Inorganic Chemistry

, том 61 , издание 3 , страницы 1264-1269

Using N-Heterocyclic Carbenes as Weak Equatorial Ligands to Design Single-Molecule Magnets: Zero-Field Slow Relaxation in Two Octahedral Dysprosium(III) Complexes

Тип публикации: Journal Article

Дата публикации: 2022-01-07

American Chemical Society (ACS)

Inorganic Chemistry

SCImago Q1

WOS Q1

БС1

SJR: 0.879

CiteScore: 7.5

Impact factor: 4.6

ISSN: 00201669, 1520510X

DOI: 10.1021/acs.inorgchem.1c03429

Скопировать DOI

PubMed ID: 34994542

Inorganic Chemistry

Physical and Theoretical Chemistry

Краткое описание

We report the synthesis, structures, and magnetic investigations of two new octahedral dysprosium complexes, based on the original N-heterocyclic carbene (NHC) tridentate bis(phenoxide) ligand, of the respective formulas mer-[DyL(THF)2Cl] (1) and mer-[DyL(THF)3][BPh4] (2), where L = 1,3-bis(3,5-di-tert-butyl-2-oxidophenyl)-5,5-dimethyl-3,4,5,6-tetrahydropyrimidin-1-ium chloride and THF = tetrahydrofuran. The short Dy-O distances in the axial direction in association with the weak donor ability of the NHC moiety provide a suitable environment for slow relaxation of magnetization, overcoming the previous single-molecule magnets based on NHC ligands.

Для доступа к списку цитирований публикации необходимо авторизоваться.

Войти с ORCID

Для доступа к списку профилей, цитирующих публикацию, необходимо авторизоваться.

Войти с ORCID

Топ-30

Журналы

	1 2
Chemistry - A European Journal	Chemistry - A European Journal, 2, 10% Chemistry - A European Journal 2 публикации, 10%
Coordination Chemistry Reviews	Coordination Chemistry Reviews, 2, 10% Coordination Chemistry Reviews 2 публикации, 10%
Journal of Molecular Structure	Journal of Molecular Structure, 2, 10% Journal of Molecular Structure 2 публикации, 10%
Dalton Transactions	Dalton Transactions, 2, 10% Dalton Transactions 2 публикации, 10%
CrystEngComm	CrystEngComm, 1, 5% CrystEngComm 1 публикация, 5%
Organometallics	Organometallics, 1, 5% Organometallics 1 публикация, 5%
European Journal of Inorganic Chemistry	European Journal of Inorganic Chemistry, 1, 5% European Journal of Inorganic Chemistry 1 публикация, 5%
Catalysts	Catalysts, 1, 5% Catalysts 1 публикация, 5%
Chemistry - An Asian Journal	Chemistry - An Asian Journal, 1, 5% Chemistry - An Asian Journal 1 публикация, 5%
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 1, 5% Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya 1 публикация, 5%
Inorganic Chemistry Frontiers	Inorganic Chemistry Frontiers, 1, 5% Inorganic Chemistry Frontiers 1 публикация, 5%
Mendeleev Communications	Mendeleev Communications, 1, 5% Mendeleev Communications 1 публикация, 5%
ChemistryEurope	ChemistryEurope, 1, 5% ChemistryEurope 1 публикация, 5%
New Journal of Chemistry	New Journal of Chemistry, 1, 5% New Journal of Chemistry 1 публикация, 5%
Crystal Growth and Design	Crystal Growth and Design, 1, 5% Crystal Growth and Design 1 публикация, 5%
	1 2

Издатели

	1 2 3 4 5
Wiley	Wiley, 5, 25% Wiley 5 публикаций, 25%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 5, 25% Royal Society of Chemistry (RSC) 5 публикаций, 25%
Elsevier	Elsevier, 5, 25% Elsevier 5 публикаций, 25%
American Chemical Society (ACS)	American Chemical Society (ACS), 2, 10% American Chemical Society (ACS) 2 публикации, 10%
MDPI	MDPI, 1, 5% MDPI 1 публикация, 5%
Pleiades Publishing	Pleiades Publishing, 1, 5% Pleiades Publishing 1 публикация, 5%
OOO Zhurnal "Mendeleevskie Soobshcheniya"	OOO Zhurnal "Mendeleevskie Soobshcheniya", 1, 5% OOO Zhurnal "Mendeleevskie Soobshcheniya" 1 публикация, 5%
	1 2 3 4 5

Мы не учитываем публикации, у которых нет DOI.
Статистика публикаций обновляется еженедельно.

Вы ученый?

Создайте профиль, чтобы получать персональные рекомендации коллег, конференций и новых статей.

Войти с ORCID

Метрики

Цитировать

ГОСТ |

Цитировать

ГОСТ Скопировать

Long J. et al. Using N-Heterocyclic Carbenes as Weak Equatorial Ligands to Design Single-Molecule Magnets: Zero-Field Slow Relaxation in Two Octahedral Dysprosium(III) Complexes // Inorganic Chemistry. 2022. Vol. 61. No. 3. pp. 1264-1269.

ГОСТ со всеми авторами (до 50) Скопировать

Long J., Lyubov D. M., Gurina G. A., Nelyubina Y. V., Salles F., Guari Y., Larionova J., Trifonov A. A. Using N-Heterocyclic Carbenes as Weak Equatorial Ligands to Design Single-Molecule Magnets: Zero-Field Slow Relaxation in Two Octahedral Dysprosium(III) Complexes // Inorganic Chemistry. 2022. Vol. 61. No. 3. pp. 1264-1269.

RIS |

Цитировать

RIS Скопировать

TY - JOUR

DO - 10.1021/acs.inorgchem.1c03429

UR - https://pubs.acs.org/doi/10.1021/acs.inorgchem.1c03429

TI - Using N-Heterocyclic Carbenes as Weak Equatorial Ligands to Design Single-Molecule Magnets: Zero-Field Slow Relaxation in Two Octahedral Dysprosium(III) Complexes

T2 - Inorganic Chemistry

AU - Long, Jérôme

AU - Lyubov, D M

AU - Gurina, Galina A

AU - Nelyubina, Yulia V.

AU - Salles, Fabrice

AU - Guari, Yannick

AU - Larionova, Joulia

AU - Trifonov, Alexander A.

PY - 2022

DA - 2022/01/07

PB - American Chemical Society (ACS)

SP - 1264-1269

IS - 3

VL - 61

PMID - 34994542

SN - 0020-1669

SN - 1520-510X

ER -

BibTex |

Цитировать

BibTex (до 50 авторов) Скопировать

@article{2022_Long,

author = {Jérôme Long and D M Lyubov and Galina A Gurina and Yulia V. Nelyubina and Fabrice Salles and Yannick Guari and Joulia Larionova and Alexander A. Trifonov},

title = {Using N-Heterocyclic Carbenes as Weak Equatorial Ligands to Design Single-Molecule Magnets: Zero-Field Slow Relaxation in Two Octahedral Dysprosium(III) Complexes},

journal = {Inorganic Chemistry},

year = {2022},

volume = {61},

publisher = {American Chemical Society (ACS)},

month = {jan},

url = {https://pubs.acs.org/doi/10.1021/acs.inorgchem.1c03429},

number = {3},

pages = {1264--1269},

doi = {10.1021/acs.inorgchem.1c03429}

}

MLA

Цитировать

MLA Скопировать

Long, Jérôme, et al. “Using N-Heterocyclic Carbenes as Weak Equatorial Ligands to Design Single-Molecule Magnets: Zero-Field Slow Relaxation in Two Octahedral Dysprosium(III) Complexes.” Inorganic Chemistry, vol. 61, no. 3, Jan. 2022, pp. 1264-1269. https://pubs.acs.org/doi/10.1021/acs.inorgchem.1c03429.

Издатель

American Chemical Society (ACS)

Журнал

Inorganic Chemistry

SCImago Q1

WOS Q1

БС1