Synthesis, structure, and properties of new perovskite PbVO3
Тип публикации: Journal Article
Дата публикации: 2004-07-28
scimago Q1
wos Q1
white level БС1
SJR: 2.065
CiteScore: 12
Impact factor: 7
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Краткое описание
The new perovskite PbVO3 was synthesized under high-temperature and high-pressure conditions. Its crystal structure (a = 3.80005(6) A, c = 4.6703(1) A, Z = 1, S.G. P4mm) contains isolated layers of corner-shared VO5 pyramids, which are formed instead of octahedra due to a strong tetragonal distortion (c/a = 1.23). The lead atom is shifted out of the center of the unit cell toward one of two [VO2]-layers due to the influence of the lone pair. This new perovskite exhibits a semiconductor-like ρ(T) dependence down to 2 K. This behavior can be qualitatively explained by taking into account strong electron correlations in electronic structure calculations.
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Shpanchenko R. V. et al. Synthesis, structure, and properties of new perovskite PbVO3 // Chemistry of Materials. 2004. Vol. 16. No. 17. pp. 3267-3273.
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Tsirlin A. A., Chizhov P. S., Khlybov E. P., Pomjakushin V., Balagurov A. M., Medvedeva J. E., Kaul E. E., Geibel C. Synthesis, structure, and properties of new perovskite PbVO3 // Chemistry of Materials. 2004. Vol. 16. No. 17. pp. 3267-3273.
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TY - JOUR
DO - 10.1021/cm049310x
UR - https://pubs.acs.org/doi/10.1021/cm049310x
TI - Synthesis, structure, and properties of new perovskite PbVO3
T2 - Chemistry of Materials
AU - Tsirlin, A. A.
AU - Chizhov, Pavel S
AU - Khlybov, Evgeny P
AU - Pomjakushin, Vladimir
AU - Balagurov, Anatoly M.
AU - Medvedeva, Julia E.
AU - Kaul, Enrique E.
AU - Geibel, C.
PY - 2004
DA - 2004/07/28
PB - American Chemical Society (ACS)
SP - 3267-3273
IS - 17
VL - 16
SN - 0897-4756
SN - 1520-5002
ER -
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@article{2004_Shpanchenko,
author = {A. A. Tsirlin and Pavel S Chizhov and Evgeny P Khlybov and Vladimir Pomjakushin and Anatoly M. Balagurov and Julia E. Medvedeva and Enrique E. Kaul and C. Geibel},
title = {Synthesis, structure, and properties of new perovskite PbVO3},
journal = {Chemistry of Materials},
year = {2004},
volume = {16},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://pubs.acs.org/doi/10.1021/cm049310x},
number = {17},
pages = {3267--3273},
doi = {10.1021/cm049310x}
}
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Shpanchenko, Roman V., et al. “Synthesis, structure, and properties of new perovskite PbVO3.” Chemistry of Materials, vol. 16, no. 17, Jul. 2004, pp. 3267-3273. https://pubs.acs.org/doi/10.1021/cm049310x.
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