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Journal of Physical Chemistry Letters

, том 6 , издание 11 , страницы 2147-2152

Toward the ultra-incompressible carbon materials. computational simulation and experimental observation

Тип публикации: Journal Article

Дата публикации: 2015-05-27

American Chemical Society (ACS)

Journal of Physical Chemistry Letters

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SJR: 1.394

CiteScore: 8.7

Impact factor: 4.6

ISSN: 19487185

DOI: 10.1021/acs.jpclett.5b00748

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PubMed ID: 26266517

Physical and Theoretical Chemistry

General Materials Science

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The common opinion that diamond is the stiffest material is disproved by a number of experimental studies where the fabrication of carbon materials based on polymerized fullerenes with outstanding mechanical stiffness was reported. Here we investigated the nature of this unusual effect. We present a model constituted of compressed polymerized fullerite clusters implemented in a diamond matrix with bulk modulus B0 much higher than that of diamond. The calculated B0 value depends on the sizes of both fullerite grain and diamond environment and shows close correspondence with measured data. Additionally, we provide results of experimental study of atomic structure and mechanical properties of ultrahard carbon material supported the presented model.

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Kvashnina Yu. A. et al. Toward the ultra-incompressible carbon materials. computational simulation and experimental observation // Journal of Physical Chemistry Letters. 2015. Vol. 6. No. 11. pp. 2147-2152.

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Kvashnina Yu. A., Kvashnin A. G., Popov M., Kulnitskiy B. A., Perezhogin I., Tyukalova E., Chernozatonskii L. A., Sorokin P. B., Blank V. D. Toward the ultra-incompressible carbon materials. computational simulation and experimental observation // Journal of Physical Chemistry Letters. 2015. Vol. 6. No. 11. pp. 2147-2152.

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TY - JOUR

DO - 10.1021/acs.jpclett.5b00748

UR - https://doi.org/10.1021/acs.jpclett.5b00748

TI - Toward the ultra-incompressible carbon materials. computational simulation and experimental observation

T2 - Journal of Physical Chemistry Letters

AU - Kvashnina, Yu A

AU - Kvashnin, Alexander G.

AU - Popov, Mikhail

AU - Kulnitskiy, Boris A.

AU - Perezhogin, Igor

AU - Tyukalova, E.V.

AU - Chernozatonskii, L A

AU - Sorokin, Pavel B.

AU - Blank, Vladimir D.

PY - 2015

DA - 2015/05/27

PB - American Chemical Society (ACS)

SP - 2147-2152

IS - 11

VL - 6

PMID - 26266517

SN - 1948-7185

ER -

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@article{2015_Kvashnina,

author = {Yu A Kvashnina and Alexander G. Kvashnin and Mikhail Popov and Boris A. Kulnitskiy and Igor Perezhogin and E.V. Tyukalova and L A Chernozatonskii and Pavel B. Sorokin and Vladimir D. Blank},

title = {Toward the ultra-incompressible carbon materials. computational simulation and experimental observation},

journal = {Journal of Physical Chemistry Letters},

year = {2015},

volume = {6},

publisher = {American Chemical Society (ACS)},

month = {may},

url = {https://doi.org/10.1021/acs.jpclett.5b00748},

number = {11},

pages = {2147--2152},

doi = {10.1021/acs.jpclett.5b00748}

}

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Kvashnina, Yu. A., et al. “Toward the ultra-incompressible carbon materials. computational simulation and experimental observation.” Journal of Physical Chemistry Letters, vol. 6, no. 11, May. 2015, pp. 2147-2152. https://doi.org/10.1021/acs.jpclett.5b00748.