Chemical Reviews, volume 119, issue 4, pages 2524-2549
3d-Metal Catalyzed N- and C-Alkylation Reactions via Borrowing Hydrogen or Hydrogen Autotransfer
Publication type: Journal Article
Publication date: 2018-11-20
Journal:
Chemical Reviews
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 62.1
ISSN: 00092665, 15206890
General Chemistry
Abstract
The conservation of our element resources is a fundamental challenge of mankind. The development of alcohol refunctionalization reactions is a possible fossil carbon conservation strategy since alcohols can be obtained from indigestible and abundantly available biomass. The conservation of our rare noble metals, frequently used in key technologies such as catalysis, might be feasible by replacing them with highly abundant metals. The alkylation of amines by alcohols and related C-C coupling reactions are early examples of alcohol refunctionalization reactions. These reactions follow mostly the borrowing hydrogen or hydrogen autotransfer catalysis concept, and many 3d-metal catalysts have been disclosed in recent years. In this review, we summarize the progress made in developing Cu, Ni, Co, Fe, and Mn catalysts for C-N and C-C bond formation reactions with alcohols and amines using the borrowing hydrogen or hydrogen autotransfer concept. We expect that the findings in this field will inspire others to develop new efficient and selective earth-abundant metal catalysts for borrowing hydrogen or hydrogen autotransfer applications or to develop novel alcohol refunctionalization reactions that can be mediated by such metals.
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Irrgang T., Kempe R. 3d-Metal Catalyzed N- and C-Alkylation Reactions via Borrowing Hydrogen or Hydrogen Autotransfer // Chemical Reviews. 2018. Vol. 119. No. 4. pp. 2524-2549.
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Irrgang T., Kempe R. 3d-Metal Catalyzed N- and C-Alkylation Reactions via Borrowing Hydrogen or Hydrogen Autotransfer // Chemical Reviews. 2018. Vol. 119. No. 4. pp. 2524-2549.
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TY - JOUR
DO - 10.1021/acs.chemrev.8b00306
UR - https://doi.org/10.1021/acs.chemrev.8b00306
TI - 3d-Metal Catalyzed N- and C-Alkylation Reactions via Borrowing Hydrogen or Hydrogen Autotransfer
T2 - Chemical Reviews
AU - Kempe, Rhett
AU - Irrgang, Torsten
PY - 2018
DA - 2018/11/20 00:00:00
PB - American Chemical Society (ACS)
SP - 2524-2549
IS - 4
VL - 119
SN - 0009-2665
SN - 1520-6890
ER -
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@article{2018_Irrgang,
author = {Rhett Kempe and Torsten Irrgang},
title = {3d-Metal Catalyzed N- and C-Alkylation Reactions via Borrowing Hydrogen or Hydrogen Autotransfer},
journal = {Chemical Reviews},
year = {2018},
volume = {119},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/acs.chemrev.8b00306},
number = {4},
pages = {2524--2549},
doi = {10.1021/acs.chemrev.8b00306}
}
Cite this
MLA
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Irrgang, Torsten, and Rhett Kempe. “3d-Metal Catalyzed N- and C-Alkylation Reactions via Borrowing Hydrogen or Hydrogen Autotransfer.” Chemical Reviews, vol. 119, no. 4, Nov. 2018, pp. 2524-2549. https://doi.org/10.1021/acs.chemrev.8b00306.