When Applying the Mercury Poisoning Test to Palladacycle-Catalyzed Reactions, One Should Not Consider the Common Misconception of Mercury(0) Selectivity
Publication type: Journal Article
Publication date: 2018-07-31
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The aim of this study was to demonstrate the absolute necessity of control experiments for a correct interpretation of mercury drop test results when applied to mechanistic studies of palladacycle-catalyzed reactions. It was shown that the interaction of diverse azapalladacycles with metallic mercury leads to the formation of organomercuric chlorides during the redox-transmetalation process. The structure of these organomercurials was confirmed by elemental analysis, 1H, 13C{1H}, and 199Hg{1H} NMR spectra, X-ray diffraction analysis, and DFT calculations. The behavior and properties of C,N-mercuracycles bearing the weak and labile N···Hg bond are discussed on the basis of the temperature dependence of the NMR spectra and calculated thermodynamic parameters of the dechelation process.
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52
Total citations:
52
Citations from 2024:
15
(28.84%)
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GOST
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Gorunova O. N. et al. When Applying the Mercury Poisoning Test to Palladacycle-Catalyzed Reactions, One Should Not Consider the Common Misconception of Mercury(0) Selectivity // Organometallics. 2018. Vol. 37. No. 17. pp. 2842-2858.
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Gorunova O. N., Novitskiy I. M., Grishin Y., Gloriozov I. P., Roznyatovsky V. A., Khrustalev V. N., Kochetkov K. A., Dunina V. V. When Applying the Mercury Poisoning Test to Palladacycle-Catalyzed Reactions, One Should Not Consider the Common Misconception of Mercury(0) Selectivity // Organometallics. 2018. Vol. 37. No. 17. pp. 2842-2858.
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TY - JOUR
DO - 10.1021/acs.organomet.8b00363
UR - https://doi.org/10.1021/acs.organomet.8b00363
TI - When Applying the Mercury Poisoning Test to Palladacycle-Catalyzed Reactions, One Should Not Consider the Common Misconception of Mercury(0) Selectivity
T2 - Organometallics
AU - Gorunova, Olga N
AU - Novitskiy, Ivan M.
AU - Grishin, Yuri
AU - Gloriozov, Igor P.
AU - Roznyatovsky, Vitaly A
AU - Khrustalev, Victor N.
AU - Kochetkov, Konstantin A.
AU - Dunina, Valery V
PY - 2018
DA - 2018/07/31
PB - American Chemical Society (ACS)
SP - 2842-2858
IS - 17
VL - 37
SN - 0276-7333
SN - 1520-6041
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Gorunova,
author = {Olga N Gorunova and Ivan M. Novitskiy and Yuri Grishin and Igor P. Gloriozov and Vitaly A Roznyatovsky and Victor N. Khrustalev and Konstantin A. Kochetkov and Valery V Dunina},
title = {When Applying the Mercury Poisoning Test to Palladacycle-Catalyzed Reactions, One Should Not Consider the Common Misconception of Mercury(0) Selectivity},
journal = {Organometallics},
year = {2018},
volume = {37},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acs.organomet.8b00363},
number = {17},
pages = {2842--2858},
doi = {10.1021/acs.organomet.8b00363}
}
Cite this
MLA
Copy
Gorunova, Olga N., et al. “When Applying the Mercury Poisoning Test to Palladacycle-Catalyzed Reactions, One Should Not Consider the Common Misconception of Mercury(0) Selectivity.” Organometallics, vol. 37, no. 17, Jul. 2018, pp. 2842-2858. https://doi.org/10.1021/acs.organomet.8b00363.