Probing Spin Crossover in a Solution by Paramagnetic NMR Spectroscopy
Alexander Pavlov
1
,
Gleb L Denisov
1
,
Publication type: Journal Article
Publication date: 2017-12-05
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
29206025
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Spin transitions in spin-crossover compounds are now routinely studied in the solid state by magnetometry; however, only a few methods exist for studies in solution. The currently used Evans method, which relies on NMR spectroscopy to measure the magnetic susceptibility, requires the availability of a very pure sample of the paramagnetic compound and its exact concentration. To overcome these limitations, we propose an alternative NMR-based technique for evaluating spin-state populations by only using the chemical shifts of a spin-crossover compound; those can be routinely obtained for a solution that contains unknown impurities and paramagnetic admixtures or is contaminated otherwise.
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48
Total citations:
48
Citations from 2024:
10
(20%)
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MLA
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GOST
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Pavlov A. et al. Probing Spin Crossover in a Solution by Paramagnetic NMR Spectroscopy // Inorganic Chemistry. 2017. Vol. 56. No. 24. pp. 14759-14762.
GOST all authors (up to 50)
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Pavlov A., Denisov G. L., Kiskin M. A., Nelyubina Y. V., Novikov V. V. Probing Spin Crossover in a Solution by Paramagnetic NMR Spectroscopy // Inorganic Chemistry. 2017. Vol. 56. No. 24. pp. 14759-14762.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.inorgchem.7b02649
UR - https://doi.org/10.1021/acs.inorgchem.7b02649
TI - Probing Spin Crossover in a Solution by Paramagnetic NMR Spectroscopy
T2 - Inorganic Chemistry
AU - Pavlov, Alexander
AU - Denisov, Gleb L
AU - Kiskin, Mikhail A.
AU - Nelyubina, Yulia V.
AU - Novikov, Valentin V
PY - 2017
DA - 2017/12/05
PB - American Chemical Society (ACS)
SP - 14759-14762
IS - 24
VL - 56
PMID - 29206025
SN - 0020-1669
SN - 1520-510X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2017_Pavlov,
author = {Alexander Pavlov and Gleb L Denisov and Mikhail A. Kiskin and Yulia V. Nelyubina and Valentin V Novikov},
title = {Probing Spin Crossover in a Solution by Paramagnetic NMR Spectroscopy},
journal = {Inorganic Chemistry},
year = {2017},
volume = {56},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/acs.inorgchem.7b02649},
number = {24},
pages = {14759--14762},
doi = {10.1021/acs.inorgchem.7b02649}
}
Cite this
MLA
Copy
Pavlov, Alexander, et al. “Probing Spin Crossover in a Solution by Paramagnetic NMR Spectroscopy.” Inorganic Chemistry, vol. 56, no. 24, Dec. 2017, pp. 14759-14762. https://doi.org/10.1021/acs.inorgchem.7b02649.