Tris(pentamethylcyclopentadienyl) Complexes of Late Lanthanides Tb, Dy, Ho, and Er: Solution and Mechanochemical Syntheses and Structural Comparisons
Publication type: Journal Article
Publication date: 2017-07-31
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The tris(pentamethylcyclopentadienyl) complexes, (C5Me5)3Ln (Ln = Tb, Dy, Ho, and Er), have been synthesized to determine if structural trends observed with the larger rare-earth metals, La–Gd, extend to the smaller metals and to determine the level of steric crowding associated with C–H bond activation of benzene and toluene as found for the (C5Me5)3Y complex of the smaller rare-earth metal, yttrium. Three different synthetic methods were used. (C5Me5)3Tb was synthesized in benzene from (C5Me5)2Tb(μ-Ph)2BPh2 and KC5Me5, which established that it does not activate benzene. In contrast, complexes of Dy, Ho, and Er were not isolable in benzene or toluene. (C5Me5)3Dy was synthesized in pentane from [(C5Me5)2DyH]2 and 1,2,3,4-tetramethylfulvene. Solvent-free mechanochemistry was utilized to synthesize the Ho and Er complexes by ball-milling (C5Me5)2Ln(μ-Ph)2BPh2 and KC5Me5 as solids. This route also provided the Tb, Dy, and Y complexes. Crystallographic analysis of these complexes of the smaller metals has al...
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Citations from 2025:
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(17.15%)
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GOST
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Woen D. H. et al. Tris(pentamethylcyclopentadienyl) Complexes of Late Lanthanides Tb, Dy, Ho, and Er: Solution and Mechanochemical Syntheses and Structural Comparisons // Organometallics. 2017. Vol. 36. No. 23. pp. 4558-4563.
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Woen D. H., Kotyk C. M., Mueller T. J., Ziller J. W., Evans W. B. Tris(pentamethylcyclopentadienyl) Complexes of Late Lanthanides Tb, Dy, Ho, and Er: Solution and Mechanochemical Syntheses and Structural Comparisons // Organometallics. 2017. Vol. 36. No. 23. pp. 4558-4563.
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TY - JOUR
DO - 10.1021/acs.organomet.7b00385
UR - https://doi.org/10.1021/acs.organomet.7b00385
TI - Tris(pentamethylcyclopentadienyl) Complexes of Late Lanthanides Tb, Dy, Ho, and Er: Solution and Mechanochemical Syntheses and Structural Comparisons
T2 - Organometallics
AU - Woen, David H
AU - Kotyk, Christopher M.
AU - Mueller, Thomas J.
AU - Ziller, Joseph W.
AU - Evans, William B.
PY - 2017
DA - 2017/07/31
PB - American Chemical Society (ACS)
SP - 4558-4563
IS - 23
VL - 36
SN - 0276-7333
SN - 1520-6041
ER -
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BibTex (up to 50 authors)
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@article{2017_Woen,
author = {David H Woen and Christopher M. Kotyk and Thomas J. Mueller and Joseph W. Ziller and William B. Evans},
title = {Tris(pentamethylcyclopentadienyl) Complexes of Late Lanthanides Tb, Dy, Ho, and Er: Solution and Mechanochemical Syntheses and Structural Comparisons},
journal = {Organometallics},
year = {2017},
volume = {36},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acs.organomet.7b00385},
number = {23},
pages = {4558--4563},
doi = {10.1021/acs.organomet.7b00385}
}
Cite this
MLA
Copy
Woen, David H., et al. “Tris(pentamethylcyclopentadienyl) Complexes of Late Lanthanides Tb, Dy, Ho, and Er: Solution and Mechanochemical Syntheses and Structural Comparisons.” Organometallics, vol. 36, no. 23, Jul. 2017, pp. 4558-4563. https://doi.org/10.1021/acs.organomet.7b00385.