Fast and Slow Release of Catalytically Active Species in Metal/NHC Systems Induced by Aliphatic Amines
Тип публикации: Journal Article
Дата публикации: 2018-04-20
scimago Q2
wos Q1
БС1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
The behavior of ubiquitously used nickel, palladium, and platinum complexes containing N-heterocyclic carbene ligands was studied in solution in the presence of aliphatic amines. Transformation of M(NHC)X2L complexes readily occurred according to the following reactions: (i) release of the NHC ligand in the form of azolium salt and formation of metal clusters or nanoparticles and (ii) isomerization of mono-NHC complexes M(NHC)X2L to bis-NHC derivatives M(NHC)2X2. Facile cleavage of the M–NHC bond was observed and provided the possibility for fast release of catalytically active NHC-free metal species. Bis-NHC metal complexes M(NHC)2X2 were found to be significantly more stable and represented a molecular reservoir of catalytically active species. Slow decomposition of the bis-NHC complexes by removal of the NHC ligands (also in the form of azolium salts) occurred, generating metal clusters or nanoparticles. The observed combination of dual fast- and slow-release channels is an intrinsic latent opportunity...
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Khazipov O. V. et al. Fast and Slow Release of Catalytically Active Species in Metal/NHC Systems Induced by Aliphatic Amines // Organometallics. 2018. Vol. 37. No. 9. pp. 1483-1492.
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Khazipov O. V., Shevchenko M. A., Chernenko A. Yu., Astakhov A. V., Pasyukov D. V., Eremin D. B., Zubavichus Y. V., Khrustalev V. N., Chernyshev V. M., Ananikov V. P. Fast and Slow Release of Catalytically Active Species in Metal/NHC Systems Induced by Aliphatic Amines // Organometallics. 2018. Vol. 37. No. 9. pp. 1483-1492.
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TY - JOUR
DO - 10.1021/acs.organomet.8b00124
UR - https://doi.org/10.1021/acs.organomet.8b00124
TI - Fast and Slow Release of Catalytically Active Species in Metal/NHC Systems Induced by Aliphatic Amines
T2 - Organometallics
AU - Khazipov, Oleg V
AU - Shevchenko, Maxim A
AU - Chernenko, Andrey Yu
AU - Astakhov, A. V.
AU - Pasyukov, Dmitry V
AU - Eremin, Dmitry B.
AU - Zubavichus, Yan V.
AU - Khrustalev, Victor N.
AU - Chernyshev, Victor M.
AU - Ananikov, Valentine P
PY - 2018
DA - 2018/04/20
PB - American Chemical Society (ACS)
SP - 1483-1492
IS - 9
VL - 37
SN - 0276-7333
SN - 1520-6041
ER -
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@article{2018_Khazipov,
author = {Oleg V Khazipov and Maxim A Shevchenko and Andrey Yu Chernenko and A. V. Astakhov and Dmitry V Pasyukov and Dmitry B. Eremin and Yan V. Zubavichus and Victor N. Khrustalev and Victor M. Chernyshev and Valentine P Ananikov},
title = {Fast and Slow Release of Catalytically Active Species in Metal/NHC Systems Induced by Aliphatic Amines},
journal = {Organometallics},
year = {2018},
volume = {37},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/acs.organomet.8b00124},
number = {9},
pages = {1483--1492},
doi = {10.1021/acs.organomet.8b00124}
}
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MLA
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Khazipov, Oleg V., et al. “Fast and Slow Release of Catalytically Active Species in Metal/NHC Systems Induced by Aliphatic Amines.” Organometallics, vol. 37, no. 9, Apr. 2018, pp. 1483-1492. https://doi.org/10.1021/acs.organomet.8b00124.