ACS Applied Energy Materials, volume 4, issue 7, pages 7309-7315
On the Lithium Distribution in Halide Superionic Argyrodites by Halide Incorporation in Li7–xPS6–xClx
Publication type: Journal Article
Publication date: 2021-07-07
Journal:
ACS Applied Energy Materials
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 6.4
ISSN: 25740962, 25740962
Materials Chemistry
Electrochemistry
Electrical and Electronic Engineering
Energy Engineering and Power Technology
Chemical Engineering (miscellaneous)
Abstract
Superionic lithium argyrodites are attractive as solid electrolytes for all-solid-state-batteries. These materials of composition Li6PS5X (X = Cl, Br, and I) exhibit structural disorder between the X−/S2− positions, with higher disorder realizing better Li+ transport. Further replacement of the sulfide by chloride anions (for the series Li7−xPS6−xClx) has been shown to increase the ionic conductivity. However, the underlying changes to the lithium substructure are still relatively unknown. Here we explore a larger range of nominal halide compositions in this material from x = 0.25 to x = 1.5 and explore the changes with neutron diffraction and impedance spectroscopy. The replacement of S2− by Cl−causes a lowered average charge in the center of the prevalent Li+ “cages”, which in turn causes weaker interactions with Li+ ions. Analysis of neutron diffraction data reveals that the increased Cl− content causes these clustered Li+ “cages” to become more interconnected, thereby increasing Li+ conductivity through the structure. This study explores the understanding of the fundamental structure–transport correlations in the argyrodites, specifically structural changes withinthe Li+ ion substructure upon changing anionic charge distribution.
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Citations by publishers
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1 publication, 2.86%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 2.86%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Gautam A. et al. On the Lithium Distribution in Halide Superionic Argyrodites by Halide Incorporation in Li7–xPS6–xClx // ACS Applied Energy Materials. 2021. Vol. 4. No. 7. pp. 7309-7315.
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Gautam A., Ghidiu M., Suard E., Kraft M. A., Zeier W. G. On the Lithium Distribution in Halide Superionic Argyrodites by Halide Incorporation in Li7–xPS6–xClx // ACS Applied Energy Materials. 2021. Vol. 4. No. 7. pp. 7309-7315.
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TY - JOUR
DO - 10.1021/acsaem.1c01417
UR - https://doi.org/10.1021/acsaem.1c01417
TI - On the Lithium Distribution in Halide Superionic Argyrodites by Halide Incorporation in Li7–xPS6–xClx
T2 - ACS Applied Energy Materials
AU - Gautam, Ajay
AU - Kraft, Marvin A
AU - Suard, E.
AU - Zeier, Wolfgang G.
AU - Ghidiu, Michael
PY - 2021
DA - 2021/07/07 00:00:00
PB - American Chemical Society (ACS)
SP - 7309-7315
IS - 7
VL - 4
SN - 2574-0962
SN - 2574-0962
ER -
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@article{2021_Gautam,
author = {Ajay Gautam and Marvin A Kraft and E. Suard and Wolfgang G. Zeier and Michael Ghidiu},
title = {On the Lithium Distribution in Halide Superionic Argyrodites by Halide Incorporation in Li7–xPS6–xClx},
journal = {ACS Applied Energy Materials},
year = {2021},
volume = {4},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acsaem.1c01417},
number = {7},
pages = {7309--7315},
doi = {10.1021/acsaem.1c01417}
}
Cite this
MLA
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Gautam, Ajay, et al. “On the Lithium Distribution in Halide Superionic Argyrodites by Halide Incorporation in Li7–xPS6–xClx.” ACS Applied Energy Materials, vol. 4, no. 7, Jul. 2021, pp. 7309-7315. https://doi.org/10.1021/acsaem.1c01417.