Inorganic Chemistry, volume 61, issue 18, pages 6773-6784
Efficient Synthesis of WB5–x–WB2 Powders with Selectivity for WB5–x Content
Publication type: Journal Article
Publication date: 2022-04-27
Journal:
Inorganic Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
We proposed an efficient method toward the synthesis of higher tungsten boride WB5-x in the vacuumless direct current atmospheric arc discharge plasma. The crystal structure of the synthesized samples of boron-rich tungsten boride was determined using computational techniques, showing a two-phase system. The ab initio calculations of the energies of various structures with similar X-ray diffraction (XRD) patterns allowed us to determine the composition of the formed higher tungsten boride. We determined the optimal parameters of synthesis to obtain samples with 61.5% WB5-x by volume. The transmission electron microscopy measurements showed that 90% of the particles have sizes of up to 100 nm, whereas the rest of them may have sizes from 125 to 225 nm. Our study shows the possibility of using the proposed vacuumless method as an efficient and inexpensive way to synthesize superhard WB5-x without employing resource-consuming vacuum techniques.
Citations by journals
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1
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Inorganic Chemistry
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Inorganic Chemistry
1 publication, 33.33%
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Journal of Materials Chemistry A
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Journal of Materials Chemistry A
1 publication, 33.33%
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Composites Part B: Engineering
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Composites Part B: Engineering
1 publication, 33.33%
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1
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Citations by publishers
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1
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American Chemical Society (ACS)
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American Chemical Society (ACS)
1 publication, 33.33%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
1 publication, 33.33%
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Elsevier
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Elsevier
1 publication, 33.33%
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1
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Pak A. Ya. et al. Efficient Synthesis of WB5–x–WB2 Powders with Selectivity for WB5–x Content // Inorganic Chemistry. 2022. Vol. 61. No. 18. pp. 6773-6784.
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Pak A. Ya., Rybkovskiy D. V., Vassilyeva Y. Z., Kolobova E. N., Filimonenko A. V., Kvashnin A. G. Efficient Synthesis of WB5–x–WB2 Powders with Selectivity for WB5–x Content // Inorganic Chemistry. 2022. Vol. 61. No. 18. pp. 6773-6784.
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TY - JOUR
DO - 10.1021/acs.inorgchem.1c03880
UR - https://doi.org/10.1021%2Facs.inorgchem.1c03880
TI - Efficient Synthesis of WB5–x–WB2 Powders with Selectivity for WB5–x Content
T2 - Inorganic Chemistry
AU - Kolobova, Ekaterina N
AU - Filimonenko, Alexander V
AU - Pak, Alexander Ya
AU - Vassilyeva, Yuliya Z
AU - Rybkovskiy, Dmitry V.
AU - Kvashnin, Alexander G.
PY - 2022
DA - 2022/04/27 00:00:00
PB - American Chemical Society (ACS)
SP - 6773-6784
IS - 18
VL - 61
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2022_Pak,
author = {Ekaterina N Kolobova and Alexander V Filimonenko and Alexander Ya Pak and Yuliya Z Vassilyeva and Dmitry V. Rybkovskiy and Alexander G. Kvashnin},
title = {Efficient Synthesis of WB5–x–WB2 Powders with Selectivity for WB5–x Content},
journal = {Inorganic Chemistry},
year = {2022},
volume = {61},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021%2Facs.inorgchem.1c03880},
number = {18},
pages = {6773--6784},
doi = {10.1021/acs.inorgchem.1c03880}
}
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Pak, Alexander Ya., et al. “Efficient Synthesis of WB5–x–WB2 Powders with Selectivity for WB5–x Content.” Inorganic Chemistry, vol. 61, no. 18, Apr. 2022, pp. 6773-6784. https://doi.org/10.1021%2Facs.inorgchem.1c03880.