Inorganic Chemistry

, volume 61 , issue 3 , pages 1264-1269

Using N-Heterocyclic Carbenes as Weak Equatorial Ligands to Design Single-Molecule Magnets: Zero-Field Slow Relaxation in Two Octahedral Dysprosium(III) Complexes

Jérôme Long ^{1, 2}

D M Lyubov ^{3, 4}

Galina A Gurina ⁴

Yulia V. Nelyubina ³

Fabrice Salles ¹

Yannick Guari ¹

Joulia Larionova ¹

Alexander A. Trifonov ^{3, 4}

Hide authors affiliations Show authors affiliations: 4 affiliations

ICGM, Univ. Montpellier, CNRS, ENSCM, 34095 Montpellier, France |

Institut Universitaire de France, 1 rue Descartes, 75231 Paris cedex 05, France |

Nesmeyanov Institute of Organoelement Compounds (INEOS), Russian Academy of Sciences (RAS), 28 Vavilova str., 119334 Moscow, Russia |

⁴

Institute of Organometallic Chemistry, Russian Academy of Sciences (RAS), 49 Tropinina str., GSP-445, 630950 Nizhny, Novgorod, Russia |

Publication type: Journal Article

Publication date: 2022-01-07

American Chemical Society (ACS)

Inorganic Chemistry

scimago Q1

wos Q1

SJR: 0.958

CiteScore: 7.4

Impact factor: 4.7

ISSN: 00201669, 1520510X

DOI: 10.1021/acs.inorgchem.1c03429

Copy DOI

PubMed ID: 34994542

Inorganic Chemistry

Physical and Theoretical Chemistry

Abstract

We report the synthesis, structures, and magnetic investigations of two new octahedral dysprosium complexes, based on the original N-heterocyclic carbene (NHC) tridentate bis(phenoxide) ligand, of the respective formulas mer-[DyL(THF)2Cl] (1) and mer-[DyL(THF)3][BPh4] (2), where L = 1,3-bis(3,5-di-tert-butyl-2-oxidophenyl)-5,5-dimethyl-3,4,5,6-tetrahydropyrimidin-1-ium chloride and THF = tetrahydrofuran. The short Dy-O distances in the axial direction in association with the weak donor ability of the NHC moiety provide a suitable environment for slow relaxation of magnetization, overcoming the previous single-molecule magnets based on NHC ligands.

Found

2 citations

Sakhapov Ilyas

🥼 🤝

PhD in Chemistry

44 publications, 351 citations

h-index: 12

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Research interests

Electrochemistry

Green chemistry

2 citations

Kagilev Alexey

32 publications, 384 citations

h-index: 11

Kazan Federal University

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Kazan Scientific Center of the Russian Academy of Sciences

1 citation

Cherkasov Anton

245 publications, 3 654 citations

h-index: 30

G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences

Research interests

Coordination Chemistry

1 citation

Gafurov Zufar

🤝

PhD in Chemistry

47 publications, 632 citations

h-index: 17

Kazan Federal University

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Research interests

Catalysis

Coordination Chemistry

Electrochemistry

Organometallic Chemistry

1 citation

Kantyukov Artyom

32 publications, 418 citations

h-index: 11

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Kazan Federal University

1 citation

Mikhailov Ilya

16 publications, 112 citations

h-index: 6

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Kazan Federal University

1 citation

Selikhov Aleksander

PhD in Chemistry

32 publications, 403 citations

h-index: 10

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences

Research interests

Chemistry of organic and organoelement compounds; chemistry of polymers; production of materials

Organic chemistry

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Long J. et al. Using N-Heterocyclic Carbenes as Weak Equatorial Ligands to Design Single-Molecule Magnets: Zero-Field Slow Relaxation in Two Octahedral Dysprosium(III) Complexes // Inorganic Chemistry. 2022. Vol. 61. No. 3. pp. 1264-1269.

GOST all authors (up to 50) Copy

Long J., Lyubov D. M., Gurina G. A., Nelyubina Y. V., Salles F., Guari Y., Larionova J., Trifonov A. A. Using N-Heterocyclic Carbenes as Weak Equatorial Ligands to Design Single-Molecule Magnets: Zero-Field Slow Relaxation in Two Octahedral Dysprosium(III) Complexes // Inorganic Chemistry. 2022. Vol. 61. No. 3. pp. 1264-1269.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/acs.inorgchem.1c03429

UR - https://doi.org/10.1021/acs.inorgchem.1c03429

TI - Using N-Heterocyclic Carbenes as Weak Equatorial Ligands to Design Single-Molecule Magnets: Zero-Field Slow Relaxation in Two Octahedral Dysprosium(III) Complexes

T2 - Inorganic Chemistry

AU - Long, Jérôme

AU - Lyubov, D M

AU - Gurina, Galina A

AU - Nelyubina, Yulia V.

AU - Salles, Fabrice

AU - Guari, Yannick

AU - Larionova, Joulia

AU - Trifonov, Alexander A.

PY - 2022

DA - 2022/01/07

PB - American Chemical Society (ACS)

SP - 1264-1269

IS - 3

VL - 61

PMID - 34994542

SN - 0020-1669

SN - 1520-510X

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2022_Long,

author = {Jérôme Long and D M Lyubov and Galina A Gurina and Yulia V. Nelyubina and Fabrice Salles and Yannick Guari and Joulia Larionova and Alexander A. Trifonov},

title = {Using N-Heterocyclic Carbenes as Weak Equatorial Ligands to Design Single-Molecule Magnets: Zero-Field Slow Relaxation in Two Octahedral Dysprosium(III) Complexes},

journal = {Inorganic Chemistry},

year = {2022},

volume = {61},

publisher = {American Chemical Society (ACS)},

month = {jan},

url = {https://doi.org/10.1021/acs.inorgchem.1c03429},

number = {3},

pages = {1264--1269},

doi = {10.1021/acs.inorgchem.1c03429}

}

MLA

Cite this

MLA Copy

Long, Jérôme, et al. “Using N-Heterocyclic Carbenes as Weak Equatorial Ligands to Design Single-Molecule Magnets: Zero-Field Slow Relaxation in Two Octahedral Dysprosium(III) Complexes.” Inorganic Chemistry, vol. 61, no. 3, Jan. 2022, pp. 1264-1269. https://doi.org/10.1021/acs.inorgchem.1c03429.

Publisher

American Chemical Society (ACS)

Journal

Inorganic Chemistry

scimago Q1

wos Q1

SJR

0.958

CiteScore

7.4

Impact factor

4.7

ISSN

00201669 (Print)

1520510X (Electronic)

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