Unusual Tri-, Hexa-, and Nonanuclear Cu(II) Cage Methylsilsesquioxanes: Synthesis, Structures, and Catalytic Activity in Oxidations with Peroxides
Alexey N Bilyachenko
1, 2
,
Alena N Kulakova
1, 2
,
Mikhail M Levitsky
1
,
Artem A Petrov
1
,
Alexander Korlyukov
1, 3
,
Alexander A. Korlyukov
1, 3
,
Lidia S Shulpina
1
,
Victor N. Khrustalev
1, 2
,
Pavel V. Dorovatovskii
4
,
A. Vologzhanina
1
,
Ulyana S Tsareva
1
,
Igor Golub
1, 2
,
Ekaterina S Gulyaeva
1
,
Elena S. Shubina
1
,
Georgiy B. Shul'pin
5, 6
3
4
Тип публикации: Journal Article
Дата публикации: 2017-03-20
scimago Q1
wos Q1
БС1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
28318235
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
Three types of unusual cagelike copper(II) methylsilsesquioxanes, namely, nona- [(MeSiO1.5)18(CuO)9] 1, hexa- [(MeSiO1.5)10(HO0.5)2(CuO)6(C12H8N2)2(MeSiO1.5)10(HO0.5)1.33(CH3COO0.5)0.67(CuO)6(C12H8N2)2] 2, [(MeSiO1.5)10(CuO)6(MeO0.5)2(C10H8N2)2] 3, and trinuclear [(MeSiO1.5)8(CuO)3(C10H8N2)2] 4, were obtained in 44%, 27%, 20%, and 16% yields, respectively. Nuclearity and structural fashion of products was controlled by the choice of solvent system and ligand, specifically assisting the assembling of cage. Structures of 1-4 were determined by single-crystal X-ray diffraction analysis. Compounds 1 and 4 are the first cage metallasilsesquioxanes, containing nine and three Cu ions, respectively. Product 1 is the first observation of nonanuclear metallasilsesquioxane ever. Unique architecture of 4 represents early unknown type of molecular geometry, based on two condensed pentamembered siloxane cycles. Topological analysis of metal clusters in products 1-4 is provided. Complex 1 efficiently catalyzes oxidation of alcohols with tert-butylhydroperoxide TBHP to ketones or alkanes with H2O2 to alkyl hydroperoxides in acetonitrile.
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Bilyachenko A. N. et al. Unusual Tri-, Hexa-, and Nonanuclear Cu(II) Cage Methylsilsesquioxanes: Synthesis, Structures, and Catalytic Activity in Oxidations with Peroxides // Inorganic Chemistry. 2017. Vol. 56. No. 7. pp. 4093-4103.
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Bilyachenko A. N., Kulakova A. N., Levitsky M. M., Petrov A. A., Korlyukov A., Korlyukov A. A., Shulpina L. S., Khrustalev V. N., Dorovatovskii P., Dorovatovskii P. V., Vologzhanina A., Tsareva U. S., Golub I., Gulyaeva E. S., Shubina E. S., Shul'pin G. B. Unusual Tri-, Hexa-, and Nonanuclear Cu(II) Cage Methylsilsesquioxanes: Synthesis, Structures, and Catalytic Activity in Oxidations with Peroxides // Inorganic Chemistry. 2017. Vol. 56. No. 7. pp. 4093-4103.
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TY - JOUR
DO - 10.1021/acs.inorgchem.7b00061
UR - https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b00061
TI - Unusual Tri-, Hexa-, and Nonanuclear Cu(II) Cage Methylsilsesquioxanes: Synthesis, Structures, and Catalytic Activity in Oxidations with Peroxides
T2 - Inorganic Chemistry
AU - Bilyachenko, Alexey N
AU - Kulakova, Alena N
AU - Levitsky, Mikhail M
AU - Petrov, Artem A
AU - Korlyukov, Alexander
AU - Korlyukov, Alexander A.
AU - Shulpina, Lidia S
AU - Khrustalev, Victor N.
AU - Dorovatovskii, Pavel
AU - Dorovatovskii, Pavel V.
AU - Vologzhanina, A.
AU - Tsareva, Ulyana S
AU - Golub, Igor
AU - Gulyaeva, Ekaterina S
AU - Shubina, Elena S.
AU - Shul'pin, Georgiy B.
PY - 2017
DA - 2017/03/20
PB - American Chemical Society (ACS)
SP - 4093-4103
IS - 7
VL - 56
PMID - 28318235
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2017_Bilyachenko,
author = {Alexey N Bilyachenko and Alena N Kulakova and Mikhail M Levitsky and Artem A Petrov and Alexander Korlyukov and Alexander A. Korlyukov and Lidia S Shulpina and Victor N. Khrustalev and Pavel Dorovatovskii and Pavel V. Dorovatovskii and A. Vologzhanina and Ulyana S Tsareva and Igor Golub and Ekaterina S Gulyaeva and Elena S. Shubina and Georgiy B. Shul'pin},
title = {Unusual Tri-, Hexa-, and Nonanuclear Cu(II) Cage Methylsilsesquioxanes: Synthesis, Structures, and Catalytic Activity in Oxidations with Peroxides},
journal = {Inorganic Chemistry},
year = {2017},
volume = {56},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b00061},
number = {7},
pages = {4093--4103},
doi = {10.1021/acs.inorgchem.7b00061}
}
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Bilyachenko, Alexey N., et al. “Unusual Tri-, Hexa-, and Nonanuclear Cu(II) Cage Methylsilsesquioxanes: Synthesis, Structures, and Catalytic Activity in Oxidations with Peroxides.” Inorganic Chemistry, vol. 56, no. 7, Mar. 2017, pp. 4093-4103. https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b00061.