Trigonal Prismatic Tris-pyridineoximate Transition Metal Complexes: A Cobalt(II) Compound with High Magnetic Anisotropy
Publication type: Journal Article
Publication date: 2017-05-25
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
28541691
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
High magnetic anisotropy is a key property of paramagnetic shift tags, which are mostly studied by NMR spectroscopy, and of single molecule magnets, for which magnetometry is usually used. We successfully employed both these methods in analyzing magnetic properties of a series of transition metal complexes, the so-called clathrochelates. A cobalt complex was found to be both a promising paramagnetic shift tag and a single molecule magnet because of it having large axial magnetic susceptibility tensor anisotropy at room temperature (22.5 × 10-32 m3 mol-1) and a high effective barrier to magnetization reversal (up to 70.5 cm-1). The origin of this large magnetic anisotropy is a negative value of zero-field splitting energy that reaches -86 cm-1 according to magnetometry and NMR measurements.
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63
Total citations:
63
Citations from 2024:
18
(28.57%)
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GOST
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Pavlov A. et al. Trigonal Prismatic Tris-pyridineoximate Transition Metal Complexes: A Cobalt(II) Compound with High Magnetic Anisotropy // Inorganic Chemistry. 2017. Vol. 56. No. 12. pp. 6943-6951.
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Pavlov A., Savkina S. A., Belov A. S., Nelyubina Y. V., Efimov N. N., Voloshin Y. Z., Novikov V. V. Trigonal Prismatic Tris-pyridineoximate Transition Metal Complexes: A Cobalt(II) Compound with High Magnetic Anisotropy // Inorganic Chemistry. 2017. Vol. 56. No. 12. pp. 6943-6951.
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TY - JOUR
DO - 10.1021/acs.inorgchem.7b00447
UR - https://doi.org/10.1021/acs.inorgchem.7b00447
TI - Trigonal Prismatic Tris-pyridineoximate Transition Metal Complexes: A Cobalt(II) Compound with High Magnetic Anisotropy
T2 - Inorganic Chemistry
AU - Pavlov, Alexander
AU - Savkina, Svetlana A
AU - Belov, Alexander S.
AU - Nelyubina, Yulia V.
AU - Efimov, Nikolay N.
AU - Voloshin, Yan Z.
AU - Novikov, Valentin V
PY - 2017
DA - 2017/05/25
PB - American Chemical Society (ACS)
SP - 6943-6951
IS - 12
VL - 56
PMID - 28541691
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2017_Pavlov,
author = {Alexander Pavlov and Svetlana A Savkina and Alexander S. Belov and Yulia V. Nelyubina and Nikolay N. Efimov and Yan Z. Voloshin and Valentin V Novikov},
title = {Trigonal Prismatic Tris-pyridineoximate Transition Metal Complexes: A Cobalt(II) Compound with High Magnetic Anisotropy},
journal = {Inorganic Chemistry},
year = {2017},
volume = {56},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acs.inorgchem.7b00447},
number = {12},
pages = {6943--6951},
doi = {10.1021/acs.inorgchem.7b00447}
}
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MLA
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Pavlov, Alexander, et al. “Trigonal Prismatic Tris-pyridineoximate Transition Metal Complexes: A Cobalt(II) Compound with High Magnetic Anisotropy.” Inorganic Chemistry, vol. 56, no. 12, May. 2017, pp. 6943-6951. https://doi.org/10.1021/acs.inorgchem.7b00447.