Inorganic Chemistry, volume 62, issue 1, pages 487-496
Solvation-Anionic Exchange Mechanism of Solvent Extraction: Enhanced U(VI) Uptake by Tetradentate Phenanthroline Ligands
Matveev Petr I
1
,
Lemport Pavel S
1
,
Novichkov Daniil A
1
,
Gloriozov Igor P.
1
,
Avagyan Nane A
1
,
Gudovannyy Alexey O
1
,
Roznyatovsky Vitaly A.
1
,
Lyssenko Konstantin A.
1, 3
,
Ustynyuk Yuri A.
1
,
Publication type: Journal Article
Publication date: 2022-12-21
Journal:
Inorganic Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Phenanthroline diamides (L) demonstrated a unique ability to extract uranium from nitric acid solutions into a polar organic solvent forming complexes of 1:2 stoichiometry as tight ion pairs {[UO2LNO3]+[UO2(NO3)3]−} by a novel extraction mechanism, which is a combination of two already well-known mechanisms: solvation and ion-pair anion exchange. A UV–vis study was used to confirm the formation of such complexes directly in the organic phase. Moreover, chemical synthesis and single crystal growth were performed to confirm unambiguously the structure of the complexes in the solid state.
Citations by journals
|
1
2
|
|
|
Inorganic Chemistry
|
Inorganic Chemistry
2 publications, 50%
|
|
International Journal of Molecular Sciences
|
International Journal of Molecular Sciences
1 publication, 25%
|
|
Dalton Transactions
|
Dalton Transactions
1 publication, 25%
|
|
1
2
|
Citations by publishers
|
1
2
|
|
|
American Chemical Society (ACS)
|
American Chemical Society (ACS)
2 publications, 50%
|
|
Multidisciplinary Digital Publishing Institute (MDPI)
|
Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 25%
|
|
Royal Society of Chemistry (RSC)
|
Royal Society of Chemistry (RSC)
1 publication, 25%
|
|
1
2
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2023,2024],"ids":[0,0],"codes":[0,0],"imageUrls":["",""],"datasets":[{"label":"Citations number","data":[2,2],"backgroundColor":["#3B82F6","#3B82F6"],"percentage":["50","50"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Inorganic Chemistry","International Journal of Molecular Sciences","Dalton Transactions"],"ids":[24714,14627,8473],"codes":[0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp"],"datasets":[{"label":"","data":[2,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6"],"percentage":[50,25,25],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["American Chemical Society (ACS)","Multidisciplinary Digital Publishing Institute (MDPI)","Royal Society of Chemistry (RSC)"],"ids":[40,202,123],"codes":[0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp"],"datasets":[{"label":"","data":[2,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6"],"percentage":[50,25,25],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Gutorova S. V. et al. Solvation-Anionic Exchange Mechanism of Solvent Extraction: Enhanced U(VI) Uptake by Tetradentate Phenanthroline Ligands // Inorganic Chemistry. 2022. Vol. 62. No. 1. pp. 487-496.
GOST all authors (up to 50)
Copy
Gutorova S. V., Matveev P. I., Lemport P. S., Novichkov D. A., Gloriozov I. P., Avagyan N. A., Gudovannyy A. O., Nelyubina Y. V., Roznyatovsky V. A., Petrov V. G., Lyssenko K. A., Ustynyuk Y. A., Kalmykov S. N., Nenajdenko V. G. Solvation-Anionic Exchange Mechanism of Solvent Extraction: Enhanced U(VI) Uptake by Tetradentate Phenanthroline Ligands // Inorganic Chemistry. 2022. Vol. 62. No. 1. pp. 487-496.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.inorgchem.2c03571
UR - https://doi.org/10.1021%2Facs.inorgchem.2c03571
TI - Solvation-Anionic Exchange Mechanism of Solvent Extraction: Enhanced U(VI) Uptake by Tetradentate Phenanthroline Ligands
T2 - Inorganic Chemistry
AU - Gutorova, Svetlana V
AU - Matveev, Petr I
AU - Lemport, Pavel S
AU - Novichkov, Daniil A
AU - Gloriozov, Igor P.
AU - Avagyan, Nane A
AU - Gudovannyy, Alexey O
AU - Nelyubina, Yulia V.
AU - Roznyatovsky, Vitaly A.
AU - Petrov, Vladimir G
AU - Lyssenko, Konstantin A.
AU - Ustynyuk, Yuri A.
AU - Kalmykov, Stepan N.
AU - Nenajdenko, Valentine G.
PY - 2022
DA - 2022/12/21 00:00:00
PB - American Chemical Society (ACS)
SP - 487-496
IS - 1
VL - 62
SN - 0020-1669
SN - 1520-510X
ER -
Cite this
BibTex
Copy
@article{2022_Gutorova,
author = {Svetlana V Gutorova and Petr I Matveev and Pavel S Lemport and Daniil A Novichkov and Igor P. Gloriozov and Nane A Avagyan and Alexey O Gudovannyy and Yulia V. Nelyubina and Vitaly A. Roznyatovsky and Vladimir G Petrov and Konstantin A. Lyssenko and Yuri A. Ustynyuk and Stepan N. Kalmykov and Valentine G. Nenajdenko},
title = {Solvation-Anionic Exchange Mechanism of Solvent Extraction: Enhanced U(VI) Uptake by Tetradentate Phenanthroline Ligands},
journal = {Inorganic Chemistry},
year = {2022},
volume = {62},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021%2Facs.inorgchem.2c03571},
number = {1},
pages = {487--496},
doi = {10.1021/acs.inorgchem.2c03571}
}
Cite this
MLA
Copy
Gutorova, Svetlana V., et al. “Solvation-Anionic Exchange Mechanism of Solvent Extraction: Enhanced U(VI) Uptake by Tetradentate Phenanthroline Ligands.” Inorganic Chemistry, vol. 62, no. 1, Dec. 2022, pp. 487-496. https://doi.org/10.1021%2Facs.inorgchem.2c03571.