ACS Materials Letters, volume 4, issue 2, pages 424-431
A Nanoscale Design Approach for Enhancing the Li-Ion Conductivity of the Li10GeP2S12 Solid Electrolyte
James Alexander Dawson
1, 2
,
Md Saiful Islam
3, 4
3
Department of Chemistry, University of Bath, Bath, BA2 7AY, U.K.
|
Publication type: Journal Article
Publication date: 2022-01-26
Journal:
ACS Materials Letters
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 11.4
ISSN: 26394979, 26394979
General Chemical Engineering
General Materials Science
Biomedical Engineering
Abstract
The discovery of the lithium superionic conductor Li10GeP2S12 (LGPS) has led to significant research activity on solid electrolytes for high-performance solid-state batteries. Despite LGPS exhibiting a remarkably high room-temperature Li-ion conductivity, comparable to that of the liquid electrolytes used in current Li-ion batteries, nanoscale effects in this material have not been fully explored. Here, we predict that nanosizing of LGPS can be used to further enhance its Li-ion conductivity. By utilizing state-of-the-art nanoscale modeling techniques, our results reveal significant nanosizing effects with the Li-ion conductivity of LGPS increasing with decreasing particle volume. These features are due to a fundamental change from a primarily one-dimensional Li-ion conduction mechanism to a three-dimensional mechanism and major changes in the local structure. For the smallest nanometric particle size, the Li-ion conductivity at room temperature is three times higher than that of the bulk system. These findings reveal that nanosizing LGPS and related solid electrolytes could be an effective design approach to enhance their Li-ion conductivity.
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1 publication, 3.57%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Dawson J. A. et al. A Nanoscale Design Approach for Enhancing the Li-Ion Conductivity of the Li10GeP2S12 Solid Electrolyte // ACS Materials Letters. 2022. Vol. 4. No. 2. pp. 424-431.
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Dawson J. A., Islam M. S. A Nanoscale Design Approach for Enhancing the Li-Ion Conductivity of the Li10GeP2S12 Solid Electrolyte // ACS Materials Letters. 2022. Vol. 4. No. 2. pp. 424-431.
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TY - JOUR
DO - 10.1021/acsmaterialslett.1c00766
UR - https://doi.org/10.1021/acsmaterialslett.1c00766
TI - A Nanoscale Design Approach for Enhancing the Li-Ion Conductivity of the Li10GeP2S12 Solid Electrolyte
T2 - ACS Materials Letters
AU - Dawson, James Alexander
AU - Islam, Md Saiful
PY - 2022
DA - 2022/01/26 00:00:00
PB - American Chemical Society (ACS)
SP - 424-431
IS - 2
VL - 4
SN - 2639-4979
SN - 2639-4979
ER -
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@article{2022_Dawson,
author = {James Alexander Dawson and Md Saiful Islam},
title = {A Nanoscale Design Approach for Enhancing the Li-Ion Conductivity of the Li10GeP2S12 Solid Electrolyte},
journal = {ACS Materials Letters},
year = {2022},
volume = {4},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/acsmaterialslett.1c00766},
number = {2},
pages = {424--431},
doi = {10.1021/acsmaterialslett.1c00766}
}
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MLA
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Dawson, James Alexander, et al. “A Nanoscale Design Approach for Enhancing the Li-Ion Conductivity of the Li10GeP2S12 Solid Electrolyte.” ACS Materials Letters, vol. 4, no. 2, Jan. 2022, pp. 424-431. https://doi.org/10.1021/acsmaterialslett.1c00766.