Chemistry of Materials, volume 30, issue 20, pages 7287-7295

Impact of Carbon Support Functionalization on the Electrochemical Stability of Pt Fuel Cell Catalysts

Schmies Henrike

Hornberger Elisabeth

Anke Björn

Jurzinsky Tilman ¹

Nong Hong Nhan ²

Dionigi Fabio

Kühl Stefanie

Drnec Jakub ³

Lerch Martin

Cremers Carsten ¹

Strasser Peter

Hide authors affiliations Show authors affiliations: 3 affiliations

Fraunhofer-Institut für Chemische Technologie ICT, 76327 Pfinztal, Germany |

Max Planck Institute for Chemical Energy Conversion, Stiftstr. 34-36, 45470 Mülheim an der Ruhr, Germany |

European Synchrotron Radiation Facility (ESRF), 38000 Grenoble, France |

Publication type: Journal Article

Publication date: 2018-09-24

American Chemical Society (ACS)

Journal: Chemistry of Materials

Quartile SCImago

Quartile WOS

Impact factor: 8.6

ISSN: 08974756, 15205002

DOI: 10.1021/acs.chemmater.8b03612

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Materials Chemistry

General Chemistry

General Chemical Engineering

Abstract

Nitrogen-enriched porous carbons have been discussed as supports for Pt nanoparticle catalysts deployed at cathode layers of polymer electrolyte membrane fuel cells (PEMFC). Here, we present an analysis of the chemical process of carbon surface modification using ammonolysis of preoxidized carbon blacks, and correlate their chemical structure with their catalytic activity and stability using in situ analytical techniques. Upon ammonolysis, the support materials were characterized with respect to their elemental composition, the physical surface area, and the surface zeta potential. The nature of the introduced N-functionalities was assessed by X-ray photoelectron spectroscopy. At lower ammonolysis temperatures, pyrrolic-N were invariably the most abundant surface species while at elevated treatment temperatures pyridinic-N prevailed. The corrosion stability under electrochemical conditions was assessed by in situ high-temperature differential electrochemical mass spectroscopy in a single gas diffusion lay...

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Journal of the Electrochemical Society	Journal of the Electrochemical Society, 5, 6.94% Journal of the Electrochemical Society 5 publications, 6.94%
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Applied Catalysis B: Environmental	Applied Catalysis B: Environmental, 3, 4.17% Applied Catalysis B: Environmental 3 publications, 4.17%
International Journal of Hydrogen Energy	International Journal of Hydrogen Energy, 3, 4.17% International Journal of Hydrogen Energy 3 publications, 4.17%
ACS Applied Energy Materials	ACS Applied Energy Materials, 3, 4.17% ACS Applied Energy Materials 3 publications, 4.17%
ACS Catalysis	ACS Catalysis, 2, 2.78% ACS Catalysis 2 publications, 2.78%
Nanomaterials	Nanomaterials, 2, 2.78% Nanomaterials 2 publications, 2.78%
Advanced Functional Materials	Advanced Functional Materials, 2, 2.78% Advanced Functional Materials 2 publications, 2.78%
Electrochimica Acta	Electrochimica Acta, 2, 2.78% Electrochimica Acta 2 publications, 2.78%
Chemistry of Materials	Chemistry of Materials, 2, 2.78% Chemistry of Materials 2 publications, 2.78%
ACS applied materials & interfaces	ACS applied materials & interfaces, 2, 2.78% ACS applied materials & interfaces 2 publications, 2.78%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 2, 2.78% Journal of Materials Chemistry A 2 publications, 2.78%
Nanobiotechnology Reports	Nanobiotechnology Reports, 2, 2.78% Nanobiotechnology Reports 2 publications, 2.78%
Journal of Applied Electrochemistry	Journal of Applied Electrochemistry, 1, 1.39% Journal of Applied Electrochemistry 1 publication, 1.39%
Springer Proceedings in Materials	Springer Proceedings in Materials, 1, 1.39% Springer Proceedings in Materials 1 publication, 1.39%
Energy & Fuels	Energy & Fuels, 1, 1.39% Energy & Fuels 1 publication, 1.39%
Materials	Materials, 1, 1.39% Materials 1 publication, 1.39%
Applied Sciences (Switzerland)	Applied Sciences (Switzerland), 1, 1.39% Applied Sciences (Switzerland) 1 publication, 1.39%
Nature Communications	Nature Communications, 1, 1.39% Nature Communications 1 publication, 1.39%
Nature Materials	Nature Materials, 1, 1.39% Nature Materials 1 publication, 1.39%
Journal of Fuel Chemistry and Technology	Journal of Fuel Chemistry and Technology, 1, 1.39% Journal of Fuel Chemistry and Technology 1 publication, 1.39%
Chemical Engineering Journal	Chemical Engineering Journal, 1, 1.39% Chemical Engineering Journal 1 publication, 1.39%
Progress in Natural Science: Materials International	Progress in Natural Science: Materials International, 1, 1.39% Progress in Natural Science: Materials International 1 publication, 1.39%
Journal of Electroanalytical Chemistry	Journal of Electroanalytical Chemistry, 1, 1.39% Journal of Electroanalytical Chemistry 1 publication, 1.39%
Frontiers of Chemical Science and Engineering	Frontiers of Chemical Science and Engineering, 1, 1.39% Frontiers of Chemical Science and Engineering 1 publication, 1.39%
Energies	Energies, 1, 1.39% Energies 1 publication, 1.39%
Journal of Industrial and Engineering Chemistry	Journal of Industrial and Engineering Chemistry, 1, 1.39% Journal of Industrial and Engineering Chemistry 1 publication, 1.39%
Catalysis Today	Catalysis Today, 1, 1.39% Catalysis Today 1 publication, 1.39%
	1 2 3 4 5

Citations by publishers

	2 4 6 8 10 12 14 16 18
Elsevier	Elsevier, 17, 23.61% Elsevier 17 publications, 23.61%
American Chemical Society (ACS)	American Chemical Society (ACS), 15, 20.83% American Chemical Society (ACS) 15 publications, 20.83%
Wiley	Wiley, 9, 12.5% Wiley 9 publications, 12.5%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 8, 11.11% Multidisciplinary Digital Publishing Institute (MDPI) 8 publications, 11.11%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 6, 8.33% Royal Society of Chemistry (RSC) 6 publications, 8.33%
The Electrochemical Society	The Electrochemical Society, 5, 6.94% The Electrochemical Society 5 publications, 6.94%
Springer Nature	Springer Nature, 4, 5.56% Springer Nature 4 publications, 5.56%
Pleiades Publishing	Pleiades Publishing, 2, 2.78% Pleiades Publishing 2 publications, 2.78%
Higher Education Press	Higher Education Press, 1, 1.39% Higher Education Press 1 publication, 1.39%
Korean Society of Industrial Engineering Chemistry	Korean Society of Industrial Engineering Chemistry, 1, 1.39% Korean Society of Industrial Engineering Chemistry 1 publication, 1.39%
SAE International	SAE International, 1, 1.39% SAE International 1 publication, 1.39%
	2 4 6 8 10 12 14 16 18

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Schmies H. et al. Impact of Carbon Support Functionalization on the Electrochemical Stability of Pt Fuel Cell Catalysts // Chemistry of Materials. 2018. Vol. 30. No. 20. pp. 7287-7295.

GOST all authors (up to 50) Copy

Schmies H., Hornberger E., Anke B., Jurzinsky T., Nong H. N., Dionigi F., Kühl S., Drnec J., Lerch M., Cremers C., Strasser P. Impact of Carbon Support Functionalization on the Electrochemical Stability of Pt Fuel Cell Catalysts // Chemistry of Materials. 2018. Vol. 30. No. 20. pp. 7287-7295.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1021/acs.chemmater.8b03612

UR - https://doi.org/10.1021%2Facs.chemmater.8b03612

TI - Impact of Carbon Support Functionalization on the Electrochemical Stability of Pt Fuel Cell Catalysts

T2 - Chemistry of Materials

AU - Anke, Björn

AU - Jurzinsky, Tilman

AU - Lerch, Martin

AU - Strasser, Peter

AU - Schmies, Henrike

AU - Hornberger, Elisabeth

AU - Nong, Hong Nhan

AU - Dionigi, Fabio

AU - Kühl, Stefanie

AU - Drnec, Jakub

AU - Cremers, Carsten

PY - 2018

DA - 2018/09/24 00:00:00

PB - American Chemical Society (ACS)

SP - 7287-7295

IS - 20

VL - 30

SN - 0897-4756

SN - 1520-5002

ER -

BibTex |

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BibTex Copy

@article{2018_Schmies,

author = {Björn Anke and Tilman Jurzinsky and Martin Lerch and Peter Strasser and Henrike Schmies and Elisabeth Hornberger and Hong Nhan Nong and Fabio Dionigi and Stefanie Kühl and Jakub Drnec and Carsten Cremers},

title = {Impact of Carbon Support Functionalization on the Electrochemical Stability of Pt Fuel Cell Catalysts},

journal = {Chemistry of Materials},

year = {2018},

volume = {30},

publisher = {American Chemical Society (ACS)},

month = {sep},

url = {https://doi.org/10.1021%2Facs.chemmater.8b03612},

number = {20},

pages = {7287--7295},

doi = {10.1021/acs.chemmater.8b03612}

}

MLA

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MLA Copy

Schmies, Henrike, et al. “Impact of Carbon Support Functionalization on the Electrochemical Stability of Pt Fuel Cell Catalysts.” Chemistry of Materials, vol. 30, no. 20, Sep. 2018, pp. 7287-7295. https://doi.org/10.1021%2Facs.chemmater.8b03612.

Found error?

Publisher

American Chemical Society (ACS)

Journal

Chemistry of Materials

Quartile SCImago

Quartile WOS

Impact factor

8.6

ISSN

08974756 (Print)
15205002 (Electronic)

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