XPS Study of Nanostructured Rhodium Oxide Film Comprising Rh4+ Species
Lidiya Kibis
1, 2
,
Andrey Stadnichenko
1, 2
,
Sergey V Koscheev
1, 2
,
Vladimir I Zaikovskii
1, 2
,
Andrei Boronin
1, 2
Publication type: Journal Article
Publication date: 2016-08-24
scimago Q1
wos Q3
SJR: 0.914
CiteScore: 6.2
Impact factor: 3.2
ISSN: 19327447, 19327455
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
General Energy
Abstract
Studies of highly oxidized rhodium species as potential active sites in catalytic oxidation reactions are of great interest. In this work, we investigated the properties of highly oxidized nanostructured rhodium film prepared by radio frequency discharge in an oxygen atmosphere. The charge states of Rh in RhOx particles, their thermal stability, and reactivity toward CO were analyzed in comparison with the properties of thermally prepared Rh2O3 oxide. The formation of Rh4+ species in a composition of Rh4+/Rh3+ oxyhydroxide structures was shown to take place in plasma-synthesized films. The highly oxidized rhodium species was stable up to 150 °C and demonstrated reactivity in a CO oxidation reaction at 100 °C. The reoxidation of a partially reduced Rh/RhOx film was observed at 100 °C under treatment with molecular O2. However, Rh4+ species were not recovered under such conditions.
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101
Total citations:
101
Citations from 2025:
10
(9.9%)
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GOST
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Kibis L. et al. XPS Study of Nanostructured Rhodium Oxide Film Comprising Rh4+ Species // Journal of Physical Chemistry C. 2016. Vol. 120. No. 34. pp. 19142-19150.
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Kibis L., Stadnichenko A., Koscheev S. V., Zaikovskii V. I., Boronin A. XPS Study of Nanostructured Rhodium Oxide Film Comprising Rh4+ Species // Journal of Physical Chemistry C. 2016. Vol. 120. No. 34. pp. 19142-19150.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.jpcc.6b05219
UR - https://doi.org/10.1021/acs.jpcc.6b05219
TI - XPS Study of Nanostructured Rhodium Oxide Film Comprising Rh4+ Species
T2 - Journal of Physical Chemistry C
AU - Kibis, Lidiya
AU - Stadnichenko, Andrey
AU - Koscheev, Sergey V
AU - Zaikovskii, Vladimir I
AU - Boronin, Andrei
PY - 2016
DA - 2016/08/24
PB - American Chemical Society (ACS)
SP - 19142-19150
IS - 34
VL - 120
SN - 1932-7447
SN - 1932-7455
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Kibis,
author = {Lidiya Kibis and Andrey Stadnichenko and Sergey V Koscheev and Vladimir I Zaikovskii and Andrei Boronin},
title = {XPS Study of Nanostructured Rhodium Oxide Film Comprising Rh4+ Species},
journal = {Journal of Physical Chemistry C},
year = {2016},
volume = {120},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acs.jpcc.6b05219},
number = {34},
pages = {19142--19150},
doi = {10.1021/acs.jpcc.6b05219}
}
Cite this
MLA
Copy
Kibis, Lidiya, et al. “XPS Study of Nanostructured Rhodium Oxide Film Comprising Rh4+ Species.” Journal of Physical Chemistry C, vol. 120, no. 34, Aug. 2016, pp. 19142-19150. https://doi.org/10.1021/acs.jpcc.6b05219.
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