Journal of Physical Chemistry C, volume 120, issue 50, pages 28509-28518

Air Stable PbSe Colloidal Quantum Dot Heterojunction Solar Cells: Ligand-Dependent Exciton Dissociation, Recombination, Photovoltaic Property, and Stability

Yaohong Zhang ¹

Chao Ding ¹

Guohua Wu ²

Naoki NAKAZAWA ¹

Jin Chang ³

Yuhei Ogomi ⁴

Taro Toyoda ^{1, 5}

Shuzi Hayase ^{4, 5}

Kenji KATAYAMA ⁶

Qing Shen ^{1, 5}

Hide authors affiliations Show authors affiliations: 6 affiliations

Faculty of Informatics and Engineering, The University of Electro-Communications, 1-5-1 Chofugaoka, Chofu, Tokyo 182-8585, Japan |

College of Science and Technology, Nihon University, 1-8-14 Kanda Surugadai, Chiyoda-ku, Tokyo 101-8308, Japan |

Institute of Advanced Materials, Nanjing Tech University, 5 Xinmofan Road, Nanjing 210009, China |

⁴

Faculty of Life Science and Systems Engineering, Kyushu Institute of Technology, 2-4 Hibikino, Wakamatsu-ku, Kitakyushu, Fukuoka 808-0196, Japan |

⁵

CREST, Japan Science and Technology Agency (JST), 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan |

⁶

Department of Applied Chemistry, Chuo University, 1-13-27, Kasuga, Bunkyo, Tokyo 112-8551, Japan |

Publication type: Journal Article

Publication date: 2016-12-13

American Chemical Society (ACS)

Journal: Journal of Physical Chemistry C

Quartile SCImago

Quartile WOS

Impact factor: 3.7

ISSN: 19327447, 19327455

DOI: 10.1021/acs.jpcc.6b10920

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Surfaces, Coatings and Films

Electronic, Optical and Magnetic Materials

Physical and Theoretical Chemistry

General Energy

Abstract

We fabricated the long-term air stable PbSe colloidal quantum dots (CQDs) based planar heterojunction solar cells (FTO/TiO2/PbSe/Au) with relatively larger active area (0.25 cm2) using tetrabutylammonium iodide (TBAI, I–) as ligand in solid state ligand-exchange process. For the first time, we have achieved the whole preparation process of the device in the ambient atmosphere from PbSe CQDs collection to PbSe colloidal quantum dot solar cells (CQDSCs) fabrication, then storage and in their following measurements. Especially, TBAI-treated PbSe CQDSCs exhibited a power conversion efficiency (PCE) of 3.53% under AM 1.5 G in air, and also a remarkable long-term stability (more than 90 days) of their storage in ambient atmosphere has been identified. By contrast, 1,2-ethanedithiol (EDT), 3-mercaptopropionic acid (MPA) and cetyltrimethylammonium bromide (CTAB, Br–) treated PbSe CQDSCs were further studied. The ligand-dependent exciton dissociation, recombination, energy level shift, and air stability of PbSe CQ...

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Journal of Photochemistry and Photobiology A: Chemistry	Journal of Photochemistry and Photobiology A: Chemistry, 1, 2.33% Journal of Photochemistry and Photobiology A: Chemistry 1 publication, 2.33%
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American Chemical Society (ACS)	American Chemical Society (ACS), 10, 23.26% American Chemical Society (ACS) 10 publications, 23.26%
Wiley	Wiley, 9, 20.93% Wiley 9 publications, 20.93%
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Frontiers Media S.A.	Frontiers Media S.A., 1, 2.33% Frontiers Media S.A. 1 publication, 2.33%
Japan Society for Analytical Chemistry	Japan Society for Analytical Chemistry, 1, 2.33% Japan Society for Analytical Chemistry 1 publication, 2.33%
Springer Nature	Springer Nature, 1, 2.33% Springer Nature 1 publication, 2.33%
Japan Society of Applied Physics	Japan Society of Applied Physics, 1, 2.33% Japan Society of Applied Physics 1 publication, 2.33%
Optical Society of America	Optical Society of America, 1, 2.33% Optical Society of America 1 publication, 2.33%
Hindawi Limited	Hindawi Limited, 1, 2.33% Hindawi Limited 1 publication, 2.33%
Proceedings of the National Academy of Sciences (PNAS)	Proceedings of the National Academy of Sciences (PNAS), 1, 2.33% Proceedings of the National Academy of Sciences (PNAS) 1 publication, 2.33%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 2.33% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 2.33%
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Zhang Y. et al. Air Stable PbSe Colloidal Quantum Dot Heterojunction Solar Cells: Ligand-Dependent Exciton Dissociation, Recombination, Photovoltaic Property, and Stability // Journal of Physical Chemistry C. 2016. Vol. 120. No. 50. pp. 28509-28518.

GOST all authors (up to 50) Copy

Zhang Y., Ding C., Wu G., NAKAZAWA N., Chang J., Ogomi Y., Toyoda T., Hayase S., KATAYAMA K., Shen Q. Air Stable PbSe Colloidal Quantum Dot Heterojunction Solar Cells: Ligand-Dependent Exciton Dissociation, Recombination, Photovoltaic Property, and Stability // Journal of Physical Chemistry C. 2016. Vol. 120. No. 50. pp. 28509-28518.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/acs.jpcc.6b10920

UR - https://doi.org/10.1021/acs.jpcc.6b10920

TI - Air Stable PbSe Colloidal Quantum Dot Heterojunction Solar Cells: Ligand-Dependent Exciton Dissociation, Recombination, Photovoltaic Property, and Stability

T2 - Journal of Physical Chemistry C

AU - Ding, Chao

AU - Wu, Guohua

AU - NAKAZAWA, Naoki

AU - Chang, Jin

AU - Ogomi, Yuhei

AU - Toyoda, Taro

AU - Hayase, Shuzi

AU - KATAYAMA, Kenji

AU - Zhang, Yaohong

AU - Shen, Qing

PY - 2016

DA - 2016/12/13 00:00:00

PB - American Chemical Society (ACS)

SP - 28509-28518

IS - 50

VL - 120

SN - 1932-7447

SN - 1932-7455

ER -

BibTex |

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BibTex Copy

@article{2016_Zhang,

author = {Chao Ding and Guohua Wu and Naoki NAKAZAWA and Jin Chang and Yuhei Ogomi and Taro Toyoda and Shuzi Hayase and Kenji KATAYAMA and Yaohong Zhang and Qing Shen},

title = {Air Stable PbSe Colloidal Quantum Dot Heterojunction Solar Cells: Ligand-Dependent Exciton Dissociation, Recombination, Photovoltaic Property, and Stability},

journal = {Journal of Physical Chemistry C},

year = {2016},

volume = {120},

publisher = {American Chemical Society (ACS)},

month = {dec},

url = {https://doi.org/10.1021/acs.jpcc.6b10920},

number = {50},

pages = {28509--28518},

doi = {10.1021/acs.jpcc.6b10920}

}

MLA

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MLA Copy

Zhang, Yaohong, et al. “Air Stable PbSe Colloidal Quantum Dot Heterojunction Solar Cells: Ligand-Dependent Exciton Dissociation, Recombination, Photovoltaic Property, and Stability.” Journal of Physical Chemistry C, vol. 120, no. 50, Dec. 2016, pp. 28509-28518. https://doi.org/10.1021/acs.jpcc.6b10920.

Found error?

Publisher

American Chemical Society (ACS)

Journal

Journal of Physical Chemistry C

Quartile SCImago

Quartile WOS

Impact factor

3.7

ISSN

19327447 (Print)
19327455 (Electronic)