Si10Cu6N4 Cage Hexacoppersilsesquioxanes Containing N Ligands: Synthesis, Structure, and High Catalytic Activity in Peroxide Oxidations
Alena N Kulakova
1, 2
,
Alexey N Bilyachenko
1, 2
,
Mikhail M Levitsky
1
,
Alexander A. Korlyukov
1, 3
,
Yan V. Zubavichus
4
,
Frédéric Lamaty
5
,
Xavier Bantreil
5
,
Benoît Villemejeanne
5
,
Jean Martinez
5
,
Lidia S Shulpina
1
,
Elena S. Shubina
1
,
Evgeniy I Gutsul
1
,
Igor A Mikhailov
6
,
Nikolay S Ikonnikov
1
,
Ulyana S Tsareva
1
,
Georgiy B Shulpin
6, 7
2
Тип публикации: Journal Article
Дата публикации: 2017-11-29
scimago Q1
wos Q1
БС1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
29185729
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
The synthesis, composition, and catalytic properties of a new family of hexanuclear Cu(II)-based phenylsilsesquioxanes are described here. Structural studies of 17 synthesized compounds revealed the general principle underlying their molecular topology: viz., a central metal oxide layer consisting of two Cu3 trimers is coordinated by two cyclic [PhSiO1.5]5 siloxanolate ligands to form a skewed sandwich architecture with the composition [(PhSiO1.5)10(CuO)6]2+. In addition to this O ligation by the siloxanolate rings, two opposite copper ions are additionally coordinated by the nitrogen atoms of corresponding N ligand(s), such as 2,2'-bipyridine (compounds 1-9), 1,10-phenanthroline (compounds 10-13), mixed 1,10-phenanthroline/2,2'-bipyridine (compound 14), or bathophenanthroline (compounds 15-17). Finally, the charge balance is maintained by two HO- (compounds 1-7, 10-13, and 15-17), two H3CO- (compound 8), or two CH3COO- (compounds 9 and 14) anions. Complexes 1 and 10 exhibited a high activity in the oxidative amidation oxidation of alcohols. Compounds 1, 10, and 15 are very efficient homogeneous catalysts in the oxidation of alkanes and alcohols with peroxides.
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Kulakova A. N. et al. Si10Cu6N4 Cage Hexacoppersilsesquioxanes Containing N Ligands: Synthesis, Structure, and High Catalytic Activity in Peroxide Oxidations // Inorganic Chemistry. 2017. Vol. 56. No. 24. pp. 15026-15040.
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Kulakova A. N., Bilyachenko A. N., Levitsky M. M., Khrustalev V. N., Korlyukov A. A., Zubavichus Y. V., Dorovatovskii P. V., Lamaty F., Bantreil X., Villemejeanne B., Martinez J., Shulpina L. S., Shubina E. S., Gutsul E. I., Mikhailov I. A., Ikonnikov N. S., Tsareva U. S., Shulpin G. B. Si10Cu6N4 Cage Hexacoppersilsesquioxanes Containing N Ligands: Synthesis, Structure, and High Catalytic Activity in Peroxide Oxidations // Inorganic Chemistry. 2017. Vol. 56. No. 24. pp. 15026-15040.
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TY - JOUR
DO - 10.1021/acs.inorgchem.7b02320
UR - https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b02320
TI - Si10Cu6N4 Cage Hexacoppersilsesquioxanes Containing N Ligands: Synthesis, Structure, and High Catalytic Activity in Peroxide Oxidations
T2 - Inorganic Chemistry
AU - Kulakova, Alena N
AU - Bilyachenko, Alexey N
AU - Levitsky, Mikhail M
AU - Khrustalev, Victor N.
AU - Korlyukov, Alexander A.
AU - Zubavichus, Yan V.
AU - Dorovatovskii, Pavel V.
AU - Lamaty, Frédéric
AU - Bantreil, Xavier
AU - Villemejeanne, Benoît
AU - Martinez, Jean
AU - Shulpina, Lidia S
AU - Shubina, Elena S.
AU - Gutsul, Evgeniy I
AU - Mikhailov, Igor A
AU - Ikonnikov, Nikolay S
AU - Tsareva, Ulyana S
AU - Shulpin, Georgiy B
PY - 2017
DA - 2017/11/29
PB - American Chemical Society (ACS)
SP - 15026-15040
IS - 24
VL - 56
PMID - 29185729
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2017_Kulakova,
author = {Alena N Kulakova and Alexey N Bilyachenko and Mikhail M Levitsky and Victor N. Khrustalev and Alexander A. Korlyukov and Yan V. Zubavichus and Pavel V. Dorovatovskii and Frédéric Lamaty and Xavier Bantreil and Benoît Villemejeanne and Jean Martinez and Lidia S Shulpina and Elena S. Shubina and Evgeniy I Gutsul and Igor A Mikhailov and Nikolay S Ikonnikov and Ulyana S Tsareva and Georgiy B Shulpin},
title = {Si10Cu6N4 Cage Hexacoppersilsesquioxanes Containing N Ligands: Synthesis, Structure, and High Catalytic Activity in Peroxide Oxidations},
journal = {Inorganic Chemistry},
year = {2017},
volume = {56},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b02320},
number = {24},
pages = {15026--15040},
doi = {10.1021/acs.inorgchem.7b02320}
}
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Kulakova, Alena N., et al. “Si10Cu6N4 Cage Hexacoppersilsesquioxanes Containing N Ligands: Synthesis, Structure, and High Catalytic Activity in Peroxide Oxidations.” Inorganic Chemistry, vol. 56, no. 24, Nov. 2017, pp. 15026-15040. https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b02320.