Steric and Acidity Control in Hydrogen Bonding and Proton Transfer to trans-W(N2 )2 (dppe)2
Nikolay V Kireev
1, 2, 3
,
Oleg A. Filippov
1, 3
,
Alexander Pavlov
1
,
Lina M. epstein
1, 3
,
Victor D Makhaev
4
,
Elena S. Shubina
1, 3
,
Natalia V Belkova
1, 3
Publication type: Journal Article
Publication date: 2018-01-19
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
29350026
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The interaction of trans-W(N2)2(dppe)2 (1; dppe = 1,2-bis(diphenylphosphino)ethane) with relatively weak acids (p-nitrophenol, fluorinated alcohols, CF3COOH) was studied by means of variable temperature IR and NMR spectroscopy and complemented by DFT/B3PW91-D3 calculations. The results show, for the first time, the formation of a hydrogen bond to the coordinated dinitrogen, W-N≡N···H-O, that is preferred over H-bonding to the metal atom, W···H-O, despite the higher proton affinity of the latter. Protonation of the core metal-the undesirable side step in the conversion of N2 to NH3-can be avoided by using weaker and, more importantly, bulkier acids.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
|
|
|
Russian Chemical Bulletin
1 publication, 12.5%
|
|
|
Journal of the American Chemical Society
1 publication, 12.5%
|
|
|
Russian Journal of Inorganic Chemistry
1 publication, 12.5%
|
|
|
European Journal of Inorganic Chemistry
1 publication, 12.5%
|
|
|
Chemical Society Reviews
1 publication, 12.5%
|
|
|
Chemistry - A European Journal
1 publication, 12.5%
|
|
|
Journal of Colloid and Interface Science
1 publication, 12.5%
|
|
|
1
|
Publishers
|
1
2
|
|
|
Elsevier
2 publications, 25%
|
|
|
Wiley
2 publications, 25%
|
|
|
Springer Nature
1 publication, 12.5%
|
|
|
American Chemical Society (ACS)
1 publication, 12.5%
|
|
|
Pleiades Publishing
1 publication, 12.5%
|
|
|
Royal Society of Chemistry (RSC)
1 publication, 12.5%
|
|
|
1
2
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
8
Total citations:
8
Citations from 2024:
3
(37%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Kireev N. V. et al. Steric and Acidity Control in Hydrogen Bonding and Proton Transfer to trans-W(N2)2(dppe)2 // Inorganic Chemistry. 2018. Vol. 57. No. 3. pp. 1656-1664.
GOST all authors (up to 50)
Copy
Kireev N. V., Filippov O. A., Pavlov A., Pavlov A. A., epstein L. M., Makhaev V. D., Dyadchenko V. P., Shubina E. S., Belkova N. V. Steric and Acidity Control in Hydrogen Bonding and Proton Transfer to trans-W(N2)2(dppe)2 // Inorganic Chemistry. 2018. Vol. 57. No. 3. pp. 1656-1664.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.inorgchem.7b03027
UR - https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b03027
TI - Steric and Acidity Control in Hydrogen Bonding and Proton Transfer to trans-W(N2)2(dppe)2
T2 - Inorganic Chemistry
AU - Kireev, Nikolay V
AU - Filippov, Oleg A.
AU - Pavlov, Alexander
AU - Pavlov, Alexander A.
AU - epstein, Lina M.
AU - Makhaev, Victor D
AU - Dyadchenko, Victor P.
AU - Shubina, Elena S.
AU - Belkova, Natalia V
PY - 2018
DA - 2018/01/19
PB - American Chemical Society (ACS)
SP - 1656-1664
IS - 3
VL - 57
PMID - 29350026
SN - 0020-1669
SN - 1520-510X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Kireev,
author = {Nikolay V Kireev and Oleg A. Filippov and Alexander Pavlov and Alexander A. Pavlov and Lina M. epstein and Victor D Makhaev and Victor P. Dyadchenko and Elena S. Shubina and Natalia V Belkova},
title = {Steric and Acidity Control in Hydrogen Bonding and Proton Transfer to trans-W(N2)2(dppe)2},
journal = {Inorganic Chemistry},
year = {2018},
volume = {57},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b03027},
number = {3},
pages = {1656--1664},
doi = {10.1021/acs.inorgchem.7b03027}
}
Cite this
MLA
Copy
Kireev, Nikolay V., et al. “Steric and Acidity Control in Hydrogen Bonding and Proton Transfer to trans-W(N2)2(dppe)2.” Inorganic Chemistry, vol. 57, no. 3, Jan. 2018, pp. 1656-1664. https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b03027.