {2043--2046},
doi = {10.1021/acscatal.5b02916}
}
Cite this
MLA
Copy
Afanasyev, Oleg I., et al. “Cyclobutadiene Metal Complexes: A New Class of Highly Selective Catalysts. An Application to Direct Reductive Amination.” ACS Catalysis, vol. 6, no. 3, Feb. 2016, pp. 2043-2046. https://doi.org/10.1021/acscatal.5b02916.