Family of Polynuclear Nickel Cagelike Phenylsilsesquioxanes; Features of Periodic Networks and Magnetic Properties
Alexey N Bilyachenko
1, 2
,
Alexey Yalymov
1
,
Marina Dronova
1
,
Alexander Korlyukov
1, 3
,
Alexander A. Korlyukov
1, 3
,
A. Vologzhanina
1
,
Marina A Eskova
1
,
Jérôme Long
4
,
Joulia Larionova
4
,
Yannick Guari
4
,
Pavel V. Dorovatovskii
6
,
Elena S. Shubina
1
,
Mikhail M Levitsky
1
3
5
Publication type: Journal Article
Publication date: 2017-10-19
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
29048173
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A new family of bi-, tetra-, penta-, and hexanickel cagelike phenylsilsesquioxanes 1-6 was obtained by self-assembly and transmetalation procedures. Their crystal structures were established by single-crystal X-ray analysis, and features of crystal packing relevant to the network formation were studied by a topological analysis. Compounds 1, 2, and 4 are isolated architectures, while 3, 5, and 6 present extended 1D and 3D networks. The investigation of magnetic properties revealed the presence of ferro- (1 and 3-5) or antiferromagnetic (2 and 6) interactions between Ni(II) ions, giving rise in the most cases (1, 2, and 4-6) to the presence of a slow relaxation of the magnetization, which can originate from the spin frustration.
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Bilyachenko A. N. et al. Family of Polynuclear Nickel Cagelike Phenylsilsesquioxanes; Features of Periodic Networks and Magnetic Properties // Inorganic Chemistry. 2017. Vol. 56. No. 21. pp. 12751-12763.
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Bilyachenko A. N., Yalymov A., Dronova M., Korlyukov A., Korlyukov A. A., Vologzhanina A., Eskova M. A., Long J., Larionova J., Guari Y., Dorovatovskii P., Dorovatovskii P. V., Shubina E. S., Levitsky M. M. Family of Polynuclear Nickel Cagelike Phenylsilsesquioxanes; Features of Periodic Networks and Magnetic Properties // Inorganic Chemistry. 2017. Vol. 56. No. 21. pp. 12751-12763.
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TY - JOUR
DO - 10.1021/acs.inorgchem.7b01436
UR - https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b01436
TI - Family of Polynuclear Nickel Cagelike Phenylsilsesquioxanes; Features of Periodic Networks and Magnetic Properties
T2 - Inorganic Chemistry
AU - Bilyachenko, Alexey N
AU - Yalymov, Alexey
AU - Dronova, Marina
AU - Korlyukov, Alexander
AU - Korlyukov, Alexander A.
AU - Vologzhanina, A.
AU - Eskova, Marina A
AU - Long, Jérôme
AU - Larionova, Joulia
AU - Guari, Yannick
AU - Dorovatovskii, Pavel
AU - Dorovatovskii, Pavel V.
AU - Shubina, Elena S.
AU - Levitsky, Mikhail M
PY - 2017
DA - 2017/10/19
PB - American Chemical Society (ACS)
SP - 12751-12763
IS - 21
VL - 56
PMID - 29048173
SN - 0020-1669
SN - 1520-510X
ER -
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Copy
@article{2017_Bilyachenko,
author = {Alexey N Bilyachenko and Alexey Yalymov and Marina Dronova and Alexander Korlyukov and Alexander A. Korlyukov and A. Vologzhanina and Marina A Eskova and Jérôme Long and Joulia Larionova and Yannick Guari and Pavel Dorovatovskii and Pavel V. Dorovatovskii and Elena S. Shubina and Mikhail M Levitsky},
title = {Family of Polynuclear Nickel Cagelike Phenylsilsesquioxanes; Features of Periodic Networks and Magnetic Properties},
journal = {Inorganic Chemistry},
year = {2017},
volume = {56},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b01436},
number = {21},
pages = {12751--12763},
doi = {10.1021/acs.inorgchem.7b01436}
}
Cite this
MLA
Copy
Bilyachenko, Alexey N., et al. “Family of Polynuclear Nickel Cagelike Phenylsilsesquioxanes; Features of Periodic Networks and Magnetic Properties.” Inorganic Chemistry, vol. 56, no. 21, Oct. 2017, pp. 12751-12763. https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b01436.