Open Access
ACS Omega, volume 6, issue 36, pages 23181-23190
Removal of Acidic-Sulfur-Containing Components from Gasoline Fractions and Their Simulated Analogues Using Silica Gel Modified with Transition-Metal Carboxylates
Publication type: Journal Article
Publication date: 2021-08-27
PubMed ID:
34549119
General Chemistry
General Chemical Engineering
Abstract
The removal of acidic sulfur-containing components [hydrogen sulfide (H2S) and alkanethiols or thiols (RSH)] from simulated mixtures and analogues of gasoline fractions with Zn(II), Cu(II), Co(II), and Ni(II) acetates, pivalates, and malonates applied on silica gel with various porosities under ultrasonic treatment in solution has been studied. The dependence of the adsorption of H2S and RSH on the surface of silica gel modified by metal complexes with organic ligands on various factors (the pore size of the silica gel, the time of ultrasonic treatment, and the nature of carboxylate complexes) is established. The best results for the removal of total sulfur from the model mixture and an analogue of the gasoline fraction were obtained using silica gel modified with zinc pivalate (96%) and cobalt pivalate (95%). A waste-free method to desulfurize fuel with zinc pivalate based on the production of practically useful ZnS is suggested.
Citations by journals
|
1
2
|
|
|
Izvestiya Vysshikh Uchebnykh Zavedenii, Seriya Khimiya i Khimicheskaya Tekhnologiya
|
Izvestiya Vysshikh Uchebnykh Zavedenii, Seriya Khimiya i Khimicheskaya Tekhnologiya
2 publications, 28.57%
|
|
Russian Chemical Bulletin
|
Russian Chemical Bulletin
1 publication, 14.29%
|
|
Journal of Materials Research
|
Journal of Materials Research
1 publication, 14.29%
|
|
Biomass Conversion and Biorefinery
|
Biomass Conversion and Biorefinery
1 publication, 14.29%
|
|
Advanced Materials
|
Advanced Materials
1 publication, 14.29%
|
|
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
|
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
1 publication, 14.29%
|
|
1
2
|
Citations by publishers
|
1
2
|
|
|
Springer Nature
|
Springer Nature
2 publications, 28.57%
|
|
Ivanovo State University of Chemistry and Technology
|
Ivanovo State University of Chemistry and Technology
2 publications, 28.57%
|
|
Cambridge University Press
|
Cambridge University Press
1 publication, 14.29%
|
|
Wiley
|
Wiley
1 publication, 14.29%
|
|
Pleiades Publishing
|
Pleiades Publishing
1 publication, 14.29%
|
|
1
2
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2021,2022,2023],"ids":[0,0,0],"codes":[0,0,0],"imageUrls":["","",""],"datasets":[{"label":"Citations number","data":[1,2,4],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6"],"percentage":["14.29","28.57","57.14"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Izvestiya Vysshikh Uchebnykh Zavedenii, Seriya Khimiya i Khimicheskaya Tekhnologiya","Russian Chemical Bulletin","Journal of Materials Research","Biomass Conversion and Biorefinery","Advanced Materials","Russian Journal of Coordination Chemistry\/Koordinatsionnaya Khimiya"],"ids":[21625,10918,1394,4276,25159,12054],"codes":[0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/PmVbwfUc2aRdrnSFGtkfcabQRXGkjjb14bQC1gcl_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/cF81zWlLdkmYekymGuDcSdvgBGNKaIDoMoeJtHS1_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp"],"datasets":[{"label":"","data":[2,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[28.57,14.29,14.29,14.29,14.29,14.29],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Springer Nature","Ivanovo State University of Chemistry and Technology","Cambridge University Press","Wiley","Pleiades Publishing"],"ids":[8,675,1,11,101],"codes":[0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/PmVbwfUc2aRdrnSFGtkfcabQRXGkjjb14bQC1gcl_medium.webp","\/storage\/images\/resized\/cF81zWlLdkmYekymGuDcSdvgBGNKaIDoMoeJtHS1_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp"],"datasets":[{"label":"","data":[2,2,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[28.57,28.57,14.29,14.29,14.29],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Okhlobystin A. O. et al. Removal of Acidic-Sulfur-Containing Components from Gasoline Fractions and Their Simulated Analogues Using Silica Gel Modified with Transition-Metal Carboxylates // ACS Omega. 2021. Vol. 6. No. 36. pp. 23181-23190.
GOST all authors (up to 50)
Copy
Okhlobystin A. O., Eremenko I. L., Storozhenko V. N., Oleinikova K. V., Kamyshnikova A. S., Pashchenko K. P., Shinkar E. V., Zorina-Tikhonova E. N., Kiskin M. A., Baranchikov A. E., Kottsov S. Yu., Berberova N. T. Removal of Acidic-Sulfur-Containing Components from Gasoline Fractions and Their Simulated Analogues Using Silica Gel Modified with Transition-Metal Carboxylates // ACS Omega. 2021. Vol. 6. No. 36. pp. 23181-23190.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acsomega.1c02777
UR - https://doi.org/10.1021%2Facsomega.1c02777
TI - Removal of Acidic-Sulfur-Containing Components from Gasoline Fractions and Their Simulated Analogues Using Silica Gel Modified with Transition-Metal Carboxylates
T2 - ACS Omega
AU - Okhlobystin, Andrey O
AU - Eremenko, Igor L.
AU - Storozhenko, Valentina N
AU - Oleinikova, Kseniya V
AU - Kamyshnikova, Anna S
AU - Pashchenko, Konstantin P
AU - Shinkar, Elena V
AU - Zorina-Tikhonova, Ekaterina N.
AU - Kiskin, Mikhail A.
AU - Baranchikov, Alexander E
AU - Kottsov, Sergey Yu
AU - Berberova, N. T.
PY - 2021
DA - 2021/08/27 00:00:00
PB - American Chemical Society (ACS)
SP - 23181-23190
IS - 36
VL - 6
PMID - 34549119
SN - 2470-1343
ER -
Cite this
BibTex
Copy
@article{2021_Okhlobystin,
author = {Andrey O Okhlobystin and Igor L. Eremenko and Valentina N Storozhenko and Kseniya V Oleinikova and Anna S Kamyshnikova and Konstantin P Pashchenko and Elena V Shinkar and Ekaterina N. Zorina-Tikhonova and Mikhail A. Kiskin and Alexander E Baranchikov and Sergey Yu Kottsov and N. T. Berberova},
title = {Removal of Acidic-Sulfur-Containing Components from Gasoline Fractions and Their Simulated Analogues Using Silica Gel Modified with Transition-Metal Carboxylates},
journal = {ACS Omega},
year = {2021},
volume = {6},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021%2Facsomega.1c02777},
number = {36},
pages = {23181--23190},
doi = {10.1021/acsomega.1c02777}
}
Cite this
MLA
Copy
Okhlobystin, Andrey O., et al. “Removal of Acidic-Sulfur-Containing Components from Gasoline Fractions and Their Simulated Analogues Using Silica Gel Modified with Transition-Metal Carboxylates.” ACS Omega, vol. 6, no. 36, Aug. 2021, pp. 23181-23190. https://doi.org/10.1021%2Facsomega.1c02777.