Phosphorus(V) Porphyrin-Based Molecular Turnstiles
Ivan B Meshkov
1, 2
,
Ivan N Meshkov
1, 3
,
Véronique Bulach
1
,
Yulia G. Gorbunova
2, 4
,
N. Kyritsakas
1
,
Nathalie Kyritsakas
1
,
Aslan Tsivadze
2, 4
,
Aslan Yu. Tsivadze
3, 5
,
Publication type: Journal Article
Publication date: 2016-10-05
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
27704797
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A new cationic molecular turnstile based on a P(V) porphyrin backbone bearing two pyridyl interaction sites, one at the meso position of the porphyrin and the other on the handle connected to the porphyrin through P-O bonds, was designed and synthesized. The dynamic behavior of the turnstile 2, investigated by 1D and 2D 1H NMR techniques, showed that in the absence of an effector, the turnstile is in its open state and undergoes a free rotation of the rotor (the handle) around the stator (the porphyrin backbone). In the presence of an external effector such as Ag+ cation or H+, the turnstile is switched to its closed states 2-Ag+ and 2-H+, respectively. The locking/unlocking process is reversible and may be achieved by precipitation of AgBr upon addition of Et4NBr in the case of the silver-locked turnstile or by addition of Et3N in the case of the proton-locked turnstile.
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Total citations:
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Citations from 2024:
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(20%)
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GOST
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Meshkov I. B. et al. Phosphorus(V) Porphyrin-Based Molecular Turnstiles // Inorganic Chemistry. 2016. Vol. 55. No. 20. pp. 10774-10782.
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Meshkov I. B., Meshkov I. N., Bulach V., Gorbunova Y. G., Kyritsakas N., Kyritsakas N., Grigoriev M. S., Tsivadze A., Tsivadze A. Y., HOSSEINI M. W. Phosphorus(V) Porphyrin-Based Molecular Turnstiles // Inorganic Chemistry. 2016. Vol. 55. No. 20. pp. 10774-10782.
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RIS
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TY - JOUR
DO - 10.1021/acs.inorgchem.6b01989
UR - https://pubs.acs.org/doi/10.1021/acs.inorgchem.6b01989
TI - Phosphorus(V) Porphyrin-Based Molecular Turnstiles
T2 - Inorganic Chemistry
AU - Meshkov, Ivan B
AU - Meshkov, Ivan N
AU - Bulach, Véronique
AU - Gorbunova, Yulia G.
AU - Kyritsakas, N.
AU - Kyritsakas, Nathalie
AU - Grigoriev, Mikhail S.
AU - Tsivadze, Aslan
AU - Tsivadze, Aslan Yu.
AU - HOSSEINI, MIR WAIS
PY - 2016
DA - 2016/10/05
PB - American Chemical Society (ACS)
SP - 10774-10782
IS - 20
VL - 55
PMID - 27704797
SN - 0020-1669
SN - 1520-510X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Meshkov,
author = {Ivan B Meshkov and Ivan N Meshkov and Véronique Bulach and Yulia G. Gorbunova and N. Kyritsakas and Nathalie Kyritsakas and Mikhail S. Grigoriev and Aslan Tsivadze and Aslan Yu. Tsivadze and MIR WAIS HOSSEINI},
title = {Phosphorus(V) Porphyrin-Based Molecular Turnstiles},
journal = {Inorganic Chemistry},
year = {2016},
volume = {55},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://pubs.acs.org/doi/10.1021/acs.inorgchem.6b01989},
number = {20},
pages = {10774--10782},
doi = {10.1021/acs.inorgchem.6b01989}
}
Cite this
MLA
Copy
Meshkov, Ivan B., et al. “Phosphorus(V) Porphyrin-Based Molecular Turnstiles.” Inorganic Chemistry, vol. 55, no. 20, Oct. 2016, pp. 10774-10782. https://pubs.acs.org/doi/10.1021/acs.inorgchem.6b01989.