A New Mode of Operation of Pd-NHC Systems Studied in a Catalytic Mizoroki–Heck Reaction
Publication type: Journal Article
Publication date: 2017-04-03
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Metal complexes bearing N-heterocyclic carbene (NHC) ligands are typically considered the system of choice for homogeneous catalysis with well-defined molecular active species due to their stable metal–ligand framework. A detailed study involving 19 different Pd-NHC complexes with imidazolium, benzimidazolium, and triazolium ligands has been carried out in the present work and revealed a new mode of operation of metal-NHC systems. The catalytic activity of the studied Pd-NHC systems is predominantly determined by the cleavage of the metal–NHC bond, while the catalyst performance is strongly affected by the stabilization of in situ formed metal clusters. In the present study, the formation of Pd nanoparticles was observed from a broad range of metal complexes with NHC ligands under standard Mizoroki–Heck reaction conditions. A mechanistic analysis revealed two different pathways to connect Pd-NHC complexes to “cocktail”-type catalysis: (i) reductive elimination from a Pd(II) intermediate and the release of...
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144
Total citations:
144
Citations from 2024:
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(23.61%)
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GOST
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Astakhov A. V. et al. A New Mode of Operation of Pd-NHC Systems Studied in a Catalytic Mizoroki–Heck Reaction // Organometallics. 2017. Vol. 36. No. 10. pp. 1981-1992.
GOST all authors (up to 50)
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Astakhov A. V., Khazipov O. V., Chernenko A. Yu., Pasyukov D. V., Kashin A. S., Gordeev E. I., Khrustalev V. N., Chernyshev V. M., Ananikov V. P. A New Mode of Operation of Pd-NHC Systems Studied in a Catalytic Mizoroki–Heck Reaction // Organometallics. 2017. Vol. 36. No. 10. pp. 1981-1992.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.organomet.7b00184
UR - https://doi.org/10.1021/acs.organomet.7b00184
TI - A New Mode of Operation of Pd-NHC Systems Studied in a Catalytic Mizoroki–Heck Reaction
T2 - Organometallics
AU - Astakhov, A. V.
AU - Khazipov, Oleg V
AU - Chernenko, Andrey Yu
AU - Pasyukov, Dmitry V
AU - Kashin, Alexey S
AU - Gordeev, Evgeniy I
AU - Khrustalev, Victor N.
AU - Chernyshev, Victor M.
AU - Ananikov, Valentine P.
PY - 2017
DA - 2017/04/03
PB - American Chemical Society (ACS)
SP - 1981-1992
IS - 10
VL - 36
SN - 0276-7333
SN - 1520-6041
ER -
Cite this
BibTex (up to 50 authors)
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@article{2017_Astakhov,
author = {A. V. Astakhov and Oleg V Khazipov and Andrey Yu Chernenko and Dmitry V Pasyukov and Alexey S Kashin and Evgeniy I Gordeev and Victor N. Khrustalev and Victor M. Chernyshev and Valentine P. Ananikov},
title = {A New Mode of Operation of Pd-NHC Systems Studied in a Catalytic Mizoroki–Heck Reaction},
journal = {Organometallics},
year = {2017},
volume = {36},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/acs.organomet.7b00184},
number = {10},
pages = {1981--1992},
doi = {10.1021/acs.organomet.7b00184}
}
Cite this
MLA
Copy
Astakhov, A. V., et al. “A New Mode of Operation of Pd-NHC Systems Studied in a Catalytic Mizoroki–Heck Reaction.” Organometallics, vol. 36, no. 10, Apr. 2017, pp. 1981-1992. https://doi.org/10.1021/acs.organomet.7b00184.