Single-Molecule Magnet Behavior in Dy3+ Half-Sandwich Complexes Based on Ene-Diamido and Cp* Ligands
Publication type: Journal Article
Publication date: 2019-02-04
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
We report in this communication the synthesis, structure, and magnetic investigations of two new half-sandwich complexes: [Dy(DAD)Cp*(THF)] (1) and [Li(THF)3][Dy(DAD)Cp*Cl] (2) (Cp*: C5Me5, DAD: [2,6-iPr2C6H3N–CMe=CMe–NC6H3iPr2–2,6). Both compounds exhibit zero-field single-molecule magnet behavior but distinct relaxation dynamics originating from difference in the arrangement of Cp* and DAD ligands. The anisotropic barrier for 1 is found to be 1 order of magnitude greater than for 2.
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GOST
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Long J. et al. Single-Molecule Magnet Behavior in Dy3+ Half-Sandwich Complexes Based on Ene-Diamido and Cp* Ligands // Organometallics. 2019. Vol. 38. No. 4. pp. 748-752.
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Long J., Tolpygin A. O., Cherkasov A. V., Lyssenko K. A., Guari Y., Larionova J., Trifonov A. A. Single-Molecule Magnet Behavior in Dy3+ Half-Sandwich Complexes Based on Ene-Diamido and Cp* Ligands // Organometallics. 2019. Vol. 38. No. 4. pp. 748-752.
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RIS
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TY - JOUR
DO - 10.1021/acs.organomet.8b00901
UR - https://doi.org/10.1021/acs.organomet.8b00901
TI - Single-Molecule Magnet Behavior in Dy3+ Half-Sandwich Complexes Based on Ene-Diamido and Cp* Ligands
T2 - Organometallics
AU - Long, Jérôme
AU - Tolpygin, Aleksei O
AU - Cherkasov, Anton V
AU - Lyssenko, Konstantin A.
AU - Guari, Yannick
AU - Larionova, Joulia
AU - Trifonov, Alexander A.
PY - 2019
DA - 2019/02/04
PB - American Chemical Society (ACS)
SP - 748-752
IS - 4
VL - 38
SN - 0276-7333
SN - 1520-6041
ER -
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BibTex (up to 50 authors)
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@article{2019_Long,
author = {Jérôme Long and Aleksei O Tolpygin and Anton V Cherkasov and Konstantin A. Lyssenko and Yannick Guari and Joulia Larionova and Alexander A. Trifonov},
title = {Single-Molecule Magnet Behavior in Dy3+ Half-Sandwich Complexes Based on Ene-Diamido and Cp* Ligands},
journal = {Organometallics},
year = {2019},
volume = {38},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acs.organomet.8b00901},
number = {4},
pages = {748--752},
doi = {10.1021/acs.organomet.8b00901}
}
Cite this
MLA
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Long, Jérôme, et al. “Single-Molecule Magnet Behavior in Dy3+ Half-Sandwich Complexes Based on Ene-Diamido and Cp* Ligands.” Organometallics, vol. 38, no. 4, Feb. 2019, pp. 748-752. https://doi.org/10.1021/acs.organomet.8b00901.