Cation-Induced Dimerization of Heteroleptic Crown-Substituted Trisphthalocyaninates as Revealed by X-ray Diffraction and NMR Spectroscopy
Georgy S Berezhnoy
2
,
Anna A Sinelshchikova
1
,
Fedor Dolgushin
3
,
Fedor M. Dolgushin
3
,
Kirill P. Birin
1
,
Gayane Kirakosyan
1, 2
,
Gayane A. Kirakosyan
1, 2
,
Yulia G. Gorbunova
1, 2
,
Aslan Tsivadze
1, 2
,
Aslan Yu. Tsivadze
1, 2
Publication type: Journal Article
Publication date: 2020-06-19
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
32559093
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
We report comprehensive X-ray diffraction and NMR studies of potassium-induced dimerization of heteroleptic triple-decker crown-phthalocyaninates [(15C5)4Pc]M(Pc)M(Pc) (1M, M = Y and Tb). Characterization of the crystalline dimer 2(1Y)·4KBPh4·12CH3CN·10CHCl3 gave the first structural evidence of the formation of a six-decker structure with four rare earth metal ions perfectly aligned near the symmetry axis. NMR studies of soluble supramolecular dimers 2(1M)·4KOAc provided a spectral-structural model that allowed us to assign the NMR spectra of related complexes with paramagnetic lanthanides and to further evaluate their structure and long-range interaction between the Ln(III) centers in multinuclear tetrapyrrolic complexes. The obtained results are promising for elaboration of new supramolecular magnetic materials.
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Martynov A. G. et al. Cation-Induced Dimerization of Heteroleptic Crown-Substituted Trisphthalocyaninates as Revealed by X-ray Diffraction and NMR Spectroscopy // Inorganic Chemistry. 2020. Vol. 59. No. 13. pp. 9424-9433.
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Martynov A. G., Polovkova M. A., Berezhnoy G. S., Sinelshchikova A., Sinelshchikova A. A., Dolgushin F., Dolgushin F. M., Birin K. P., Kirakosyan G., Kirakosyan G. A., Gorbunova Y. G., Tsivadze A., Tsivadze A. Y. Cation-Induced Dimerization of Heteroleptic Crown-Substituted Trisphthalocyaninates as Revealed by X-ray Diffraction and NMR Spectroscopy // Inorganic Chemistry. 2020. Vol. 59. No. 13. pp. 9424-9433.
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RIS
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TY - JOUR
DO - 10.1021/acs.inorgchem.0c01346
UR - https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c01346
TI - Cation-Induced Dimerization of Heteroleptic Crown-Substituted Trisphthalocyaninates as Revealed by X-ray Diffraction and NMR Spectroscopy
T2 - Inorganic Chemistry
AU - Martynov, Alexander G.
AU - Polovkova, Marina A
AU - Berezhnoy, Georgy S
AU - Sinelshchikova, Anna
AU - Sinelshchikova, Anna A
AU - Dolgushin, Fedor
AU - Dolgushin, Fedor M.
AU - Birin, Kirill P.
AU - Kirakosyan, Gayane
AU - Kirakosyan, Gayane A.
AU - Gorbunova, Yulia G.
AU - Tsivadze, Aslan
AU - Tsivadze, Aslan Yu.
PY - 2020
DA - 2020/06/19
PB - American Chemical Society (ACS)
SP - 9424-9433
IS - 13
VL - 59
PMID - 32559093
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2020_Martynov,
author = {Alexander G. Martynov and Marina A Polovkova and Georgy S Berezhnoy and Anna Sinelshchikova and Anna A Sinelshchikova and Fedor Dolgushin and Fedor M. Dolgushin and Kirill P. Birin and Gayane Kirakosyan and Gayane A. Kirakosyan and Yulia G. Gorbunova and Aslan Tsivadze and Aslan Yu. Tsivadze},
title = {Cation-Induced Dimerization of Heteroleptic Crown-Substituted Trisphthalocyaninates as Revealed by X-ray Diffraction and NMR Spectroscopy},
journal = {Inorganic Chemistry},
year = {2020},
volume = {59},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c01346},
number = {13},
pages = {9424--9433},
doi = {10.1021/acs.inorgchem.0c01346}
}
Cite this
MLA
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Martynov, Alexander G., et al. “Cation-Induced Dimerization of Heteroleptic Crown-Substituted Trisphthalocyaninates as Revealed by X-ray Diffraction and NMR Spectroscopy.” Inorganic Chemistry, vol. 59, no. 13, Jun. 2020, pp. 9424-9433. https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c01346.