Vanadium Diboride (VB2) Synthesized at High Pressure: Elastic, Mechanical, Electronic, and Magnetic Properties and Thermal Stability.
Pei Wang
1
,
Ravhi S. Kumar
1
,
Esakki Muthu Sankaran
1
,
Xintong Qi
2
,
Xinyu Zhang
3
,
D. Popov
4
,
Andrew L. Cornelius
1
,
Bao-Sheng Li
2
,
Yusheng Zhao
1
,
Liping Wang
1
Тип публикации: Journal Article
Дата публикации: 2018-01-23
scimago Q1
wos Q1
БС1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
29360374
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
Vanadium diboride (VB2) with an AlB2-type structure has been synthesized at 8 GPa and 1700 K in a D-DIA-type multianvil apparatus. The obtained bulk modulus is B0 = 262(2) GPa with fixed B' = 4.0 for VB2 via high-pressure X-ray diffraction measurements. Meanwhile, VB2 has also been demonstrated to possess a high Vickers hardness of 27.2 ± 1.5 GPa, a high thermal stability of 1410 K in air, among the highest for transition-metal borides, and an extremely low resistivity value (41 μΩ cm) at room temperature. Results from first-principles calculations regarding the mechanical and electronic properties of VB2 are largely consistent with the experimental observations and further suggest that VB2 possesses simultaneously the properties of a hard and refractory ceramic and those of an excellent electric conductor.
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Wang P. et al. Vanadium Diboride (VB2) Synthesized at High Pressure: Elastic, Mechanical, Electronic, and Magnetic Properties and Thermal Stability. // Inorganic Chemistry. 2018. Vol. 57. No. 3. pp. 1096-1105.
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Wang P., Kumar R. S., Sankaran E. M., Qi X., Zhang X., Popov D., Cornelius A. L., Li B., Zhao Y., Wang L. Vanadium Diboride (VB2) Synthesized at High Pressure: Elastic, Mechanical, Electronic, and Magnetic Properties and Thermal Stability. // Inorganic Chemistry. 2018. Vol. 57. No. 3. pp. 1096-1105.
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TY - JOUR
DO - 10.1021/acs.inorgchem.7b02550
UR - https://doi.org/10.1021/acs.inorgchem.7b02550
TI - Vanadium Diboride (VB2) Synthesized at High Pressure: Elastic, Mechanical, Electronic, and Magnetic Properties and Thermal Stability.
T2 - Inorganic Chemistry
AU - Wang, Pei
AU - Kumar, Ravhi S.
AU - Sankaran, Esakki Muthu
AU - Qi, Xintong
AU - Zhang, Xinyu
AU - Popov, D.
AU - Cornelius, Andrew L.
AU - Li, Bao-Sheng
AU - Zhao, Yusheng
AU - Wang, Liping
PY - 2018
DA - 2018/01/23
PB - American Chemical Society (ACS)
SP - 1096-1105
IS - 3
VL - 57
PMID - 29360374
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2018_Wang,
author = {Pei Wang and Ravhi S. Kumar and Esakki Muthu Sankaran and Xintong Qi and Xinyu Zhang and D. Popov and Andrew L. Cornelius and Bao-Sheng Li and Yusheng Zhao and Liping Wang},
title = {Vanadium Diboride (VB2) Synthesized at High Pressure: Elastic, Mechanical, Electronic, and Magnetic Properties and Thermal Stability.},
journal = {Inorganic Chemistry},
year = {2018},
volume = {57},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/acs.inorgchem.7b02550},
number = {3},
pages = {1096--1105},
doi = {10.1021/acs.inorgchem.7b02550}
}
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MLA
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Wang, Pei, et al. “Vanadium Diboride (VB2) Synthesized at High Pressure: Elastic, Mechanical, Electronic, and Magnetic Properties and Thermal Stability..” Inorganic Chemistry, vol. 57, no. 3, Jan. 2018, pp. 1096-1105. https://doi.org/10.1021/acs.inorgchem.7b02550.