Inorganic Chemistry

, том 57 , издание 3 , страницы 1656-1664

Steric and Acidity Control in Hydrogen Bonding and Proton Transfer to trans-W(N2)2(dppe)2

Nikolay V Kireev ^{1, 2, 3}

Oleg A. Filippov ^{1, 3}

Alexander Pavlov ¹

Alexander A. Pavlov ³

Lina M. epstein ^{1, 3}

Victor D Makhaev ⁴

Victor P. Dyadchenko ²

Elena S. Shubina ^{1, 3}

Natalia V Belkova ^{1, 3}

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A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences (INEOS RAS), 28 Vavilova St, 119991 Moscow, Russia |

Department of Chemistry, M.V. Lomonosov Moscow State University, Leninskie Gory 1/3, 119234 Moscow, Russia |

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences (INEOS RAS), 28 Vavilova St, 119991 Moscow, Russia |

⁴

Institute of Problems of Chemical Physics, Russian Academy of Sciences (IPCP RAS), 1 Academician Semenov Avenue, 142432 Chernogolovka, Moscow Oblast, Russia |

Тип публикации: Journal Article

Дата публикации: 2018-01-19

American Chemical Society (ACS)

Inorganic Chemistry

scimago Q1

wos Q1

БС1

SJR: 0.958

CiteScore: 7.4

Impact factor: 4.7

ISSN: 00201669, 1520510X

DOI: 10.1021/acs.inorgchem.7b03027

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PubMed ID: 29350026

Inorganic Chemistry

Physical and Theoretical Chemistry

Краткое описание

The interaction of trans-W(N2)2(dppe)2 (1; dppe = 1,2-bis(diphenylphosphino)ethane) with relatively weak acids (p-nitrophenol, fluorinated alcohols, CF3COOH) was studied by means of variable temperature IR and NMR spectroscopy and complemented by DFT/B3PW91-D3 calculations. The results show, for the first time, the formation of a hydrogen bond to the coordinated dinitrogen, W-N≡N···H-O, that is preferred over H-bonding to the metal atom, W···H-O, despite the higher proton affinity of the latter. Protonation of the core metal-the undesirable side step in the conversion of N2 to NH3-can be avoided by using weaker and, more importantly, bulkier acids.

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Russian Chemical Bulletin	Russian Chemical Bulletin, 1, 12.5% Russian Chemical Bulletin 1 публикация, 12.5%
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Kireev N. V. et al. Steric and Acidity Control in Hydrogen Bonding and Proton Transfer to trans-W(N2)2(dppe)2 // Inorganic Chemistry. 2018. Vol. 57. No. 3. pp. 1656-1664.

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Kireev N. V., Filippov O. A., Pavlov A., Pavlov A. A., epstein L. M., Makhaev V. D., Dyadchenko V. P., Shubina E. S., Belkova N. V. Steric and Acidity Control in Hydrogen Bonding and Proton Transfer to trans-W(N2)2(dppe)2 // Inorganic Chemistry. 2018. Vol. 57. No. 3. pp. 1656-1664.

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TY - JOUR

DO - 10.1021/acs.inorgchem.7b03027

UR - https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b03027

TI - Steric and Acidity Control in Hydrogen Bonding and Proton Transfer to trans-W(N2)2(dppe)2

T2 - Inorganic Chemistry

AU - Kireev, Nikolay V

AU - Filippov, Oleg A.

AU - Pavlov, Alexander

AU - Pavlov, Alexander A.

AU - epstein, Lina M.

AU - Makhaev, Victor D

AU - Dyadchenko, Victor P.

AU - Shubina, Elena S.

AU - Belkova, Natalia V

PY - 2018

DA - 2018/01/19

PB - American Chemical Society (ACS)

SP - 1656-1664

IS - 3

VL - 57

PMID - 29350026

SN - 0020-1669

SN - 1520-510X

ER -

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@article{2018_Kireev,

author = {Nikolay V Kireev and Oleg A. Filippov and Alexander Pavlov and Alexander A. Pavlov and Lina M. epstein and Victor D Makhaev and Victor P. Dyadchenko and Elena S. Shubina and Natalia V Belkova},

title = {Steric and Acidity Control in Hydrogen Bonding and Proton Transfer to trans-W(N2)2(dppe)2},

journal = {Inorganic Chemistry},

year = {2018},

volume = {57},

publisher = {American Chemical Society (ACS)},

month = {jan},

url = {https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b03027},

number = {3},

pages = {1656--1664},

doi = {10.1021/acs.inorgchem.7b03027}

}

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Kireev, Nikolay V., et al. “Steric and Acidity Control in Hydrogen Bonding and Proton Transfer to trans-W(N2)2(dppe)2.” Inorganic Chemistry, vol. 57, no. 3, Jan. 2018, pp. 1656-1664. https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b03027.