Single Au Atom Doping of Silver Nanoclusters
Тип публикации: Journal Article
Дата публикации: 2018-11-20
scimago Q1
wos Q1
БС1
SJR: 4.497
CiteScore: 24.2
Impact factor: 16.0
ISSN: 19360851, 1936086X
PubMed ID:
30458110
General Physics and Astronomy
General Materials Science
General Engineering
Краткое описание
Ag29 nanoclusters capped with lipoic acid (LA) can be doped with Au. The doped clusters show enhanced stability and increased luminescence efficiency. We attribute the higher quantum yield to an increase in the rate of radiative decay. With mass spectrometry, the Au-doped clusters were found to consist predominantly of Au1Ag28(LA)123-. The clusters were characterized using X-ray absorption spectroscopy at the Au L3-edge. Both the extended absorption fine structure (EXAFS) and the near edge structure (XANES) in combination with electronic structure calculations confirm that the Au dopant is preferentially located in the center of the cluster. A useful XANES spectrum can be recorded for lower concentrations, or in shorter time, than the more commonly used EXAFS. This makes XANES a valuable tool for structural characterization.
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ГОСТ
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van der Linden M. et al. Single Au Atom Doping of Silver Nanoclusters // ACS Nano. 2018. Vol. 12. No. 12. pp. 12751-12760.
ГОСТ со всеми авторами (до 50)
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van der Linden M., van Bunningen A. J., Amidani L., Bransen M., Elnaggar H., Glatzel P., Meijerink A., de Groot F. M. F. Single Au Atom Doping of Silver Nanoclusters // ACS Nano. 2018. Vol. 12. No. 12. pp. 12751-12760.
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RIS
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TY - JOUR
DO - 10.1021/acsnano.8b07807
UR - https://doi.org/10.1021/acsnano.8b07807
TI - Single Au Atom Doping of Silver Nanoclusters
T2 - ACS Nano
AU - van der Linden, Marte
AU - van Bunningen, Arnoldus J.
AU - Amidani, Lucia
AU - Bransen, Maarten
AU - Elnaggar, Hebatalla
AU - Glatzel, Pieter
AU - Meijerink, A.
AU - de Groot, F. M. F.
PY - 2018
DA - 2018/11/20
PB - American Chemical Society (ACS)
SP - 12751-12760
IS - 12
VL - 12
PMID - 30458110
SN - 1936-0851
SN - 1936-086X
ER -
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BibTex (до 50 авторов)
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@article{2018_van der Linden,
author = {Marte van der Linden and Arnoldus J. van Bunningen and Lucia Amidani and Maarten Bransen and Hebatalla Elnaggar and Pieter Glatzel and A. Meijerink and F. M. F. de Groot},
title = {Single Au Atom Doping of Silver Nanoclusters},
journal = {ACS Nano},
year = {2018},
volume = {12},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/acsnano.8b07807},
number = {12},
pages = {12751--12760},
doi = {10.1021/acsnano.8b07807}
}
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MLA
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van der Linden, Marte, et al. “Single Au Atom Doping of Silver Nanoclusters.” ACS Nano, vol. 12, no. 12, Nov. 2018, pp. 12751-12760. https://doi.org/10.1021/acsnano.8b07807.