Heptanuclear Fe5Cu2-Phenylgermsesquioxane containing 2,2′-Bipyridine: Synthesis, Structure, and Catalytic Activity in Oxidation of C–H Compounds
Alexey N Bilyachenko
1, 2
,
Yan V. Zubavichus
3
,
Lidia S Shulpina
1
,
Alena N Kulakova
1, 2
,
Xavier Bantreil
4
,
Frédéric Lamaty
4
,
Mikhail M Levitsky
1
,
Evgeniy I Gutsul
1
,
Elena S. Shubina
1
,
Georgiy B Shulpin
5, 6
3
Publication type: Journal Article
Publication date: 2017-12-12
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
29232118
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A new representative of an unusual family of metallagermaniumsesquioxanes, namely the heterometallic cagelike phenylgermsesquioxane (PhGeO2)12Cu2Fe5(O)OH(PhGe)2O5(bipy)2 (2), was synthesized and structurally characterized. Fe(III) ions of the complex are coordinated by oxa ligands: (i) cyclic (PhGeO2)12 and acyclic (Ph2Ge2O5) germoxanolates and (ii) O2- and (iii) HO- moieties. In turn, Cu(II) ions are coordinated by both oxa (germoxanolates) and aza ligands (2,2'-bipyridines). This "hetero-type" of ligation gives in sum an attractive pagoda-like molecular architecture of the complex 2. Product 2 showed a high catalytic activity in the oxidation of alkanes to the corresponding alkyl hydroperoxides (in yields up to 30%) and alcohols (in yields up to 100%) and in the oxidative formation of benzamides from alcohols (catalyst loading down to 0.4 mol % in Cu/Fe).
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Bilyachenko A. N. et al. Heptanuclear Fe5Cu2-Phenylgermsesquioxane containing 2,2′-Bipyridine: Synthesis, Structure, and Catalytic Activity in Oxidation of C–H Compounds // Inorganic Chemistry. 2017. Vol. 57. No. 1. pp. 528-534.
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Bilyachenko A. N., Khrustalev V. N., Zubavichus Y. V., Shulpina L. S., Kulakova A. N., Bantreil X., Lamaty F., Levitsky M. M., Gutsul E. I., Shubina E. S., Shulpin G. B. Heptanuclear Fe5Cu2-Phenylgermsesquioxane containing 2,2′-Bipyridine: Synthesis, Structure, and Catalytic Activity in Oxidation of C–H Compounds // Inorganic Chemistry. 2017. Vol. 57. No. 1. pp. 528-534.
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TY - JOUR
DO - 10.1021/acs.inorgchem.7b02881
UR - https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b02881
TI - Heptanuclear Fe5Cu2-Phenylgermsesquioxane containing 2,2′-Bipyridine: Synthesis, Structure, and Catalytic Activity in Oxidation of C–H Compounds
T2 - Inorganic Chemistry
AU - Bilyachenko, Alexey N
AU - Khrustalev, Victor N.
AU - Zubavichus, Yan V.
AU - Shulpina, Lidia S
AU - Kulakova, Alena N
AU - Bantreil, Xavier
AU - Lamaty, Frédéric
AU - Levitsky, Mikhail M
AU - Gutsul, Evgeniy I
AU - Shubina, Elena S.
AU - Shulpin, Georgiy B
PY - 2017
DA - 2017/12/12
PB - American Chemical Society (ACS)
SP - 528-534
IS - 1
VL - 57
PMID - 29232118
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2017_Bilyachenko,
author = {Alexey N Bilyachenko and Victor N. Khrustalev and Yan V. Zubavichus and Lidia S Shulpina and Alena N Kulakova and Xavier Bantreil and Frédéric Lamaty and Mikhail M Levitsky and Evgeniy I Gutsul and Elena S. Shubina and Georgiy B Shulpin},
title = {Heptanuclear Fe5Cu2-Phenylgermsesquioxane containing 2,2′-Bipyridine: Synthesis, Structure, and Catalytic Activity in Oxidation of C–H Compounds},
journal = {Inorganic Chemistry},
year = {2017},
volume = {57},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b02881},
number = {1},
pages = {528--534},
doi = {10.1021/acs.inorgchem.7b02881}
}
Cite this
MLA
Copy
Bilyachenko, Alexey N., et al. “Heptanuclear Fe5Cu2-Phenylgermsesquioxane containing 2,2′-Bipyridine: Synthesis, Structure, and Catalytic Activity in Oxidation of C–H Compounds.” Inorganic Chemistry, vol. 57, no. 1, Dec. 2017, pp. 528-534. https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b02881.