Polyhedral Rearrangements in the Complexes of Rhodium and Iridium with Isomeric Carborane Anions [7,8-Me2-X-SMe2-7,8-nido-C2B9H8]− (X = 9 and 10)
Alexander Pavlov
1
,
Alexander R Kudinov
1
Publication type: Journal Article
Publication date: 2017-02-08
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Polyhedral rearrangement of iridacarborane 1,2-Me2-3,3-(cod)-4-SMe2-3,1,2-closo-IrC2B9H8 (1) proceeds in a solution at RT and affords a product of 1,2 → 1,7 isomerization 1,8-Me2-2,2-(cod)-7-SMe2-2,1,8-closo-IrC2B9H8 (2). Rhodium derivative 1,2-Me2-3,3-(cod)-4-SMe2-3,1,2-closo-RhC2B9H8 (3) is significantly more stable toward heating than iridium complex 1 and isomerizes at 110 °C by 1,2 → 1,2 and 1,2 → 1,7 reaction schemes with 1,2 → 1,2 being the predominant route forming 1,2-Me2-4,4-(cod)-8-SMe2-4,1,2-closo-RhC2B9H8 (4) and 1,8-Me2-2,2-(cod)-7-SMe2-2,1,8-closo-RhC2B9H8 (5). Complexes 4 and 5 were characterized by 11B{1H}–11B{1H} COSY NMR spectrometry. A mechanism of 1,2 → 1,2 isomerization of 3 to 4 was proposed on the basis of DFT calculations. Reaction of the thallium salt Tl[7,8-Me2-9-SMe2-7,8-nido-C2B9H8] (CarbTl) with [Cp*RuCl]4 in THF furnishes new ruthenacarborane 1,2-Me2-3-(Cp*)-4-SMe2-3,1,2-closo-RuC2B9H8 (6). Heating of 6 at 80 and 144 °C leads to the partial and complete decomposition, respec...
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Vinogradov M. M. et al. Polyhedral Rearrangements in the Complexes of Rhodium and Iridium with Isomeric Carborane Anions [7,8-Me2-X-SMe2-7,8-nido-C2B9H8]− (X = 9 and 10) // Organometallics. 2017. Vol. 36. No. 4. pp. 791-800.
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Vinogradov M. M., Nelyubina Y. V., Pavlov A., Novikov V. V., Shvydkiy N. V., Kudinov A. R. Polyhedral Rearrangements in the Complexes of Rhodium and Iridium with Isomeric Carborane Anions [7,8-Me2-X-SMe2-7,8-nido-C2B9H8]− (X = 9 and 10) // Organometallics. 2017. Vol. 36. No. 4. pp. 791-800.
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TY - JOUR
DO - 10.1021/acs.organomet.6b00858
UR - https://doi.org/10.1021/acs.organomet.6b00858
TI - Polyhedral Rearrangements in the Complexes of Rhodium and Iridium with Isomeric Carborane Anions [7,8-Me2-X-SMe2-7,8-nido-C2B9H8]− (X = 9 and 10)
T2 - Organometallics
AU - Vinogradov, Mikhail M
AU - Nelyubina, Yulia V.
AU - Pavlov, Alexander
AU - Novikov, Valentin V
AU - Shvydkiy, Nikita V
AU - Kudinov, Alexander R
PY - 2017
DA - 2017/02/08
PB - American Chemical Society (ACS)
SP - 791-800
IS - 4
VL - 36
SN - 0276-7333
SN - 1520-6041
ER -
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@article{2017_Vinogradov,
author = {Mikhail M Vinogradov and Yulia V. Nelyubina and Alexander Pavlov and Valentin V Novikov and Nikita V Shvydkiy and Alexander R Kudinov},
title = {Polyhedral Rearrangements in the Complexes of Rhodium and Iridium with Isomeric Carborane Anions [7,8-Me2-X-SMe2-7,8-nido-C2B9H8]− (X = 9 and 10)},
journal = {Organometallics},
year = {2017},
volume = {36},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acs.organomet.6b00858},
number = {4},
pages = {791--800},
doi = {10.1021/acs.organomet.6b00858}
}
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Vinogradov, Mikhail M., et al. “Polyhedral Rearrangements in the Complexes of Rhodium and Iridium with Isomeric Carborane Anions [7,8-Me2-X-SMe2-7,8-nido-C2B9H8]− (X = 9 and 10).” Organometallics, vol. 36, no. 4, Feb. 2017, pp. 791-800. https://doi.org/10.1021/acs.organomet.6b00858.