Unusual Tri-, Hexa-, and Nonanuclear Cu(II) Cage Methylsilsesquioxanes: Synthesis, Structures, and Catalytic Activity in Oxidations with Peroxides
Alexey N Bilyachenko
1, 2
,
Alena N Kulakova
1, 2
,
Mikhail M Levitsky
1
,
Artem A Petrov
1
,
Alexander Korlyukov
1, 3
,
Alexander A. Korlyukov
1, 3
,
Lidia S Shulpina
1
,
Victor N. Khrustalev
1, 2
,
Pavel V. Dorovatovskii
4
,
A. Vologzhanina
1
,
Ulyana S Tsareva
1
,
Igor Golub
1, 2
,
Ekaterina S Gulyaeva
1
,
Elena S. Shubina
1
,
Georgiy B. Shul'pin
5, 6
3
4
Publication type: Journal Article
Publication date: 2017-03-20
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
28318235
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Three types of unusual cagelike copper(II) methylsilsesquioxanes, namely, nona- [(MeSiO1.5)18(CuO)9] 1, hexa- [(MeSiO1.5)10(HO0.5)2(CuO)6(C12H8N2)2(MeSiO1.5)10(HO0.5)1.33(CH3COO0.5)0.67(CuO)6(C12H8N2)2] 2, [(MeSiO1.5)10(CuO)6(MeO0.5)2(C10H8N2)2] 3, and trinuclear [(MeSiO1.5)8(CuO)3(C10H8N2)2] 4, were obtained in 44%, 27%, 20%, and 16% yields, respectively. Nuclearity and structural fashion of products was controlled by the choice of solvent system and ligand, specifically assisting the assembling of cage. Structures of 1-4 were determined by single-crystal X-ray diffraction analysis. Compounds 1 and 4 are the first cage metallasilsesquioxanes, containing nine and three Cu ions, respectively. Product 1 is the first observation of nonanuclear metallasilsesquioxane ever. Unique architecture of 4 represents early unknown type of molecular geometry, based on two condensed pentamembered siloxane cycles. Topological analysis of metal clusters in products 1-4 is provided. Complex 1 efficiently catalyzes oxidation of alcohols with tert-butylhydroperoxide TBHP to ketones or alkanes with H2O2 to alkyl hydroperoxides in acetonitrile.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
2
4
6
8
10
12
14
|
|
|
Inorganic Chemistry
13 publications, 21.67%
|
|
|
Catalysts
5 publications, 8.33%
|
|
|
Journal of Organometallic Chemistry
4 publications, 6.67%
|
|
|
Dalton Transactions
4 publications, 6.67%
|
|
|
Organometallics
3 publications, 5%
|
|
|
Chemistry - A European Journal
3 publications, 5%
|
|
|
Crystals
2 publications, 3.33%
|
|
|
Journal of Cluster Science
2 publications, 3.33%
|
|
|
Crystal Growth and Design
2 publications, 3.33%
|
|
|
European Journal of Inorganic Chemistry
2 publications, 3.33%
|
|
|
Molecules
2 publications, 3.33%
|
|
|
Coordination Chemistry Reviews
2 publications, 3.33%
|
|
|
Inorganica Chimica Acta
2 publications, 3.33%
|
|
|
ChemCatChem
1 publication, 1.67%
|
|
|
Inorganic Chemistry Frontiers
1 publication, 1.67%
|
|
|
Materials
1 publication, 1.67%
|
|
|
Science China Chemistry
1 publication, 1.67%
|
|
|
RSC Advances
1 publication, 1.67%
|
|
|
Journal of Materials Chemistry A
1 publication, 1.67%
|
|
|
Green Chemistry and Sustainable Technology
1 publication, 1.67%
|
|
|
Polymer Science - Series C
1 publication, 1.67%
|
|
|
High Performance Polymers
1 publication, 1.67%
|
|
|
Высокомолекулярные соединения С
1 publication, 1.67%
|
|
|
New Journal of Chemistry
1 publication, 1.67%
|
|
|
Chemical Communications
1 publication, 1.67%
|
|
|
2
4
6
8
10
12
14
|
Publishers
|
2
4
6
8
10
12
14
16
18
|
|
|
American Chemical Society (ACS)
18 publications, 30%
|
|
|
MDPI
10 publications, 16.67%
|
|
|
Elsevier
9 publications, 15%
|
|
|
Royal Society of Chemistry (RSC)
9 publications, 15%
|
|
|
Wiley
7 publications, 11.67%
|
|
|
Springer Nature
4 publications, 6.67%
|
|
|
Pleiades Publishing
1 publication, 1.67%
|
|
|
SAGE
1 publication, 1.67%
|
|
|
The Russian Academy of Sciences
1 publication, 1.67%
|
|
|
2
4
6
8
10
12
14
16
18
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
60
Total citations:
60
Citations from 2024:
5
(8.34%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Bilyachenko A. N. et al. Unusual Tri-, Hexa-, and Nonanuclear Cu(II) Cage Methylsilsesquioxanes: Synthesis, Structures, and Catalytic Activity in Oxidations with Peroxides // Inorganic Chemistry. 2017. Vol. 56. No. 7. pp. 4093-4103.
GOST all authors (up to 50)
Copy
Bilyachenko A. N., Kulakova A. N., Levitsky M. M., Petrov A. A., Korlyukov A., Korlyukov A. A., Shulpina L. S., Khrustalev V. N., Dorovatovskii P., Dorovatovskii P. V., Vologzhanina A., Tsareva U. S., Golub I., Gulyaeva E. S., Shubina E. S., Shul'pin G. B. Unusual Tri-, Hexa-, and Nonanuclear Cu(II) Cage Methylsilsesquioxanes: Synthesis, Structures, and Catalytic Activity in Oxidations with Peroxides // Inorganic Chemistry. 2017. Vol. 56. No. 7. pp. 4093-4103.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.inorgchem.7b00061
UR - https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b00061
TI - Unusual Tri-, Hexa-, and Nonanuclear Cu(II) Cage Methylsilsesquioxanes: Synthesis, Structures, and Catalytic Activity in Oxidations with Peroxides
T2 - Inorganic Chemistry
AU - Bilyachenko, Alexey N
AU - Kulakova, Alena N
AU - Levitsky, Mikhail M
AU - Petrov, Artem A
AU - Korlyukov, Alexander
AU - Korlyukov, Alexander A.
AU - Shulpina, Lidia S
AU - Khrustalev, Victor N.
AU - Dorovatovskii, Pavel
AU - Dorovatovskii, Pavel V.
AU - Vologzhanina, A.
AU - Tsareva, Ulyana S
AU - Golub, Igor
AU - Gulyaeva, Ekaterina S
AU - Shubina, Elena S.
AU - Shul'pin, Georgiy B.
PY - 2017
DA - 2017/03/20
PB - American Chemical Society (ACS)
SP - 4093-4103
IS - 7
VL - 56
PMID - 28318235
SN - 0020-1669
SN - 1520-510X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2017_Bilyachenko,
author = {Alexey N Bilyachenko and Alena N Kulakova and Mikhail M Levitsky and Artem A Petrov and Alexander Korlyukov and Alexander A. Korlyukov and Lidia S Shulpina and Victor N. Khrustalev and Pavel Dorovatovskii and Pavel V. Dorovatovskii and A. Vologzhanina and Ulyana S Tsareva and Igor Golub and Ekaterina S Gulyaeva and Elena S. Shubina and Georgiy B. Shul'pin},
title = {Unusual Tri-, Hexa-, and Nonanuclear Cu(II) Cage Methylsilsesquioxanes: Synthesis, Structures, and Catalytic Activity in Oxidations with Peroxides},
journal = {Inorganic Chemistry},
year = {2017},
volume = {56},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b00061},
number = {7},
pages = {4093--4103},
doi = {10.1021/acs.inorgchem.7b00061}
}
Cite this
MLA
Copy
Bilyachenko, Alexey N., et al. “Unusual Tri-, Hexa-, and Nonanuclear Cu(II) Cage Methylsilsesquioxanes: Synthesis, Structures, and Catalytic Activity in Oxidations with Peroxides.” Inorganic Chemistry, vol. 56, no. 7, Mar. 2017, pp. 4093-4103. https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b00061.