Supramolecular Design of the Trinuclear Silver(I) and Copper(I) Metal Pyrazolates Complexes with Ruthenium Sandwich Compounds via Intermolecular Metal−π Interactions
Aleksei A Titov
1, 2
,
Alexander F. Smol’yakov
1, 2
,
Oleg A. Filippov
1
,
Ivan A Godovikov
1
,
Dmitry A Muratov
1
,
Fedor Dolgushin
1
,
Lina M. epstein
1
,
Publication type: Journal Article
Publication date: 2017-11-10
scimago Q2
wos Q1
SJR: 0.633
CiteScore: 5.6
Impact factor: 3.4
ISSN: 15287483, 15287505
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
The interaction of copper(I) and silver(I) macrocyclic pyrazolates with aromatic ligands of ruthenium sandwiches (Cp*RuInd, CpRuInd, and Ind2Ru) in solution is shown for the first time. The similar mode of coordination of macrocycles to the C6 fragment of indenyl ligand was found both in the solution and in the solid state. Complexation of macrocycles with the nonencumbered sandwiches (CpRuInd, Ind2Ru) leads to the formation of infinite stacks via alternating molecules of macrocycles and sandwich compounds as one-dimensional coordination polymers with a regular structure. Coordination mode of the indenyl ligand is independent of the second part of the ruthenium sandwich as well as of the aromatic ligand coordinated to another face of the macrocycle. The general principle of macrocycle supramolecular packing suggests coordination of two ligands on both faces of the macrocycle.
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Total citations:
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Citations from 2024:
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GOST
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Titov A. A. et al. Supramolecular Design of the Trinuclear Silver(I) and Copper(I) Metal Pyrazolates Complexes with Ruthenium Sandwich Compounds via Intermolecular Metal−π Interactions // Crystal Growth and Design. 2017. Vol. 17. No. 12. pp. 6770-6779.
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Titov A. A., Smol’yakov A. F., Filippov O. A., Godovikov I. A., Muratov D. A., Dolgushin F., epstein L. M., Shubina E. S. Supramolecular Design of the Trinuclear Silver(I) and Copper(I) Metal Pyrazolates Complexes with Ruthenium Sandwich Compounds via Intermolecular Metal−π Interactions // Crystal Growth and Design. 2017. Vol. 17. No. 12. pp. 6770-6779.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.cgd.7b01351
UR - https://doi.org/10.1021/acs.cgd.7b01351
TI - Supramolecular Design of the Trinuclear Silver(I) and Copper(I) Metal Pyrazolates Complexes with Ruthenium Sandwich Compounds via Intermolecular Metal−π Interactions
T2 - Crystal Growth and Design
AU - Titov, Aleksei A
AU - Smol’yakov, Alexander F.
AU - Filippov, Oleg A.
AU - Godovikov, Ivan A
AU - Muratov, Dmitry A
AU - Dolgushin, Fedor
AU - epstein, Lina M.
AU - Shubina, Elena S.
PY - 2017
DA - 2017/11/10
PB - American Chemical Society (ACS)
SP - 6770-6779
IS - 12
VL - 17
SN - 1528-7483
SN - 1528-7505
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2017_Titov,
author = {Aleksei A Titov and Alexander F. Smol’yakov and Oleg A. Filippov and Ivan A Godovikov and Dmitry A Muratov and Fedor Dolgushin and Lina M. epstein and Elena S. Shubina},
title = {Supramolecular Design of the Trinuclear Silver(I) and Copper(I) Metal Pyrazolates Complexes with Ruthenium Sandwich Compounds via Intermolecular Metal−π Interactions},
journal = {Crystal Growth and Design},
year = {2017},
volume = {17},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/acs.cgd.7b01351},
number = {12},
pages = {6770--6779},
doi = {10.1021/acs.cgd.7b01351}
}
Cite this
MLA
Copy
Titov, Aleksei A., et al. “Supramolecular Design of the Trinuclear Silver(I) and Copper(I) Metal Pyrazolates Complexes with Ruthenium Sandwich Compounds via Intermolecular Metal−π Interactions.” Crystal Growth and Design, vol. 17, no. 12, Nov. 2017, pp. 6770-6779. https://doi.org/10.1021/acs.cgd.7b01351.