Cobalt-Catalyzed Dearomatization of Indoles via Transfer Hydrogenation To Afford Polycyclic Indolines
Publication type: Journal Article
Publication date: 2021-03-08
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
33683891
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A cobalt-catalyzed dearomatization of indoles via transfer hydrogenation with HBpin and H2O has been developed. This reaction offered a straightforward platform to access hexahydropyrido[1,2-a]indoles in high regio- and chemoselectivity. A preliminary reaction mechanism was proposed on the basis of deuterium-labeling experiments, and a cobalt hydride species was involved in the reaction.
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Metrics
23
Total citations:
23
Citations from 2024:
9
(39.13%)
Cite this
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MLA
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GOST
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Chen S. et al. Cobalt-Catalyzed Dearomatization of Indoles via Transfer Hydrogenation To Afford Polycyclic Indolines // Organic Letters. 2021. Vol. 23. No. 6. pp. 2212-2216.
GOST all authors (up to 50)
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Chen S., Cai M., Huang J., Yao H., Lin A. Cobalt-Catalyzed Dearomatization of Indoles via Transfer Hydrogenation To Afford Polycyclic Indolines // Organic Letters. 2021. Vol. 23. No. 6. pp. 2212-2216.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.1c00354
UR - https://doi.org/10.1021/acs.orglett.1c00354
TI - Cobalt-Catalyzed Dearomatization of Indoles via Transfer Hydrogenation To Afford Polycyclic Indolines
T2 - Organic Letters
AU - Chen, Siwei
AU - Cai, Min
AU - Huang, Junru
AU - Yao, Hequan
AU - Lin, Aijun
PY - 2021
DA - 2021/03/08
PB - American Chemical Society (ACS)
SP - 2212-2216
IS - 6
VL - 23
PMID - 33683891
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2021_Chen,
author = {Siwei Chen and Min Cai and Junru Huang and Hequan Yao and Aijun Lin},
title = {Cobalt-Catalyzed Dearomatization of Indoles via Transfer Hydrogenation To Afford Polycyclic Indolines},
journal = {Organic Letters},
year = {2021},
volume = {23},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acs.orglett.1c00354},
number = {6},
pages = {2212--2216},
doi = {10.1021/acs.orglett.1c00354}
}
Cite this
MLA
Copy
Chen, Siwei, et al. “Cobalt-Catalyzed Dearomatization of Indoles via Transfer Hydrogenation To Afford Polycyclic Indolines.” Organic Letters, vol. 23, no. 6, Mar. 2021, pp. 2212-2216. https://doi.org/10.1021/acs.orglett.1c00354.