o-Silylaryl Triflates: A Journey of Kobayashi Aryne Precursors
Publication type: Journal Article
Publication date: 2021-02-18
scimago Q1
wos Q1
SJR: 16.455
CiteScore: 100.5
Impact factor: 55.8
ISSN: 00092665, 15206890
PubMed ID:
33599472
General Chemistry
Abstract
Arynes are among the most active organic intermediates and have found numerous applications in expeditious preparation of substituted arenes. In the past 20 years, chemists have witnessed a resurgence in aryne chemistry, which is mainly attributed by the extensive utilization of Kobayashi's method, a fluoride-induced removal of the TMS group with concomitant departure of its ortho OTf group on o-silylaryl triflates. Nowadays, o-silylaryl triflates are the most frequently employed aryne precursors. This review provides an overview of the history of Kobayashi's method, its methodological achievements, and its applications in the synthesis of natural products, bioactive molecules, and polycyclic aromatic hydrocarbons.
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335
Total citations:
335
Citations from 2024:
165
(49.4%)
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Shi J., Li L., Li Y. o-Silylaryl Triflates: A Journey of Kobayashi Aryne Precursors // Chemical Reviews. 2021. Vol. 121. No. 7. pp. 3892-4044.
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Shi J., Li L., Li Y. o-Silylaryl Triflates: A Journey of Kobayashi Aryne Precursors // Chemical Reviews. 2021. Vol. 121. No. 7. pp. 3892-4044.
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TY - JOUR
DO - 10.1021/acs.chemrev.0c01011
UR - https://doi.org/10.1021/acs.chemrev.0c01011
TI - o-Silylaryl Triflates: A Journey of Kobayashi Aryne Precursors
T2 - Chemical Reviews
AU - Shi, Jiarong
AU - Li, Lianggui
AU - Li, Yang
PY - 2021
DA - 2021/02/18
PB - American Chemical Society (ACS)
SP - 3892-4044
IS - 7
VL - 121
PMID - 33599472
SN - 0009-2665
SN - 1520-6890
ER -
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BibTex (up to 50 authors)
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@article{2021_Shi,
author = {Jiarong Shi and Lianggui Li and Yang Li},
title = {o-Silylaryl Triflates: A Journey of Kobayashi Aryne Precursors},
journal = {Chemical Reviews},
year = {2021},
volume = {121},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acs.chemrev.0c01011},
number = {7},
pages = {3892--4044},
doi = {10.1021/acs.chemrev.0c01011}
}
Cite this
MLA
Copy
Shi, Jiarong, et al. “o-Silylaryl Triflates: A Journey of Kobayashi Aryne Precursors.” Chemical Reviews, vol. 121, no. 7, Feb. 2021, pp. 3892-4044. https://doi.org/10.1021/acs.chemrev.0c01011.